公开(公告)号：US3725239A

公开(公告)日：1973-04-03

申请号：US3725239D

申请日：1971-11-15

申请人： SHELL OIL CO

发明人： KIOVSKY T ,  WALD M

IPC分类号： B01J31/18 ,  C07C5/11 ,  C10G1/08 ,  C10G1/06

CPC分类号： C10G1/086 ,  B01J31/1805 ,  B01J2231/641 ,  B01J2231/646 ,  B01J2531/26 ,  B01J2531/28 ,  B01J2531/50 ,  B01J2531/52 ,  C07C5/11 ,  C07C2527/125 ,  C07C2527/133 ,  C07C2527/135 ,  C07C2527/138 ,  Y10S585/943 ,  C07C13/48

摘要： A CATALYST FOR INCREASING THE RATE OF HYDROGENATION REACTIONS INCLUDNG A COMPLEX SALT OF THE CHLORIDE, BROMIDE OR IODIDE OF ZINC, TIN, ANTIMONY, BISMUTH, CADMIUM, GALLIUM, MERCURY OR ARSENIC, AND THE CORRESPONDING AMMONIUM HALIDE.

公开(公告)号：US3764515A

公开(公告)日：1973-10-09

申请号：US3764515D

申请日：1971-04-23

申请人： SHELL OIL CO

发明人： KIOVSKY T

IPC分类号： C10G47/08 ,  C10G1/06

CPC分类号： C10G47/08

摘要： There is disclosed a process for hydrocracking coal or other heavy hydrocarbon fractions employing a molten catalyst system, including a mineral acid that is stable at reaction conditions, and a metal halide catalyst selected from zinc chloride, bromide or iodide, antimony bromide or iodide, tin bromide, titanium iodide, arsenic bromide or iodide, mercuric bromide or iodide, gallium bromide, or bismuth bromide. If a halogen acid is employed as the mineral acid, it is preferred that the halogen in the metal salt correspond to the halogen in the acid.

摘要翻译： 公开了一种使用熔融催化剂体系，包括在反应条件下稳定的无机酸和选自氯化锌，溴化物或碘化物的金属卤化物催化剂或其他重质烃馏分加氢裂化的方法， 溴化物，碘化钛，溴化砷或碘化物，溴化汞或碘化物，溴化镓或溴化铋。 如果使用卤酸作为无机酸，则金属盐中的卤素优选对应于酸中的卤素。

公开(公告)号：US3824179A

公开(公告)日：1974-07-16

申请号：US35496673

申请日：1973-04-27

申请人： SHELL OIL CO

发明人： KIOVSKY T

IPC分类号： B01J23/04 ,  B01J27/16 ,  B01J37/28 ,  C10G47/08 ,  C10G13/08 ,  B01J11/78

CPC分类号： B01J37/28 ,  B01J23/04 ,  B01J27/16 ,  C10G47/08

摘要： HIGHER MOLECULAR WEIGHT HYDROCARBONACEOUS MATERIALS CONTAINING POLYNUCLEAR SUBSTANCES, SUCH AS HEAVY PETROLEUM CRUDES AND HIGHER BOILING PETROLEUM FRACTIONS, INCLUDING RESIDUAL FRACTIONS, SHALE OIL, TAR SAND OIL, OIL AND TAR FROM COAL AND COAL ITSELF ARE HYDROCRACKED AT A ELEVATED TEMPERATURE RANGING FROM 200*C. TO 500*C. AND IN THE PRESENCE OF HYDROGEN AT A PRESSURE OF 200 TO 3000 P.S.I.G., WHILE INTIMATELY MIXED WITH A HOMOGENEOUS CONTINUOUS LIQUID PHASE CATALYST SYSTEM COMPRISING PREDOMINATELY ONE OR MORE PHOSPHORIIC ACIDS THERMALLY STABLE UNDER THE HYDROCRACKING CONDITIONS, SUCH AS PYROPHOSPHORIC ACID AND POLYPHOSPHORIC ACIDS HAVING AN EMPIRICAL RATIO OF H2O:P2O5 OF 3 OR LESS, AND MINOR PROPORTION, E.G., LESS THAN 20% BY WEIGHT OF CERTAIN IODINE COMPOUNDS, E.G., SPECIALLY HL, OR NH4L.