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    Living radical polymerization method
    1.
    发明授权
    Living radical polymerization method 有权
    活性自由基聚合法

    公开(公告)号：US07399814B2

    公开(公告)日：2008-07-15

    申请号：US11459370

    申请日：2006-07-24

    申请人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

    发明人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

    IPC分类号： C08F4/20 ,  C08F4/16 ,  C08F4/72 ,  B01J27/135 ,  C07F7/30

    CPC分类号： B01J31/122 ,  B01J31/22 ,  B01J2531/42 ,  B01J2531/52 ,  C08F112/08 ,  C08F220/14

    摘要： A highly active and environment-friendly catalyst for use in a living radical polymerization is provided.A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from germanium, tin and antimony, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction under the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as low toxicity of the catalyst, a small amount of the catalyst can be used, high solubility of the catalyst, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than a conventional living radical polymerization method.

    摘要翻译： 提供了用于活性自由基聚合的高活性和环境友好的催化剂。 提供了一种用于活性自由基聚合方法的催化剂。 该催化剂包括选自锗，锡和锑的中心元素和与中心元素结合的至少一个卤素原子。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应，从而可以得到分子量分布窄的聚合物。 本发明具有催化剂毒性低，可使用少量催化剂，催化剂溶解性高，反应条件温和，无着色，无异味（成型品不必要后处理）等优点。 本发明的方法比常规的活性自由基聚合方法更环保且更经济。

    Polyester polycondensation with catalyst and a catalyst enhancer
    2.
    发明申请
    Polyester polycondensation with catalyst and a catalyst enhancer 失效

    公开(公告)号：US20020032300A1

    公开(公告)日：2002-03-14

    申请号：US09895990

    申请日：2001-06-29

    发明人： Conor M. Dowling ,  Bin Chen ,  Sri R. Seshadri

    IPC分类号： C08G063/02 ,  B01J031/00

    CPC分类号： C08G63/85 ,  B01J21/063 ,  B01J31/04 ,  B01J31/2239 ,  B01J31/26 ,  B01J2531/0205 ,  B01J2531/10 ,  B01J2531/20 ,  B01J2531/46 ,  B01J2531/52 ,  C08G63/82 ,  C08G63/83 ,  C08G63/84 ,  C08G63/87

    摘要： The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium or potassium titanyl oxalate, Li2 or K2TiO(C2O4)2, lithium or potassium oxalate, Li2 or K2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.

    Trivalent antimony catalyst
    3.
    发明授权
    Trivalent antimony catalyst 失效
    三价锑催化剂

    公开(公告)号：US3935170A

    公开(公告)日：1976-01-27

    申请号：US546794

    申请日：1975-02-03

    申请人： Otto Ernest Loeffler

    发明人： Otto Ernest Loeffler

    IPC分类号： B01J31/02 ,  B01J31/04 ,  C07F9/90 ,  C08G63/86 ,  C08G63/14

    CPC分类号： C08G63/866 ,  B01J31/0212 ,  B01J31/04 ,  B01J31/2234 ,  B01J31/2239 ,  B01J31/4015 ,  C07F9/902 ,  B01J2531/52 ,  Y02P20/584

    摘要： A novel antimony catalyst for polyester condensation reactions is described comprising trivalent antimony having its valences occupied by dianion radicals of 1,2-diols and anion radicals or organic carboxylic acids. The molar ratio of antimony to dianion radical of 1,2-diol to anion radical of organic carboxylic acid is 1:1:1. The antimony compound is prepared by reacting a mixture of a 1,2-diol and a trivalent antimony reactant represented by the formula; ##EQU1## wherein Sb is antimony, R.sub.1 is an anion radical of an organic carboxylic acid; and R.sub.2 is selected from the group consisting of anions of alcohols, anions of organic carboxylic acids and mixtures thereof.

    摘要翻译： 描述了一种用于聚酯缩合反应的新型锑催化剂，其包含其价态被1,2-二醇和阴离子基团或有机羧酸的二阴离子占据的三价锑。 1,2-二醇与有机羧酸阴离子自由基的锑与二阴离子自由基的摩尔比为1:1:1。 锑化合物通过使1,2-二醇和由式表示的三价锑反应物的混合物反应来制备; R2是Sb，其中Sb是锑，R1是有机羧酸的阴离子基团; 并且R 2选自醇阴离子，有机羧酸的阴离子及其混合物。

    Polyester polycondensation with catalyst and a catalyst enhancer
    6.
    发明授权
    Polyester polycondensation with catalyst and a catalyst enhancer 失效
    与催化剂和催化剂增强剂的聚酯缩聚

    公开(公告)号：US06372879B1

    公开(公告)日：2002-04-16

    申请号：US09895990

    申请日：2001-06-29

    申请人： Conor M. Dowling ,  Bin Chen ,  Sri R. Seshadri

    发明人： Conor M. Dowling ,  Bin Chen ,  Sri R. Seshadri

    IPC分类号： C08G6302

    CPC分类号： C08G63/85 ,  B01J21/063 ,  B01J31/04 ,  B01J31/2239 ,  B01J31/26 ,  B01J2531/0205 ,  B01J2531/10 ,  B01J2531/20 ,  B01J2531/46 ,  B01J2531/52 ,  C08G63/82 ,  C08G63/83 ,  C08G63/84 ,  C08G63/87

    摘要： The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium or potassium titanyl oxalate, Li2 or K2TiO(C2O4)2, lithium or potassium oxalate, Li2 or K2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.

    摘要翻译： 本发明基于以下发现，即草酸钛酸酯可以增强草酸氧钛催化剂的催化功能。 本发明提供一种含有草酸氧钛催化剂和金属草酸盐催化剂增强剂并任选地含有金属助催化剂如锑基催化剂的新型催化组合物。 在草酸氧钛催化剂和催化剂增强剂之间已经发现协同关系。 在草酸氧钛催化剂，催化剂增强剂和金属助催化剂如氧化锑或三乙酸锑之间也发现了协同关系。 还提供了通过在催化有效量的缩聚催化剂存在下，通过聚酯形成反应物的缩聚来生产聚酯的改进方法，其中改进包括利用含有草酸氧钛的新型催化剂组合物作为缩聚催化剂， 草酸氧钛酸锂和催化剂增强剂如非钛酸金属草酸盐如草酸锂，并任选地含有金属催化剂如氧化锑或三乙酸锑。 改进的方法产生具有较低乙醛数和良好颜色的改进的聚酯。 草酸氧钛/催化剂增强剂组合物可以与其它催化剂组合用作缩聚催化剂以实现协同催化活性。 优选的是草酸锂或钾钛酸盐，Li 2或K 2 TiO（C 2 O 4）2，草酸锂或钾，Li 2或K 2（C 2 O 4）2与氧化锑或三乙酸锑或三羟基氧化锑的组合。

    Process for preparing a carboxylic ester
    8.
    发明授权
    Process for preparing a carboxylic ester 失效
    羧酸酯的制备方法

    公开(公告)号：US3959352A

    公开(公告)日：1976-05-25

    申请号：US556265

    申请日：1975-03-07

    申请人： Takeru Onoda ,  Keisuke Wada ,  Masayuki Otake

    发明人： Takeru Onoda ,  Keisuke Wada ,  Masayuki Otake

    IPC分类号： B01J21/08 ,  B01J23/644 ,  B01J31/04 ,  B01J31/28 ,  C07C67/055 ,  C07C67/05

    CPC分类号： B01J31/28 ,  B01J23/6445 ,  B01J31/04 ,  B01J31/1616 ,  C07C67/055 ,  B01J21/08 ,  B01J2231/321 ,  B01J2531/52

    摘要： A carboxylic ester is prepared by reacting a hydrocarbon selected from monoolefins having 2 to 6 carbon atoms, benzene, toluene and xylene with an aliphatic saturated carboxylic acid having 2 to 4 carbon atoms and molecular oxygen in the vapor phase in the presence of a supported solid catalyst of palladium metal, an antimony component and a carboxylic acid salt of alkali metal, alkaline earth metal, zinc, cadmium, lead or tin, with the improvement comprising: adding said antimony compound to the support of said catalyst by dipping a carrier into an aqueous solution of a water-soluble antimony compound selected from the group consisting of antimonic acid, antimonates and antimony complexes of organic acids.

    摘要翻译： 羧酸酯是通过使选自具有2至6个碳原子的单烯烃，苯，甲苯和二甲苯的烃与具有2至4个碳原子的脂族饱和羧酸和分子氧在气相中在负载的固体存在下反应来制备的 钯金属的催化剂，锑成分和碱金属，碱土金属，锌，镉，铅或锡的羧酸盐，其改进包括：通过将载体浸渍到所述催化剂的载体中而将所述锑化合物加入到所述催化剂的载体中 水溶性锑化合物的水溶液，其选自由锑酸，锑酸盐和有机酸的锑络合物组成的组。

    Trivalent antimony catalyst
    9.
    发明授权
    Trivalent antimony catalyst 失效
    三价锑催化剂

    公开(公告)号：US3899522A

    公开(公告)日：1975-08-12

    申请号：US39112173

    申请日：1973-08-24

    申请人： NL INDUSTRIES INC

    发明人： LOEFFLER OTTO ERNEST

    IPC分类号： C08G63/00 ,  B01J31/02 ,  B01J31/04 ,  C07F9/90 ,  C08G63/82 ,  C08G63/86

    CPC分类号： B01J31/0212 ,  B01J31/04 ,  B01J31/2234 ,  B01J31/2239 ,  B01J2531/52 ,  C07F9/902 ,  C08G63/866

    摘要： A novel antimony catalyst for polyester condensation reactions is described comprising trivalent antimony having its valences occupied by dianion radicals of 1,2-diols and anion radicals or organic carboxylic acids. The molar ratio of antimony to dianion radical of 1,2-diol to anion radical of organic carboxylic acid is 1:1:1. The antimony compound is prepared by reacting a mixture of a 1,2-diol and a trivalent antimony reactant represented by the formula;

    wherein Sb is antimony, R1 is an anion radical of an organic carboxylic acid; and R2 is selected from the group consisting of anions of alcohols, anions of organic carboxylic acids and mixtures thereof.

    摘要翻译： 描述了一种用于聚酯缩合反应的新型锑催化剂，其包含其价态被1,2-二醇和阴离子基团或有机羧酸的二阴离子占据的三价锑。 1,2-二醇与有机羧酸阴离子自由基的锑与二阴离子自由基的摩尔比为1:1:1。 锑化合物通过使1,2-二醇和由式表示的三价锑反应物的混合物反应来制备; } | R2} Sb--R1} | R2}其中Sb是锑，R1是有机羧酸的阴离子基团; 并且R 2选自醇阴离子，有机羧酸的阴离子及其混合物。

    A NOVEL LIVING RADICAL POLYMERIZATION METHOD
    10.
    发明申请
    A NOVEL LIVING RADICAL POLYMERIZATION METHOD 有权
    一种新型的生物辐射聚合方法

    公开(公告)号：US20070049715A1

    公开(公告)日：2007-03-01

    申请号：US11459370

    申请日：2006-07-24

    申请人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

    发明人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

    IPC分类号： C08F112/02 ,  B01J27/135 ,  B01J27/06 ,  B01J31/00

    CPC分类号： B01J31/122 ,  B01J31/22 ,  B01J2531/42 ,  B01J2531/52 ,  C08F112/08 ,  C08F220/14

    摘要： A highly active and environment-friendly catalyst for use in a living radical polymerization is provided. A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from germanium, tin and antimony, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction under the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as low toxicity of the catalyst, a small amount of the catalyst can be used, high solubility of the catalyst, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than a conventional living radical polymerization method.

    摘要翻译： 提供了用于活性自由基聚合的高活性和环境友好的催化剂。 提供了一种用于活性自由基聚合方法的催化剂。 该催化剂包括选自锗，锡和锑的中心元素和与中心元素结合的至少一个卤素原子。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应，从而可以得到分子量分布窄的聚合物。 本发明具有催化剂毒性低，可使用少量催化剂，催化剂溶解性高，反应条件温和，无着色，无异味（成型品不必要后处理）等优点。 本发明的方法比常规的活性自由基聚合方法更环保且更经济。