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公开(公告)号:US11028212B2
公开(公告)日:2021-06-08
申请号:US16324204
申请日:2017-08-01
Applicant: SHOWA DENKO K.K.
Inventor: Naoki Sekioka , Yuya Ohguma , Masanao Kamijo , Yoichiro Takenoshita
IPC: C08F279/02 , C08L51/04 , C09J151/04 , C09J111/02
Abstract: Provided is a method for producing a chloroprene graft copolymer latex containing no organic solvent and exhibiting high adhesive strength even for soft polyvinyl chloride. A method for producing a chloroprene graft copolymer latex includes a chloroprene polymerization step of giving a chloroprene polymer latex and a graft copolymerization step of giving a chloroprene graft copolymer latex. The chloroprene polymerization step is a step of subjecting at least chloroprene (A-1) of chloroprene (A-1) and a monomer (A-2) copolymerizable with chloroprene (A-1) to emulsion radical polymerization. The graft copolymerization step is a step of adding, to the chloroprene polymer latex, a (meth)acrylate (B) and an organic peroxide (C) having an octanol/water partition coefficient of −2.0 or more and 3.0 or less to subject the chloroprene polymer to graft copolymerization with the (meth)acrylate (B) at a temperature of 10° C. or more and 40° C. or less.