公开(公告)号：US20030157367A1

公开(公告)日：2003-08-21

申请号：US10290808

申请日：2002-11-08

申请人： SK CORPORATION

发明人： Hong You ,  Dong-Jin Joo ,  Gil-Su Kwak ,  Jong-Wook Kim ,  Soon-Ki Kwon ,  Yun-Hi Kim ,  Dong-Cheol Shin ,  Hyung-Sun Kim ,  Hyun-Cheol Jeong

IPC分类号： H05B033/14 ,  C09K011/06 ,  C08G061/02

CPC分类号： H01L51/0043 ,  C07C17/2635 ,  C07C25/24 ,  C07C45/68 ,  C07C49/784 ,  C08G61/02 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1011 ,  C09K2211/1408 ,  C09K2211/1416 ,  C09K2211/1425 ,  H01L51/0035 ,  H01L51/0038 ,  H01L51/0052 ,  H01L51/5012

摘要： There are provided novel blue light-emitting organic electroluminescent polymers having a main chain consisting of 9,10-diphenylanthracene and vinylene, and electroluminescent devices using the same. With the introduction of substituents which are of high thermal stability and are capable of steric hindrance at the alpha position of the vinyl group, the electroluminescent polymers make it easy to conduct inter- and intra-molecular energy transfer, and the injection and transportation of holes or electrons, as well as restraining null-stacking between polymer chains. Also, the prevention of intermolecular two- and three-dimensional interference by the introduced bulky substituents leads to reduced extinction of excitons, whereby the organic electroluminescent device can emit blue light at high luminous efficiency.

摘要翻译： 提供了具有由9,10-二苯基蒽和亚乙烯基组成的主链的新型蓝色发光有机电致发光聚合物和使用其的电致发光器件。 通过引入具有高热稳定性并且能够在乙烯基的α位置处具有空间位阻的取代基，电致发光聚合物使得易于进行分子间和分子内能量转移，并且孔的注入和输送 或电子，以及限制聚合物链之间的π-堆叠。 此外，通过引入的大体积取代基防止分子间的二维和三维干扰导致激子的消光减少，由此有机电致发光器件可以以高发光效率发射蓝光。