公开(公告)号：US3879483A

公开(公告)日：1975-04-22

申请号：US45480174

申请日：1974-03-26

申请人： SOLVAY

发明人： VANLAUTEM NOEL ,  DONZEL ALAIN

IPC分类号： C07C1/26 ,  B01J23/00 ,  B01J27/00 ,  B01J31/00 ,  C07B61/00 ,  C07C1/00 ,  C07C1/32 ,  C07C13/19 ,  C07C67/00 ,  C07B17/00 ,  C07C3/00

CPC分类号： C07C1/326 ,  C07C2527/128 ,  C07C2531/24 ,  C07C2601/14 ,  C07C13/19

摘要： Vinylcycloalkanes of the formula R-CH CH2 wherein R is a cycloaliphatic radical with 5 or 6 carbon atoms which can be substituted by substituents selected from the group consisting of alkyl groups containing 1 to 6 carbon atoms and saturated chains containing 1 to 6 carbon atoms and a hetero-atom selected from the group consisting of sulfur, oxygen and nitrogen are prepared by reacting vinyl chloride and an organometallic compound of the formula (R)n-M. The radical R of the organometallic compound is defined as above, M is a lithium atom, a cadmium atom or a magnesium-halogen group and n is equal to 1 when M is lithium or the magnesium-halogen group and is equal to 2 when M is cadmium. A catalyst is used which consists of a metal from Group VIII of the Periodic Table or a compound of a metal from Group VIII of the Periodic Table and at least one compound of an element from Groups VA and VIA of the Periodic Table of elements which is complexed with the metal from Group VIII or the compound of a metal from Group VIII.

摘要翻译： 式R-CH = CH 2的乙烯基环烷烃其中R是具有5或6个碳原子的脂环族基团，其可以被选自含有1至6个碳原子的烷基和含有1至6个碳原子的饱和链的取代基取代 并且通过氯乙烯和式（R）nM的有机金属化合物反应制备选自硫，氧和氮的杂原子。 有机金属化合物的基团R如上定义，M为锂原子，镉原子或卤素 - 卤素基团，当M为锂或卤化镁基团时，n为1，当M为 是镉。 使用由元素周期表第VIII族金属或周期表第VIII族金属化合物组成的催化剂，以及元素周期表第VA族和第VA族元素的至少一种元素化合物 与来自VIII族的金属或VIII族金属的化合物络合。