公开(公告)号：US3686295A

公开(公告)日：1972-08-22

申请号：US3686295D

申请日：1970-06-01

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  MILLER ROBERT C

IPC: C07C45/33 ,  C07C45/34 ,  C07C45/36 ,  C07C57/05 ,  C07C51/20 ,  C07C45/02

CPC classification number: C07C45/36 ,  C07C45/33 ,  C07C45/34 ,  C07C253/24 ,  C07C253/28 ,  C07C47/22 ,  C07C255/08 ,  C07C255/34

Abstract: The instant application is related to a process for the oxidation of saturated hydrocarbons and substituted saturated hydrocarbons in a vapor phase reaction over an antimonycontaining oxidation catalyst in which the hydrocarbon in the presence of a minor quantity of an inorganic or organic halide, hydrogen chloride, hydrogen bromide or hydrogen iodide or of a halogen other than fluorine, is reacted with (a) oxygen, to form unsaturated aldehydes and acids or (b) oxygen and ammonia, to form unsaturated nitriles.

Abstract translation: 本申请涉及在含锑氧化催化剂的气相反应中氧化饱和烃和取代饱和烃的方法，其中烃在少量无机或有机卤化物，氯化氢存在下 ，溴化氢或碘化氢或氟以外的卤素与（a）氧反应，形成不饱和醛和酸或（b）氧和氨，形成不饱和腈。