公开(公告)号：US20160251382A1

公开(公告)日：2016-09-01

申请号：US15030897

申请日：2014-10-14

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Alois FÜRSTNER ,  Stephan RUMMELT

IPC: C07F7/22 ,  B01J31/22

CPC classification number: C07F7/2208 ,  B01J31/2295 ,  B01J2231/323 ,  B01J2531/821 ,  C07F15/0046

Abstract: The present invention refers to a process for the ruthenium-catalyzed trans-selective hydrostannation of alkynes and the so-obtained products. The inventive process makes use of a tin hydride which is reacted with an alkyne in the presence of a cyclopentadienyl-coordinated ruthenium catalyst.

Abstract translation: 本发明涉及一种用于钌催化的炔的反式选择性氢化方法和所得产物的方法。 本发明方法利用在环戊二烯基配位钌催化剂存在下与炔反应的氢化锡。