公开(公告)号：US20220088571A1

公开(公告)日：2022-03-24

申请号：US17426391

申请日：2020-01-21

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Amol AMRUTE ,  Ferdi SCHUETH ,  Hannah SCHREYER

IPC: B01J21/04 ,  B01J37/00 ,  C01F7/441 ,  B01J35/10 ,  B01J35/02 ,  B01J37/08

Abstract: The present invention refers to a process for the preparation of a high surface area nanoparticulate alpha alumina.

公开(公告)号：US20220002263A1

公开(公告)日：2022-01-06

申请号：US17291113

申请日：2019-11-05

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Tobias RITTER ,  Florian BERGER

IPC: C07D339/08

Abstract: The present invention refers to a process for direct C—H functionalization, the reagents used in the process and the use thereof for the direct C—H functionalization as well as the so-obtained products.

公开(公告)号：US20210130286A1

公开(公告)日：2021-05-06

申请号：US16491594

申请日：2018-03-04

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Zhong LIAN ,  Bill MORANDI ,  Benjamin N. BHAWAL ,  Peng YU ,  Tristan DELCAILLAU

IPC: C07C319/14 ,  C07C321/28 ,  C07D319/06 ,  C07C323/20 ,  C07F7/18 ,  C07C323/09 ,  C07F7/08 ,  C07C323/36 ,  C07D277/74 ,  C07D213/70 ,  C07D241/18 ,  C07J31/00 ,  C07C321/22 ,  C07D417/06

Abstract: The present invention refers to a process for a catalytic aryl transfer to rearrange the backbone of aromatic C—X bonds.

公开(公告)号：US10597356B2

公开(公告)日：2020-03-24

申请号：US15780424

申请日：2016-11-26

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Bill Morandi ,  Xianjie Fang ,  Peng Yu

IPC: C07C253/30 ,  B01J31/14 ,  B01J31/24 ,  C07D209/86 ,  C07D209/76 ,  B01J27/125 ,  B01J31/22 ,  B01J31/26 ,  C07D209/56 ,  C07F7/08

Abstract: The present invention refers to processes for catalytic reversible alkene-nitrile interconversion through controllable HCN-free transfer hydrocyanation.

公开(公告)号：US20200031777A1

公开(公告)日：2020-01-30

申请号：US15739239

申请日：2016-06-21

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Manuel ALCARAZO ,  Javier PEÑA GONZALEZ ,  Garazi TALAVERA URQUIJO

IPC: C07D233/42

Abstract: The present invention refers to substituted imidazolium sulfuranes, the use thereof for the transfer of a —CN group or an alkyne group.

公开(公告)号：US20180371144A1

公开(公告)日：2018-12-27

申请号：US16065176

申请日：2016-12-20

Applicant: STUDIENGESELLSCHAFT KOHLE MBH ,  HASSELT UNIVERSITY

Inventor： Martin KLUSSMANN ,  Joke VANDENBERGH ,  Thomas JUNKERS ,  Bertrand SCHWEITZER-CHAPUT

IPC: C08F293/00 ,  C08K5/14 ,  C07C409/22 ,  C07C409/40 ,  C07D307/79

Abstract: The present invention refers to a process making use of a radical initiator system comprising peroxy compounds, in particular peroxyketals, in the presence of an acid catalyst to initiate radical processes at low temperature, such as room temperature and below.

公开(公告)号：US09844774B2

公开(公告)日：2017-12-19

申请号：US15300823

申请日：2015-03-24

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Ferdi Schueth ,  Alois Fürstner ,  Feng Wang

IPC: C07C51/00 ,  C08G61/00 ,  B01J31/00 ,  B01J31/06 ,  C07C1/32 ,  C07C45/38 ,  B01J23/44 ,  B01J37/04 ,  B01J37/16 ,  C07C41/30 ,  C07C51/255 ,  C08G61/10

CPC classification number: B01J31/06 ,  B01J23/44 ,  B01J37/04 ,  B01J37/16 ,  B01J2231/4211 ,  C07C1/321 ,  C07C41/30 ,  C07C45/38 ,  C07C51/255 ,  C07C2523/42 ,  C07C2531/02 ,  C07C2531/06 ,  C07C2531/28 ,  C08G61/10 ,  C08G2261/11 ,  C08G2261/312 ,  C08G2261/79 ,  C08G2261/90 ,  C07C15/14 ,  C07C47/54

Abstract: The present invention refers to processes for preparing catalyst loaded polyphenylene particles, the so-obtained polyphenylene particles and their use as catalysts.

公开(公告)号：US20170050180A1

公开(公告)日：2017-02-23

申请号：US15307077

申请日：2015-04-21

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Manuel ALCARAZO ,  Christian WILLE ,  Hendrik TINNERMANN

IPC: B01J31/24 ,  C07C2/66 ,  C07D311/04 ,  C07C67/30 ,  C07F9/58 ,  C07F15/00

CPC classification number: B01J31/2409 ,  B01J31/2404 ,  B01J2231/32 ,  B01J2231/324 ,  B01J2531/18 ,  B01J2531/822 ,  B01J2531/828 ,  C07C2/66 ,  C07C67/30 ,  C07C2531/24 ,  C07D311/04 ,  C07F9/58 ,  C07F15/0073 ,  C07F15/0093

Abstract: The present invention deals with the synthesis and applications of new cationic compounds being useful as metal ligands. Specifically, N-alkyl/aryl substituted pyridiniophosphines are prepared and used as ligands for transition metals. The so-obtained metal complexes and their use as catalysts in chemical synthesis is also described. It also worth mentioning that N-alkyl/aryl pyridiniophosphines can be synthesized through a short, scalable and highly modular route.

Abstract translation: 本发明涉及用作金属配体的新的阳离子化合物的合成和应用。 具体地说，制备N-烷基/芳基取代的吡啶鎓膦并用作过渡金属的配体。 还描述了如此获得的金属络合物及其在化学合成中作为催化剂的用途。 还值得一提的是，N-烷基/芳基吡啶基膦可以通过短的，可扩展的和高度模块化的途径合成。

公开(公告)号：US20160251382A1

公开(公告)日：2016-09-01

申请号：US15030897

申请日：2014-10-14

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Alois FÜRSTNER ,  Stephan RUMMELT

IPC: C07F7/22 ,  B01J31/22

CPC classification number: C07F7/2208 ,  B01J31/2295 ,  B01J2231/323 ,  B01J2531/821 ,  C07F15/0046

Abstract: The present invention refers to a process for the ruthenium-catalyzed trans-selective hydrostannation of alkynes and the so-obtained products. The inventive process makes use of a tin hydride which is reacted with an alkyne in the presence of a cyclopentadienyl-coordinated ruthenium catalyst.

Abstract translation: 本发明涉及一种用于钌催化的炔的反式选择性氢化方法和所得产物的方法。 本发明方法利用在环戊二烯基配位钌催化剂存在下与炔反应的氢化锡。

公开(公告)号：US20140051870A1

公开(公告)日：2014-02-20

申请号：US14000997

申请日：2012-02-23

Applicant: STUDIENGESELLSCHAFT KOHLE MBH

Inventor： Manuel Alcarazo ,  Hans Bruns ,  Jekaterina Petuskova

IPC: C07F9/50 ,  C07D311/94 ,  B01J31/24

CPC classification number: C07F9/5018 ,  B01J31/2404 ,  B01J2231/4211 ,  B01J2231/52 ,  B01J2531/18 ,  B01J2531/822 ,  B01J2531/847 ,  C07D311/94 ,  C07F1/12 ,  C07F9/02 ,  C07F9/50 ,  C07F9/5022 ,  C07F15/00 ,  C07F15/0073 ,  C07F15/0093

Abstract: Phosphenium compounds with the general formula I: in whichR1, R2, R3 and R4 are identical or different and represent a linear or branched C1-C6-alkyl radical, which can optionally be substituted, or R1 and R2 and/or R3 and R4 are bonded to one another with the formation of a ring,R5 and R6 stand for a saturated or unsaturated and linear or branched alkyl group, alkenyl group or aryl group, which can have suitable substituents, even heteroatoms as substituents, or a heteroatom-comprising hydrocarbon group, which can have suitable substituents, and the R5 and R6 radicals can form a ring which can be 4- to 20-membered, saturated or unsaturated and alicyclic or heteroalicyclic and can exhibit suitable substituents, X− represents an anion,a process for the preparation thereof, and also the use of these compounds in metal complexes which can be used as catalysts in organic synthesis, are claimed.

Abstract translation: 具有通式I的磷酸酯化合物，其中R 1，R 2，R 3和R 4相同或不同，表示可任选被取代的直链或支链C 1 -C 6烷基，或R 1和R 2和/或R 3和R 4 形成环，R5和R6表示饱和或不饱和的直链或支链烷基，烯基或芳基，其可以具有合适的取代基，甚至杂原子作为取代基，或含杂原子的 烃基，其可以具有合适的取代基，并且R 5和R 6基团可以形成可以是4-至20-元饱和或不饱和和脂环族或杂脂环的环并且可以表现出合适的取代基，X-表示阴离子， 为了制备它们，还要求使用这些化合物在可用作有机合成中的催化剂的金属络合物中。