公开(公告)号：US3736342A

公开(公告)日：1973-05-29

申请号：US3736342D

申请日：1971-07-27

申请人： SUMITOMO CHEMICAL CO

发明人： ICHIKI E ,  IDA K ,  KOZAI M ,  KONDO Y

IPC分类号： C07C29/72 ,  C07C27/00 ,  C07C29/54 ,  C07C31/32 ,  C07C67/00 ,  C07F5/06

CPC分类号： C07C29/54 ,  C07C31/02 ,  C07C31/12 ,  C07C31/125

摘要： A TRIALKOXYLAUMINUM IS PRODUCED FROM AN ALKYLALUMINUM COMPOUND,

R1-AL(-R2)-R3

WHEREIN R1 AND R2 REPRESENT ALKYL GROUP HAVING 2 TO 30 CARBON ATOMS, AND R3 AN ALKYL OR ALKOXY GROUPS HAVING 2 TO 30 CARBON ATOMS THROUGH OXIDATION BY CONTACTING THE ALKYLALUMINUM COMPOUND WITH A MOLECULAR OXYGEN-CONTAINING GAS IN A STATE OF FILM HAVING A THICKNESS OF NOT MORE THAN 5 MM., PREFERABLY NOT MORE THAN 3 MM., AT -20* TO 150*C., PREFERABLE 0* TO 100*C. UNDER A PRESSURE OF NOT MORE THAN 50 KG./CM.2 ABSOLUTE, PREFERABLE 0.5 TO 40 KG./CM.2 ABSOLUTE.

公开(公告)号：US3720698A

公开(公告)日：1973-03-13

申请号：US3720698D

申请日：1971-06-07

申请人： SUMITOMO CHEMICAL CO

发明人： ICHIKI E ,  IIDA K ,  KOZAI M ,  KONDO Y

IPC分类号： C07C29/72 ,  C07C27/00 ,  C07C29/54 ,  C07C31/32 ,  C07C67/00 ,  C07F5/06

CPC分类号： C07C29/54 ,  C07C31/12 ,  C07C31/125

摘要： WHEREIN R1 REPRESENTS AN ALKYL GROPU HAVING 2-30 CARBON ATOMS AND R2 AND R3 REPRESENT ALKYL GROUPS OR ALKOXY GROUPS HAVING 2-30 CARBON ATOMS THROUGH OXIDATION BY INTRODUCING THE ALKYLALUMINUM COMPOUND DILUTED WITH AT LEAST 600 G. OF A SOLVENT HAVING A BOILING POINT OF -50*150*C. AND BEING SUBSTANTIALLY INERT TO THE ALKYLALUMINUM COMPOUND, PER GRAM EQUIVALENT OF ALKYL GROUPS OF THE ALKYLALUMINM COMPOUND, INTO A MOLECULAR OXYGENCONTAINING GAS UNDER A PARTIAL PRESSURE OF OXYGEN OF AT LEAST 0.1 KG/CM.2 ABSOLTUT AT A TEMPERATURE OF -20-* 150*C., PREFERABLY 0* - 100*C. UNDER A PRESSURE OF NOT MORE THAN 50 KG./CM.2 ABSOLUYE, PREFERABLY 0.5-40 KG./ CM.2 ABSOLUTE IN A FINELY DIVIDED DROPLET STATE THEREBY TO OXIDIZE THE ALKYLALUMINUM COMPOUND.

R1-AL(-R2)-R3

A TRIALKOXYALUMIM IS PRODUCED FROM AN ALKYLALUMINUM COMPOUND,