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公开(公告)号:US20190107636A1
公开(公告)日:2019-04-11
申请号:US16206545
申请日:2018-11-30
IPC分类号: G01T1/202 , C30B15/04 , C30B11/04 , C30B11/02 , C30B11/00 , C09K11/77 , C30B29/12 , C30B15/00
CPC分类号: G01T1/2023 , C09K11/77 , C09K11/7766 , C09K11/7773 , C30B11/00 , C30B11/02 , C30B11/04 , C30B15/00 , C30B15/04 , C30B29/12 , G01T1/20 , G01T1/202
摘要: The present disclosure relates to a process for fabricating a crystalline scintillator material with a structure of elpasolite type of theoretical composition A2BC(1-y)MyX(6-y) wherein: A is chosen from among Cs, Rb, K, Na, B is chosen from among Li, K, Na, C is chosen from among the rare earths, Al, Ga, M is chosen from among the alkaline earths, X is chosen from among F, Cl, Br, I, y representing the atomic fraction of substitution of C by M and being in the range extending from 0 to 0.05, comprising its crystallization by cooling from a melt bath comprising r moles of A and s moles of B, the melt bath in contact with the material containing A and B in such a way that 2s/r is above 1. The process shows an improved fabrication yield. Moreover, the crystals obtained can have compositions closer to stoichiometry and have improved scintillation properties.
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公开(公告)号:US20160103232A1
公开(公告)日:2016-04-14
申请号:US14879650
申请日:2015-10-09
CPC分类号: G01T1/2023 , C09K11/7766 , C09K11/7773 , C30B11/00 , C30B11/02 , C30B11/04 , C30B15/00 , C30B15/04 , C30B29/12
摘要: The present disclosure relates to a process for fabricating a crystalline scintillator material with a structure of elpasolite type of theoretical composition A2BC(1-y)MyX(6-y) wherein A is chosen from among Cs, Rb, K, Na, B is chosen from among Li, K, Na, C is chosen from among the rare earths, Al, Ga, M is chosen from among the alkaline earths, X is chosen from among F, Cl, Br, I, y representing the atomic fraction of substitution of C by M and being in the range extending from 0 to 0.05, comprising its crystallization by cooling from a melt bath comprising r moles of A and s moles of B, the melt bath in contact with the material containing A and B in such a way that 2s/r is above 1. The process shows an improved fabrication yield. Moreover, the crystals obtained can have compositions closer to stoichiometry and have improved scintillation properties.
摘要翻译: 本公开内容涉及一种制备具有理论组成的堇青石型理论组合物A2BC(1-y)MyX(6-y)的结晶闪烁体材料的方法,其中A选自Cs,Rb,K,Na,B为 选自Li,K,Na,C中的稀土,Al,Ga,M选自碱土金属,X选自F,Cl,Br,I,y,代表 将C取代为M并且在0至0.05的范围内,包括通过从包含r摩尔A摩尔和S摩尔的B的熔融浴冷却而结晶,熔融浴与含有A和B的材料接触 2s / r大于1的方法。该方法显示出改进的制造产量。 此外,获得的晶体可以具有更接近化学计量的组成并且具有改善的闪烁性质。
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公开(公告)号:US20170139059A1
公开(公告)日:2017-05-18
申请号:US15418396
申请日:2017-01-27
CPC分类号: G01T1/2023 , C09K11/7766 , C09K11/7773 , C30B11/00 , C30B11/02 , C30B11/04 , C30B15/00 , C30B15/04 , C30B29/12
摘要: The present disclosure relates to a process for fabricating a crystalline scintillator material with a structure of elpasolite type of theoretical composition A2BC(1-y)MyX(6-y) wherein: A is chosen from among Cs, Rb, K, Na, B is chosen from among Li, K, Na, C is chosen from among the rare earths, Al, Ga, M is chosen from among the alkaline earths, X is chosen from among F, Cl, Br, I, y representing the atomic fraction of substitution of C by M and being in the range extending from 0 to 0.05, comprising its crystallization by cooling from a melt bath comprising r moles of A and s moles of B, the melt bath in contact with the material containing A and B in such a way that 2s/r is above 1. The process shows an improved fabrication yield. Moreover, the crystals obtained can have compositions closer to stoichiometry and have improved scintillation properties.
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公开(公告)号:US20180246230A1
公开(公告)日:2018-08-30
申请号:US15960061
申请日:2018-04-23
CPC分类号: G01T1/2023 , C09K11/7766 , C09K11/7773 , C30B11/00 , C30B11/02 , C30B11/04 , C30B15/00 , C30B15/04 , C30B29/12
摘要: The present disclosure relates to a process for fabricating a crystalline scintillator material with a structure of elpasolite type of theoretical composition A2BC(1-y)MyX(6-y) wherein: A is chosen from among Cs, Rb, K, Na, B is chosen from among Li, K, Na, C is chosen from among the rare earths, Al, Ga, M is chosen from among the alkaline earths, X is chosen from among F, Cl, Br, I, y representing the atomic fraction of substitution of C by M and being in the range extending from 0 to 0.05, comprising its crystallization by cooling from a melt bath comprising r moles of A and s moles of B, the melt bath in contact with the material containing A and B in such a way that 2s/r is above 1. The process shows an improved fabrication yield. Moreover, the crystals obtained can have compositions closer to stoichiometry and have improved scintillation properties.
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