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1.发明授权
公开(公告)号：US5955396A
公开(公告)日：1999-09-21
申请号：US682397
申请日：1996-07-17
申请人： Sam S. Lee , Mary K. Trost , Steven A. Cohen
发明人： Sam S. Lee , Mary K. Trost , Steven A. Cohen
CPC分类号： C08F10/00
摘要： A solid, hydrocarbon-insoluble, olefin-polymerization catalyst component having substantially uniform particles useful in polymerizing olefins is formed by:reacting a magnesium-containing compound with carbon dioxide or sulfur dioxide;forming a two-phase mixture of the resulting magnesium-containing compound with a suitable liquid hydrocarbon-miscible phase and a suitable polar solvent phase;forming particles by adding the two-phase mixture after vigorous agitation to a liquid hydrocarbon; andcontacting the formed particles at least once with a transition metal halide in the presence of an electron donor.
摘要翻译： 通过使含镁化合物与二氧化碳或二氧化硫反应形成具有用于聚合烯烃的基本上均匀的颗粒的固体，不溶于烃的烯烃聚合催化剂组分; 形成所得含镁化合物与合适的液体烃混溶相和合适的极性溶剂相的两相混合物; 通过在剧烈搅拌后将两相混合物加入到液体烃中形成颗粒; 并在电子给体的存在下使形成的颗粒与过渡金属卤化物接触至少一次。
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公开(公告)号：US4946816A
公开(公告)日：1990-08-07
申请号：US395990
申请日：1989-08-21
申请人： Steven A. Cohen , Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee
发明人： Steven A. Cohen , Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee
CPC分类号： C08F10/00 , Y10S526/903
摘要： In a solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprising the product formed by (A) forming a solution of a magnesium-containing species from a magnesium alkyl (or hydrocarbyl) carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing toluene-based solvent by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic either; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor, the morphology of such component is modified by incorporating a morphology-affecting amount of C.sub.8 -C.sub.10 aromatics within the toluene-based solvent in Step B, Step A, in Step C prior to addition of ether, or combinations thereof.
摘要翻译： 在具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分中，包括通过（A）由碳酸烷基（或烃基）或镁的镁形成镁的物质溶液形成的产物 羧酸酯; （B）用过渡金属卤化物和有机硅烷处理从这种含镁甲苯系溶剂中析出固体颗粒; （C）从含有环状的混合物中再沉淀此类固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒，通过在步骤B，步骤A中在甲苯系溶剂中引入形态影响量的C 8 -C 10芳族化合物来修饰这些组分的形态， 在步骤C中加入醚之前，或其组合。
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公开(公告)号：US5223466A
公开(公告)日：1993-06-29
申请号：US855598
申请日：1992-03-20
申请人： Sam S. Lee , Nicholas M. Karayannis
发明人： Sam S. Lee , Nicholas M. Karayannis
CPC分类号： C08F10/00 , Y10S526/903
摘要： A process for making a magnesium-containing supported titanium-containing, alpha-olefin polymerization or co-polymerization catalyst or catalyst component having a large particle size, semi-spherical particle shape and high resistance to attrition.
摘要翻译： 一种制备含有镁的负载钛，α-烯烃聚合或共聚催化剂或具有大颗粒尺寸，半球形颗粒形状和高耐磨性的催化剂组分的方法。
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4.发明授权Activation of complexed reduced titanium halide olefin polymerization catalyst with haloalkylchlorosilanes 失效用卤代烷基氯硅烷活化复合的还原卤化钛烯烃聚合催化剂
公开(公告)号：US4422956A
公开(公告)日：1983-12-27
申请号：US378405
申请日：1982-05-14
CPC分类号： C08F10/00
摘要： A titanium-containing olefin polymerization catalyst component comprises a titanium-containing component formed by reducing titanium tetrachloride with an organoaluminum compound, optionally contacting the resulting reduced solid with a pretreatment amount of alpha-olefin monomer under polymerization conditions, and reacting the resulting product with a Lewis base complexing agent and a haloalkylchlorosilane.
摘要翻译： 含钛烯烃聚合催化剂组分包括通过用有机铝化合物还原四氯化钛形成的含钛组分，任选地在聚合条件下使所得还原固体与预处理量的α-烯烃单体接触，并将所得产物与 路易斯碱络合剂和卤代烷基氯硅烷。
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公开(公告)号：US4988656A
公开(公告)日：1991-01-29
申请号：US351408
申请日：1989-05-12
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonte or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括通过（A）由镁碳酸镁或羧酸镁形成含镁物质的溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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公开(公告)号：US4256866A
公开(公告)日：1981-03-17
申请号：US696811
申请日：1976-06-16
申请人： Nicholas M. Karayannis , Sam S. Lee
发明人： Nicholas M. Karayannis , Sam S. Lee
摘要： In an alpha-olefin polymerization process using a transition metal halide-aluminum alkyl catalyst system, addition of minor, effective amounts of a sterically hindered 5- or 6-membered cyclic ether decreases the amount of low molecular weight or amorphous polymer produced.
摘要翻译： 在使用过渡金属卤化物 - 铝烷基催化剂体系的α-烯烃聚合方法中，加入少量有效量的空间位阻的5-或6-元环醚降低了低分子量或无定形聚合物的产生量。
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公开(公告)号：US4189556A
公开(公告)日：1980-02-19
申请号：US696813
申请日：1976-06-16
申请人： Nicholas M. Karayannis , Sam S. Lee
发明人： Nicholas M. Karayannis , Sam S. Lee
CPC分类号： C08F10/00
摘要： In an alpha-olefin polymerization process using a transition metal halide-aluminum alkyl catalyst system, addition of minor, effective amounts of aromatic amines or amine N-oxides substituted with electron withdrawing groups decreases the amount of low molecular weight or amorphous polymer produced.
摘要翻译： 在使用过渡金属卤化物 - 铝烷基催化剂体系的α-烯烃聚合方法中，加入少量有效量的由吸电子基团取代的芳族胺或胺N-氧化物减少了低分子量或无定形聚合物的产生量。
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公开(公告)号：US4866022A
公开(公告)日：1989-09-12
申请号：US186359
申请日：1988-04-25
申请人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
发明人： Gregory G. Arzoumanidis , Nicholas M. Karayannis , Habet M. Khelghatian , Sam S. Lee , Bryce V. Johnson
CPC分类号： C08F10/00
摘要： A solid hydrocarbon-insoluble, alpha-olefin polymerization catalyst component with superior activity, stereospecificity and morphology characteristics comprises the product formed by (A) forming a solution of a magnesium-containing species from a magnesium carbonate or a magnesium carboxylate; (B) precipitating solid particles from such magnesium-containing solution by treatment with a transition metal halide and an organosilane; (C) reprecipitating such solid particles from a mixture containing a cyclic ether; and (D) treating the reprecipitated particles with a transition metal compound and an electron donor.
摘要翻译： 具有优异活性，立体定向性和形态特征的固体烃不溶性α-烯烃聚合催化剂组分包括由（A）形成镁酸盐或羧酸镁的含镁物质溶液形成的产物; （B）用过渡金属卤化物和有机硅烷处理从这种含镁溶液中沉淀固体颗粒; （C）从含有环醚的混合物中再沉淀这样的固体颗粒; 和（D）用过渡金属化合物和电子给体处理再沉淀的颗粒。
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公开(公告)号：US4317898A
公开(公告)日：1982-03-02
申请号：US223476
申请日：1981-01-08
申请人： Nicholas M. Karayannis , Sam S. Lee
发明人： Nicholas M. Karayannis , Sam S. Lee
IPC分类号： C08F10/06 , C08F297/08 , C08F4/64
CPC分类号： C08F297/08 , C08F10/06
摘要： A novel catalyst and process for producing highly-crystalline polypropylene or pure block or terminal block types of copolymers of propylene and ethylene or propylene and another alpha-olefin in excellent yields which coproduce minor amounts of low-molecular-weight and, particularly, amorphous polymers. The catalyst comprises an aluminum alkyl compound, titanium trichloride, a sterically-hindered cyclic amine and an organotin sulfide. This novel catalyst and process are useful in polymerization techniques which use a polymerization medium or those in which the condensed monomer is polymerized from the liquid phase or those in which polymerization is accomplished from monomer substantially in the vapor phase.
摘要翻译： 用于以优异的产率生产高结晶聚丙烯或纯嵌段或末端嵌段类型的丙烯和乙烯或丙烯与另一种α-烯烃的共聚物的新型催化剂和方法，其共同产生少量的低分子量，特别是无定形聚合物 。 该催化剂包括烷基铝化合物，三氯化钛，空间位阻环胺和有机锡硫化物。 该新型催化剂和方法可用于使用聚合介质的聚合技术或其中缩合单体从液相聚合的聚合技术或其中基本上在气相中由单体完成聚合反应的聚合技术。
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公开(公告)号：US5124297A
公开(公告)日：1992-06-23
申请号：US624210
申请日：1990-12-07
CPC分类号： C08F10/00
摘要： A catalyst or catalyst component for the polymerization of copolymerization of alpha-olefins, which is formed by a process comprising forming a solution of a magnesium-containing species in a liquid comprising at least one alcohol.
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