公开(公告)号：US06395913B1

公开(公告)日：2002-05-28

申请号：US09910359

申请日：2001-07-20

申请人： Scott Donald Barnicki ,  Jerome Leonard Stavinoha, Jr. ,  Robert Sterling Kline ,  Jackie Lee Hamilton

发明人： Scott Donald Barnicki ,  Jerome Leonard Stavinoha, Jr. ,  Robert Sterling Kline ,  Jackie Lee Hamilton

IPC分类号： C07D30132

CPC分类号： C07D301/32 ,  C07D301/10

摘要： Disclosed is a method of recovering and purifying 3,4-epoxy-1-butene (epoxybutene) from a reaction product gas, obtained by the vapor phase catalytic partial oxidation of 1,3-butadiene with oxygen over a silver catalyst. The recovery and purification comprises absorption of the epoxybutene into a water-miscible solvent followed by separation of the absorbed epoxybutene from the absorbent by extraction into a water-immiscible solvent. A method of recovering and purifying epoxybutene from the extraction solvent and other reaction by-products by a novel combination of distillation and decantation steps also is disclosed.

摘要翻译： 公开了一种通过在银催化剂上用氧气气相催化部分氧化1,3-丁二烯而获得的反应产物气体中3,4-环氧-1-丁烯（环氧丁烯）的回收和纯化方法。 回收和纯化包括将环氧丁烯吸收到水混溶性溶剂中，然后通过萃取与水不混溶的溶剂将吸收的环氧丁烯从吸收剂中分离出来。 公开了一种通过蒸馏和倾析步骤的新组合从提取溶剂和其它反应副产物中回收和纯化环氧丁烯的方法。

公开(公告)号：US06596882B2

公开(公告)日：2003-07-22

申请号：US09910332

申请日：2001-07-20

申请人： Scott Donald Barnicki ,  Jerome Leonard Stavinoha, Jr. ,  Robert Sterling Kline ,  Steven Edward Briley ,  Jackie Lee Hamilton

发明人： Scott Donald Barnicki ,  Jerome Leonard Stavinoha, Jr. ,  Robert Sterling Kline ,  Steven Edward Briley ,  Jackie Lee Hamilton

IPC分类号： C07D30132

CPC分类号： C07D301/32

摘要： Disclosed is a method of recovering and purifying 3,4-epoxy-1-butene (epoxybutene) from an epoxidation effluent gas obtained by the vapor phase, catalytic, partial oxidation of 1,3-butadiene (butadiene) with molecular oxygen in the presence of a silver catalyst wherein the epoxybutene-laden epoxidation product gas is reacted with a water-miscible solvent to absorb the epoxybutene. The disclosed process includes a method of separating epoxybutene from the solvent and other reaction by-products by a novel combination of distillation and decantation steps.

公开(公告)号：US06500970B1

公开(公告)日：2002-12-31

申请号：US09910330

申请日：2001-07-20

申请人： Scott Donald Barnicki ,  Jerome Leonard Stavinoha, Jr. ,  Robert Sterling Kline ,  Jackie Lee Hamilton

发明人： Scott Donald Barnicki ,  Jerome Leonard Stavinoha, Jr. ,  Robert Sterling Kline ,  Jackie Lee Hamilton

IPC分类号： C07D30132

CPC分类号： C07D301/32

摘要： Disclosed is a process of recovering 3,4-epoxy-1-butene (epoxybutene) from an epoxybutene-laden reaction product gas by absorption into a high-boiling solvent. Also disclosed is a process for the purification of the epoxybutene by separating epoxybutene from the solvent and other reaction by-products by a novel combination of distillation and decantation steps.

摘要翻译： 公开了通过吸收到高沸点溶剂中从含环氧丁烯的反应产物气中回收3,4-环氧-1-丁烯（环氧丁烯）的方法。 还公开了通过蒸馏和倾析步骤的新组合从溶剂和其它反应副产物中分离环氧丁烯来纯化环氧丁烯的方法。