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1.发明申请公开(公告)号：US20130261328A1
公开(公告)日：2013-10-03
申请号：US13431369
申请日：2012-03-27
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C67/58 , C07C51/09 , C07C51/493 , C07C67/00 , C07C67/36 , C07C59/06 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a homogeneous acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the carboxylic acid is readily removed from the glycolic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在均相酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，羧酸容易从乙醇酸中除去，羧酸被再循环。
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2.发明授权公开(公告)号：US08765999B2
公开(公告)日：2014-07-01
申请号：US13431369
申请日：2012-03-27
IPC分类号： C07C51/10
CPC分类号： C07C67/58 , C07C51/09 , C07C51/493 , C07C67/00 , C07C67/36 , C07C59/06 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a homogeneous acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the carboxylic acid is readily removed from the glycolic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在均相酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，羧酸容易从乙醇酸中除去，羧酸被再循环。
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3.发明申请HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF PROPIONIC ACID AND A HETEROGENEOUS CATALYST 有权在丙酸和异构催化剂存在下亚甲基二苯甲酸酯的甲基化公开(公告)号：US20130261337A1
公开(公告)日：2013-10-03
申请号：US13431386
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/347
CPC分类号： C07C51/09 , C07C67/00 , C07C67/36 , C07C59/06 , C07C53/122 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a solid acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the propionic acid stream is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中丙酸流容易从乙醇酸中除去，丙酸被再循环。
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4.发明授权公开(公告)号：US08829234B2
公开(公告)日：2014-09-09
申请号：US13431358
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/10 , C07C59/00 , C07C51/42 , C07C51/12 , C07C51/09 , C07C67/58 , C07C51/48 , C07C51/493 , C07C67/36
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C51/48 , C07C51/493 , C07C67/08 , C07C67/36 , C07C67/58 , Y02P20/52 , C07C59/06 , C07C31/202 , C07C69/675 , C07C69/67
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a solid acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the glycolic acid stream is readily removed from the carboxylic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中乙醇酸流容易地从羧酸中除去并且羧酸被再循环。
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5.发明申请HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF A PROPIONIC ACID AND A HOMOGENEOUS CATALYST 有权丙酸与均相催化剂存在下亚甲基二苯甲酸的烷基化反应公开(公告)号：US20130261329A1
公开(公告)日：2013-10-03
申请号：US13431402
申请日：2012-03-27
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled
摘要翻译： 公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均相酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环
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6.发明申请公开(公告)号：US20130331605A1
公开(公告)日：2013-12-12
申请号：US13491954
申请日：2012-06-08
申请人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
发明人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
CPC分类号： C07C51/12 , C07C29/149 , C07C59/06 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of aqueous formaldehyde. The water in the hydrocarboxylation zone is reduced via reaction with the ester bonds in a recycle stream comprising glycolic acid oligomers and/or methyl glycolate oligomers.
摘要翻译： 公开了通过甲醛水解羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 在包含乙醇酸低聚物和/或乙醇酸甲酯低聚物的再循环料流中，通过与酯键的反应来还原加氢羧化区中的水。
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7.发明授权公开(公告)号：US09040748B2
公开(公告)日：2015-05-26
申请号：US13491954
申请日：2012-06-08
申请人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
发明人： Mesfin Ejerssa Janka , Scott Donald Barnicki , Robert Thomas Hembre , Kelley Margaret Moran , Stephen Neal Falling
IPC分类号： C07C51/12 , C07C27/04 , C07C29/149
CPC分类号： C07C51/12 , C07C29/149 , C07C59/06 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of aqueous formaldehyde. The water in the hydrocarboxylation zone is reduced via reaction with the ester bonds in a recycle stream comprising glycolic acid oligomers and/or methyl glycolate oligomers.
摘要翻译： 公开了通过甲醛水解羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 在包含乙醇酸低聚物和/或乙醇酸甲酯低聚物的再循环料流中，通过与酯键的反应来还原加氢羧化区中的水。
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8.发明授权Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst 有权在丙酸和均相催化剂存在下，将二丙酸亚丙基酯加氢羧化公开(公告)号：US08927766B2
公开(公告)日：2015-01-06
申请号：US13431402
申请日：2012-03-27
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译： 公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均匀的酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环。
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9.发明授权Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst 有权在丙酸和非均相催化剂存在下，二丙酸亚丙基酯的加氢羧化作用公开(公告)号：US08703999B2
公开(公告)日：2014-04-22
申请号：US13431386
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/42
CPC分类号： C07C51/09 , C07C67/00 , C07C67/36 , C07C59/06 , C07C53/122 , C07C69/675 , C07C69/24
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a solid acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the propionic acid stream is readily removed from the glycolic acid and the propionic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中丙酸流容易从乙醇酸中除去，丙酸被再循环。
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10.发明申请公开(公告)号：US20130261333A1
公开(公告)日：2013-10-03
申请号：US13431358
申请日：2012-03-27
申请人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
发明人： Scott Donald Barnicki , Robert Thomas Hembre , Stephen Neal Falling , Mesfin Ejerssa Janka , Kelley Margaret Moran
IPC分类号： C07C51/12
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C51/48 , C07C51/493 , C07C67/08 , C07C67/36 , C07C67/58 , Y02P20/52 , C07C59/06 , C07C31/202 , C07C69/675 , C07C69/67
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of formaldehyde in the presence of a solid acid catalyst and a carboxylic acid. This invention discloses hydrocarboxylations and corresponding glycolic acid separations wherein the glycolic acid stream is readily removed from the carboxylic acid and the carboxylic acid is recycled.
摘要翻译： 公开了一种在固体酸催化剂和羧酸存在下通过甲醛羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的乙醇酸分离，其中乙醇酸流容易地从羧酸中除去并且羧酸被再循环。
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