公开(公告)号：US08968920B2

公开(公告)日：2015-03-03

申请号：US11848919

申请日：2007-08-31

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim ,  Nina K. Gusarova

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim ,  Nina K. Gusarova

IPC分类号： H01M6/16 ,  H01M10/0567 ,  C07F7/04 ,  H01M10/0525

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/0525 ,  H01M2220/30 ,  Y02E60/122

摘要： Organic electrolyte solutions and lithium batteries employing the same are provided. In one embodiment, an organic electrolyte solution includes a silane compound. The inventive organic electrolyte solutions prevent crack formation caused by volumetric changes in the anode active material during charging/discharging of the battery. This improves charge/discharge characteristics, resulting in improved battery stability, reliability, and charge/discharge efficiency, which is a dramatic improvement over conventional organic electrolyte solutions, which have higher irreversible capacities due to the decomposition of polar solvents.

摘要翻译： 提供有机电解质溶液和使用其的锂电池。 在一个实施方案中，有机电解质溶液包括硅烷化合物。 本发明的有机电解质溶液防止在电池充电/放电期间负极活性材料的体积变化引起的裂纹形成。 这提高了充电/放电特性，从而提高了电池稳定性，可靠性和充电/放电效率，这是由于极性溶剂的分解而具有更高不可逆容量的常规有机电解质溶液的显着改进。

公开(公告)号：US20080063937A1

公开(公告)日：2008-03-13

申请号：US11848919

申请日：2007-08-31

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim ,  Nina K. Gusarova

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim ,  Nina K. Gusarova

IPC分类号： H01M6/16 ,  C07F7/04 ,  C07F7/07

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/0525 ,  H01M2220/30 ,  Y02E60/122

摘要： Organic electrolyte solutions and lithium batteries employing the same are provided. In one embodiment, an organic electrolyte solution includes a silane compound. The inventive organic electrolyte solutions prevent crack formation caused by volumetric changes in the anode active material during charging/discharging of the battery. This improves charge/discharge characteristics, resulting in improved battery stability, reliability, and charge/discharge efficiency, which is a dramatic improvement over conventional organic electrolyte solutions, which have higher irreversible capacities due to the decomposition of polar solvents.

摘要翻译： 提供有机电解质溶液和使用其的锂电池。 在一个实施方案中，有机电解质溶液包括硅烷化合物。 本发明的有机电解质溶液防止在电池充电/放电期间负极活性材料的体积变化引起的裂纹形成。 这提高了充电/放电特性，从而提高了电池稳定性，可靠性和充电/放电效率，这是由于极性溶剂的分解而具有更高不可逆容量的常规有机电解质溶液的显着改进。

公开(公告)号：US07678505B2

公开(公告)日：2010-03-16

申请号：US11453641

申请日：2006-06-14

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0025

摘要： An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an additive comprising a crotonate derivative including a substituted silyl group. The organic electrolytic solution and the lithium battery employing such an electrolytic solution suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.

摘要翻译： 提供有机电解液和使用其的锂电池。 有机电解液包括：锂盐; 含有高介电常数溶剂和低沸点溶剂的有机溶剂; 和含有取代甲硅烷基的巴豆酸酯衍生物的添加剂。 使用这种电解液的有机电解液和锂电池抑制极性溶剂的还原分解，并且在第一循环中降低不可逆容量。 因此，可以提高电池的充电/放电效率，寿命和可靠性。

公开(公告)号：US08048573B2

公开(公告)日：2011-11-01

申请号：US11653658

申请日：2007-01-12

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

IPC分类号： H01M6/16

CPC分类号： H01M10/0567 ,  H01M4/133 ,  H01M4/134 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569

摘要： Organic electrolytic solutions and lithium batteries using the organic electrolytic solutions are provided. One organic electrolytic solution includes a lithium salt, a mixed organic solvent consisting of a high-dielectric constant solvent and a low-boiling point solvent, and a compound represented by Formula 1 or 2 as an additive. The organic electrolytic solution and the lithium battery using the organic electrolytic solution may inhibit the reductive cleavage reaction of a polar solvent, thereby increasing capacity retention of the battery, and improving charge-discharge efficiency and battery lifetime.

摘要翻译： 提供有机电解液和使用有机电解液的锂电池。 一种有机电解液包括锂盐，由高介电常数溶剂和低沸点溶剂组成的混合有机溶剂，以及由式1或2表示的化合物作为添加剂。 有机电解液和使用有机电解液的锂电池可以抑制极性溶剂的还原性裂解反应，从而增加电池的容量保持性，并且提高充放电效率和电池寿命。

公开(公告)号：US07781105B2

公开(公告)日：2010-08-24

申请号：US11451716

申请日：2006-06-12

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

IPC分类号： H01M6/16

CPC分类号： H01M10/4235 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025

摘要： An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an acetate derivative including two or more substituted silyl groups as an additive. The organic electrolytic solution and the lithium battery employing the same relatively suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.

摘要翻译： 提供有机电解液和使用其的锂电池。 有机电解液包括：锂盐; 含有高介电常数溶剂和低沸点溶剂的有机溶剂; 和含有2个以上取代甲硅烷基的乙酸酯衍生物作为添加剂。 有机电解液和使用该有机电解液的锂电池相对抑制极性溶剂的还原分解并降低第一循环中的不可逆容量。 因此，可以提高电池的充电/放电效率，寿命和可靠性。

公开(公告)号：US20060281010A1

公开(公告)日：2006-12-14

申请号：US11451716

申请日：2006-06-12

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

IPC分类号： H01M10/40

CPC分类号： H01M10/4235 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025

摘要： An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an acetate derivative including two or more substituted silyl groups as an additive. The organic electrolytic solution and the lithium battery employing the same relatively suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.

摘要翻译： 提供有机电解液和使用其的锂电池。 有机电解液包括：锂盐; 含有高介电常数溶剂和低沸点溶剂的有机溶剂; 和含有2个以上取代甲硅烷基的乙酸酯衍生物作为添加剂。 有机电解液和使用该有机电解液的锂电池相对抑制极性溶剂的还原分解并降低第一循环中的不可逆容量。 因此，可以提高电池的充电/放电效率，寿命和可靠性。

公开(公告)号：US20060292451A1

公开(公告)日：2006-12-28

申请号：US11472664

申请日：2006-06-21

申请人： Seok-soo Lee ,  Han-su Kim ,  Young-gyoon Ryu ,  Boris Trofimov ,  Galing Myachina

发明人： Seok-soo Lee ,  Han-su Kim ,  Young-gyoon Ryu ,  Boris Trofimov ,  Galing Myachina

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0025 ,  H01M2300/0091

摘要： An organic electrolytic solution includes a lithium salt; an organic solvent including a high dielectric constant solvent and a low boiling point solvent; and an additive of a hetero ring compound including a cyano group and an alkenyl group as substituents. The organic electrolytic solution and the lithium battery employing the organic electrolytic solution suppress the reduction decomposition of a polar solvent to improve the capacity retention ratio of the battery. Thus, the charge/discharge efficiency and lifespan of the battery can be improved.

公开(公告)号：US20060281011A1

公开(公告)日：2006-12-14

申请号：US11453641

申请日：2006-06-14

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0025

摘要： An organic electrolytic solution and a lithium battery employing the same are provided. The organic electrolytic solution includes: a lithium salt; an organic solvent containing a high dielectric constant solvent and a low boiling point solvent; and an additive comprising a crotonate derivative including a substituted silyl group. The organic electrolytic solution and the lithium battery employing such an electrolytic solution suppress a reduction decomposition of a polar solvent and decrease irreversible capacity in the first cycle. Thus, the charge/discharge efficiency, lifespan, and reliability of the battery can be improved.

摘要翻译： 提供有机电解液和使用其的锂电池。 有机电解液包括：锂盐; 含有高介电常数溶剂和低沸点溶剂的有机溶剂; 和含有取代甲硅烷基的巴豆酸酯衍生物的添加剂。 使用这种电解液的有机电解液和锂电池抑制极性溶剂的还原分解，并且在第一循环中降低不可逆容量。 因此，可以提高电池的充电/放电效率，寿命和可靠性。

公开(公告)号：US07579118B2

公开(公告)日：2009-08-25

申请号：US11472664

申请日：2006-06-21

申请人： Seok-soo Lee ,  Han-su Kim ,  Young-gyoon Ryu ,  Boris Trofimov ,  Galing Myachina

发明人： Seok-soo Lee ,  Han-su Kim ,  Young-gyoon Ryu ,  Boris Trofimov ,  Galing Myachina

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M10/052 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0025 ,  H01M2300/0091

摘要： An organic electrolytic solution includes a lithium salt; an organic solvent including a high dielectric constant solvent and a low boiling point solvent; and an additive of a hetero ring compound including a cyano group and an alkenyl group as substituents. The organic electrolytic solution and the lithium battery employing the organic electrolytic solution suppress the reduction decomposition of a polar solvent to improve the capacity retention ratio of the battery. Thus, the charge/discharge efficiency and lifespan of the battery can be improved.

摘要翻译： 有机电解液包括锂盐; 包括高介电常数溶剂和低沸点溶剂的有机溶剂; 以及包含氰基和烯基作为取代基的杂环化合物的添加剂。 有机电解液和使用有机电解液的锂电池抑制极性溶剂的还原分解，提高电池的容量保持率。 因此，能够提高电池的充放电效率和寿命。

公开(公告)号：US20070275306A1

公开(公告)日：2007-11-29

申请号：US11653658

申请日：2007-01-12

申请人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

发明人： Seok-soo Lee ,  Young-gyoon Ryu ,  Han-su Kim

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M4/133 ,  H01M4/134 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569

摘要： Organic electrolytic solutions and lithium batteries using the organic electrolytic solutions are provided. One organic electrolytic solution includes a lithium salt, a mixed organic solvent consisting of a high-dielectric constant solvent and a low-boiling point solvent, and a compound represented by Formula 1 or 2 as an additive. The organic electrolytic solution and the lithium battery using the organic electrolytic solution may inhibit the reductive cleavage reaction of a polar solvent, thereby increasing capacity retention of the battery, and improving charge-discharge efficiency and battery lifetime.

摘要翻译： 提供有机电解液和使用有机电解液的锂电池。 一种有机电解液包括锂盐，由高介电常数溶剂和低沸点溶剂组成的混合有机溶剂，以及由式1或2表示的化合物作为添加剂。 有机电解液和使用有机电解液的锂电池可以抑制极性溶剂的还原性裂解反应，从而增加电池的容量保持性，并且提高充放电效率和电池寿命。