High speed photothermographic materials containing tellurium compounds and methods of using same
    9.
    发明授权
    High speed photothermographic materials containing tellurium compounds and methods of using same 失效
    含碲化合物的高速光热成像材料及其使用方法

    公开(公告)号:US06699647B2

    公开(公告)日:2004-03-02

    申请号:US09975909

    申请日:2001-10-11

    Abstract: Photothermographic imaging materials having increased photospeed are provided by certain tellurium chemical sensitizers that are added during the formulation of a photothermographic emulsion. These useful chemical sensitizers are represented by the following Structure I or II: Te(L)m(X1)n  (I) Pd(X2)2[Te(R′)2]2  (II) wherein X1 and X2 independently represent halo, OCN, SCN, S(C═S)N(Ra)(Rb), S(C═S)ORa, S(C═S)SRa, S(P═S)(ORa)(ORb)2, S(P═S)(Ra)(Rb), SeCN, TeCN, CN, SRa, ORa, N3, alkyl, aryl, or O(C═O)Ra groups, Ra and Rb are an alkyl, alkenyl, cycloalkyl, heterocycyl, or aryl group, or Ra and Rb taken together can form a 5-, 6- or 7-membered heterocyclic ring, L is a ligand derived from a neutral Lewis base, R′ is an alkyl or aryl group, m is 0, 1, 2, or 4, and n is 2 or 4 provided that when m is 0 or 2, n is 2 or 4, and when m is 1 or 4, n is 2, and further provided that multiple X1, X2, L, Ra, Rb, or R′ groups in the molecule can be the same or different groups.

    Abstract translation: 具有增加的感光速度的光热成像材料由在光热敏成像乳剂的配制过程中加入的某些碲化学增感剂提供。 这些有用的化学增感剂由以下结构I或II表示:其中X 1和X 2独立地表示卤素,OCN,SCN,S(C = S)N(Ra)(Rb),S(C = S(S = S)SRa,S(P = S)(ORa)(ORb)2,S(P = S)(Ra)(Rb),SeCN,TeCN,CN,SRa,ORa,N3 ,烷基,芳基或O(C = O)R a基团,R a和R b是烷基,烯基,环烷基,杂环基或芳基,或者R a和R b可以一起形成5-,6-或7-元 杂环,L为衍生自中性路易斯碱的配体,R'为烷基或芳基,m为0,1,2或4,n为2或4,条件是当m为0或2时,n 是2或4,当m是1或4时,n是2,并且进一步地,分子中多个X 1,X 2,L,R a,R b或R'基团可以相同或 不同群体。

    Photothermographic and photographic elements having a transparent support having antihalation properties and properties for reducing woodgrain
    10.
    发明授权
    Photothermographic and photographic elements having a transparent support having antihalation properties and properties for reducing woodgrain 失效
    具有透明支持物的光热照相和照相元件具有抗卤化性质和降低木纹的性质

    公开(公告)号:US06630283B1

    公开(公告)日:2003-10-07

    申请号:US09656930

    申请日:2000-09-07

    CPC classification number: G03C1/49872 G03C1/815 G03C1/825

    Abstract: A photosensitive element includes a layer of a photosensitive material on a transparent, multilayer, polymeric support having numerous alternating layers of at least two different polymeric materials. The polymeric multilayer support reflects at least 50% of actinic radiation in the range of wavelengths to which the photosensitive material is sensitive. If the polymeric multilayer reflector includes numerous, thin, alternating layers located at the surface of the polymeric support closest to the photosensitive material, the element not only provides increased speed but also provides an antihalation effect. In another aspect, a multilayer reflector is located a distance removed from the photosensitive layer sufficient to reduce any woodgrain that would otherwise occur, while increasing speed.

    Abstract translation: 感光元件包括在透明的多层聚合物载体上的感光材料层,其具有至少两种不同的聚合物材料的多个交替层。 聚合物多层载体反射感光材料敏感的波长范围内的至少50%的光化辐射。 如果聚合物多层反射器包括位于最靠近感光材料的聚合物载体表面的多个薄的交替层,则元件不仅提供增加的速度,而且还提供防晕效应。 在另一方面,多层反射器位于离感光层一定距离处,足以减少否则会发生的任何木纹,同时增加速度。

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