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公开(公告)号：US08101683B2
公开(公告)日：2012-01-24
申请号：US12790269
申请日：2010-05-28
申请人： Shinji Irifune , Tsutomu Nakajima , Kenji Yamamoto
发明人： Shinji Irifune , Tsutomu Nakajima , Kenji Yamamoto
摘要： An addition-curable silicone emulsion that exhibits stable curability even with a small amount of platinum. The curable emulsion composition is composed of an emulsion A and an emulsion B described below which are mixed together at the time of use, wherein the ratio of [number-average particle size of dispersed particles in emulsion A]/[number-average particle size of dispersed particles in emulsion B] is within a range from 0.4 to 2.0. The emulsion A comprises a specific alkenyl group-containing organopolysiloxane, a specific organohydrogenpolysiloxane, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm. The emulsion B comprises a specific alkenyl group-containing organopolysiloxane, a platinum-based complex, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm.
摘要翻译： 即使使用少量铂也显示稳定的固化性的可加成固化的硅氧烷乳液。 可固化乳液组合物由使用时混合在一起的乳液A和下述乳液B组成，其中[乳液A中分散颗粒的数均粒径] / [数均粒径 的分散颗粒在乳液B中]在0.4至2.0的范围内。 乳液A包含特定的含烯基的有机聚硅氧烷，特定的有机氢聚硅氧烷，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。 乳液B包含特定的含烯基的有机聚硅氧烷，铂系配合物，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。
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公开(公告)号：US20100305258A1
公开(公告)日：2010-12-02
申请号：US12790269
申请日：2010-05-28
申请人： Shinji Irifune , Tsutomu Nakajima , Kenji Yamamoto
发明人： Shinji Irifune , Tsutomu Nakajima , Kenji Yamamoto
IPC分类号： C08L83/06
摘要： An addition-curable silicone emulsion that exhibits stable curability even with a small amount of platinum. The curable emulsion composition is composed of an emulsion A and an emulsion B described below which are mixed together at the time of use, wherein the ratio of [number-average particle size of dispersed particles in emulsion A]/[number-average particle size of dispersed particles in emulsion B] is within a range from 0.4 to 2.0. The emulsion A comprises a specific alkenyl group-containing organopolysiloxane, a specific organohydrogenpolysiloxane, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm. The emulsion B comprises a specific alkenyl group-containing organopolysiloxane, a platinum-based complex, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm.
摘要翻译： 即使使用少量铂也显示稳定的固化性的可加成固化的硅氧烷乳液。 可固化乳液组合物由使用时混合在一起的乳液A和下述乳液B组成，其中[乳液A中分散颗粒的数均粒径] / [数均粒径 的分散颗粒在乳液B中]在0.4至2.0的范围内。 乳液A包含特定的含烯基的有机聚硅氧烷，特定的有机氢聚硅氧烷，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。 乳液B包含特定的含烯基的有机聚硅氧烷，铂系配合物，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。
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3.发明授权Silicone emulsion composition adherent to plastic film substrates and release film 失效硅胶乳胶组合物粘附在塑料薄膜基材和脱模膜上公开(公告)号：US06794444B2
公开(公告)日：2004-09-21
申请号：US10327887
申请日：2002-12-26
IPC分类号： C08G7708
CPC分类号： C09D183/04 , Y10T428/31663 , C08L83/00
摘要： A silicone emulsion composition of the addition reaction curing type comprising a major proportion of an organopolysiloxane containing at least two alkenyl radicals and T units and having a viscosity of 5-100 mPa·s, a minor proportion of another organopolysiloxane containing at least two alkenyl radicals and having a 30% toluene diluted viscosity of 1,000-10,000 mPa·s, an organohydrogenpolysiloxane, a platinum radical metal catalyst, a surfactant, and water cures into a coating that adheres well to plastic film substrates. The cured coating exhibits release properties to pressure-sensitive adhesives and can be utilized as release film.
摘要翻译： 一种加成反应固化型的硅氧烷乳液组合物，其包含主要部分含有至少两个烯基和T单元并且具有5-100mPa.s的粘度的有机聚硅氧烷，少量的另外的含有至少两个烯基的有机聚硅氧烷 并且具有1,000-10,000mPa.s的30％甲苯稀释粘度，有机氢聚硅氧烷，铂自由基金属催化剂，表面活性剂和水固化到与塑料膜基材良好粘合的涂层中。 固化的涂层对压敏粘合剂表现出释放性能，并可用作剥离膜。
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4.发明授权Liquid silicone rubber coating composition, curtain airbag, and its production method 有权液体硅橡胶涂料组合物，帘式气囊及其制备方法公开(公告)号：US08608846B2
公开(公告)日：2013-12-17
申请号：US12879488
申请日：2010-09-10
IPC分类号： C04B41/49
CPC分类号： C09D183/04 , C08G77/20 , C08G77/50 , C08G77/52 , C09D183/14 , C08L83/00
摘要： A liquid silicone rubber coating composition exhibiting high adhesion for an airbag base fabric; a curtain airbag having a silicone rubber coating layer of the cured composition formed on at least one surface of the base fabric; and a method for producing such curtain airbag are provided. The composition comprises (A) an organopolysiloxane having at least 2 alkenyl groups bonded to the silicon atoms per molecule; (B) an organohydrogenpolysiloxane having at least 2 structural units represented by formula (1) per molecule, the structural units being linked by a non-siloxane structural unit not containing SiH group; (C) an addition catalyst; (E) an organosilicon compound having an epoxy group and an alkoxy group bonded to the silicon atom in the molecule; and (F) a titanium compound and/or a zirconium compound; and preferably (D) a fine powder silica having a specific surface area of at least 50 m2/g.
摘要翻译： 对气囊底布显示出高粘合性的液体硅橡胶涂料组合物; 帘式气囊，其具有形成在所述基底织物的至少一个表面上的所述固化组合物的硅橡胶涂层; 并提供了这种帘式气囊的制造方法。 该组合物包含（A）每分子具有至少2个与硅原子键合的烯基的有机聚硅氧烷; （B）每分子具有至少2个由式（1）表示的结构单元的有机氢聚硅氧烷，该结构单元由不含SiH基的非硅氧烷结构单元连接; （C）加成催化剂; （E）分子中具有与硅原子键合的环氧基和烷氧基的有机硅化合物; 和（F）钛化合物和/或锆化合物; 优选（D）比表面积为50m 2 / g以上的细粉二氧化硅。
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公开(公告)号：US20070129507A1
公开(公告)日：2007-06-07
申请号：US11602369
申请日：2006-11-21
申请人： Shinji Irifune
发明人： Shinji Irifune
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08L83/00 , C09D183/04 , C09J7/40 , C09J183/04 , C09J2483/005
摘要： A solvent-free silicone composition for release paper, comprising: (A) an organopolysiloxane represented by the following average compositional formula (1) (B) an organopolysiloxane represented by the following average compositional formula (2) (C) an organopolysiloxane having alkenyl groups only at its ends, represented by the following formula (3) and (D) an organohydrogenpolysiloxane represented by the following formula (4) , wherein the component (A) is contained in an amount of from 10 to 30 wt %, the component (B) is contained in an amount of from 10 to 30 wt %, the component (C) is contained in an amount of from 40 to 80 wt %, based on a total weight of the components (A), (B) and (C), and the component (D) is contained in such an amount that a molar ratio of the hydrogen atom or atoms bonded to a silicon atom to a total of the alkenyl groups of the components (A), (B) and (C) ranges from 1.0 to 4.0. The composition forms a tight release layer whose release force largely increases with release speed.
摘要翻译： 一种用于剥离纸的无溶剂硅氧烷组合物，其包含：（A）由以下平均组成式（1）表示的有机聚硅氧烷（B）由以下平均组成式（2）表示的有机聚硅氧烷：（C）具有烯基的有机聚硅氧烷 仅在其末端由下式（3）和（D）表示的下述式（4）表示的有机氢聚硅氧烷，其中成分（A）的含量为10〜30重量％，成分（ B）含量为10〜30重量％，基于（A）成分，（B）成分和（B）成分的总重量，成分（C）的含量为40〜80重量％ （A），（B）和（C（C））中的链烯基的总量相对于硅原子键合的原子的摩尔比， ）范围从1.0到4.0。 该组合物形成了释放力大大地随释放速度而增加的紧密释放层。
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公开(公告)号：US20070087207A1
公开(公告)日：2007-04-19
申请号：US11580015
申请日：2006-10-13
申请人： Shinji Irifune
发明人： Shinji Irifune
CPC分类号： C08G77/44 , C09D183/04 , C09J7/401 , C09J2483/005 , Y10T428/1471 , Y10T428/1476 , Y10T428/31663 , C08L83/00
摘要： A solvent-free silicone composition for release paper, comprising a mixture prepared by i) subjecting the organopolysiloxane (I) which is composed of R13SiO1/2 units, SiO4/2 units and (HO)SiO3/2 units, and has an OH group content of from 0.02 to 0.1 mol/100 g, to a partial condensation reaction in an organic solvent in the presence of an alkaline catalyst and the organopolysiloxane (II) represented by the following formula (2), and ii) removing the organic solvent, said mixture having an OH group content of less than 0.02 mol/100 g. The composition forms a tight-release layer stable with time.
摘要翻译： 一种用于脱模纸的无溶剂硅氧烷组合物，其包含通过以下步骤制备的混合物：i）使由R 1，3/3 SiO 1/2组成的有机聚硅氧烷（I） 2单元，SiO 2/2/2单元和（HO）SiO 3/2/2单元，OH基含量为0.02-0.1mol / 100 g，在有机溶剂中，在碱性催化剂和由下式（2）表示的有机聚硅氧烷（II）的存在下进行部分缩合反应，和ii）除去有机溶剂，所述混合物的OH基含量少 大于0.02mol / 100g。 该组合物形成了随时间稳定的紧密释放层。
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公开(公告)号：US06696161B2
公开(公告)日：2004-02-24
申请号：US10193315
申请日：2002-07-12
申请人： Shinji Irifune , Masahiko Ogawa
发明人： Shinji Irifune , Masahiko Ogawa
IPC分类号： B32B904
CPC分类号： C08L83/04 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/20 , C08L2205/02 , C09D183/04 , C09J7/401 , C09J2400/226 , C09J2483/005 , Y10T428/31663 , C08L83/00
摘要： A silicone composition comprising a first organopolysiloxane containing T units, a second organopolysiloxane, an organohydrogenpolysiloxane, and a platinum catalyst cures into a coating that adheres well to plastic film substrates and even to polyester film substrates which are difficult for conventional solventless silicone compositions to adhere. The cured coating exhibits release properties to pressure-sensitive adhesives, and a film substrate coated with the cured silicone composition provides a release film.
摘要翻译： 包含含有T单元的第一有机聚硅氧烷，第二有机聚硅氧烷，有机氢聚硅氧烷和铂催化剂的硅氧烷组合物固化到与塑料薄膜基材甚至聚酯薄膜基材良好粘附的涂层中，所述聚酯薄膜基材难以用于常规的无溶剂硅酮组合物粘附。 固化的涂层对压敏粘合剂表现出剥离性能，并且涂覆有固化的硅氧烷组合物的膜基材提供了脱模膜。
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8.发明授权公开(公告)号：US08211547B2
公开(公告)日：2012-07-03
申请号：US12413960
申请日：2009-03-30
申请人： Shinji Irifune , Akinari Itagaki
发明人： Shinji Irifune , Akinari Itagaki
IPC分类号： B32B15/04
CPC分类号： C08L83/06 , C08G77/14 , C08K5/0025 , C09D183/06 , C09J7/401 , C09J2483/005 , Y10T428/31663 , C08L83/00
摘要： An ultraviolet-curable silicone composition for a release paper including (A) 100 parts by mass of a specific organopolysiloxane having a polymerization degree of 8 to 20 and containing one epoxy group, and (C) an effective quantity of an onium salt photoinitiator. In a preferred embodiment, the composition further includes (B) 10 to 1,000 parts by mass of at least one specific organopolysiloxane containing a plurality of epoxy groups. In another preferred embodiment, the composition has a viscosity of not more than 100 mPa·s. The composition has a peel strength that exhibits a positive dependency on the peel speed when peeled from a hot-melt pressure-sensitive adhesive, and can therefore be used to produce a release paper capable of reducing peeling noise. Further, because the composition has a low viscosity, it exhibits excellent wetting of substrates having significant unevenness, even in a solventless form.
摘要翻译： 一种用于剥离纸的紫外线固化型硅氧烷组合物，其包含（A）100质量份聚合度为8〜20的特定有机聚硅氧烷并含有一个环氧基，和（C）有效量的鎓盐光引发剂。 在优选的实施方案中，组合物还包含（B）10至1,000质量份的至少一种含有多个环氧基团的特定有机聚硅氧烷。 在另一个优选的实施方案中，组合物的粘度不超过100mPa·s。 该组合物具有剥离强度，其从热熔压敏粘合剂剥离时对剥离速度呈现正向依赖性，因此可用于制造能够降低剥离噪音的剥离纸。 此外，由于该组合物具有低粘度，所以即使在无溶剂形式下也具有显着不均匀性的基材润湿性优异。
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9.发明申请LIQUID SILICONE RUBBER COATING COMPOSITION, CURTAIN AIRBAG, AND ITS PRODUCTION METHOD 有权液体硅橡胶涂料组合物，幕墙安全气囊及其生产方法公开(公告)号：US20110064882A1
公开(公告)日：2011-03-17
申请号：US12879488
申请日：2010-09-10
CPC分类号： C09D183/04 , C08G77/20 , C08G77/50 , C08G77/52 , C09D183/14 , C08L83/00
摘要： A liquid silicone rubber coating composition exhibiting high adhesion for an airbag base fabric; a curtain airbag having a silicone rubber coating layer of the cured composition formed on at least one surface of the base fabric; and a method for producing such curtain airbag are provided. The composition comprises (A) an organopolysiloxane having at least 2 alkenyl groups bonded to the silicon atoms per molecule; (B) an organohydrogenpolysiloxane having at least 2 structural units represented by formula (1) per molecule, the structural units being linked by a non-siloxane structural unit not containing SiH group; (C) an addition catalyst; (E) an organosilicon compound having an epoxy group and an alkoxy group bonded to the silicon atom in the molecule; and (F) a titanium compound and/or a zirconium compound; and preferably (D) a fine powder silica having a specific surface area of at least 50 m2/g.
摘要翻译： 对气囊底布显示出高粘合性的液体硅橡胶涂料组合物; 帘式气囊，其具有形成在所述基底织物的至少一个表面上的所述固化组合物的硅橡胶涂层; 并提供了这种帘式气囊的制造方法。 该组合物包含（A）每分子具有至少2个与硅原子键合的烯基的有机聚硅氧烷; （B）每分子具有至少2个由式（1）表示的结构单元的有机氢聚硅氧烷，该结构单元由不含SiH基的非硅氧烷结构单元连接; （C）加成催化剂; （E）分子中具有与硅原子键合的环氧基和烷氧基的有机硅化合物; 和（F）钛化合物和/或锆化合物; 优选（D）比表面积为50m 2 / g以上的细粉二氧化硅。
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10.发明授权Method for preparation of organopolysilixame having branched molecular structure 有权制备具有支链分子结构的有机聚硅酮的方法公开(公告)号：US06573355B2
公开(公告)日：2003-06-03
申请号：US09901633
申请日：2001-07-11
申请人： Shinji Irifune , Masahiko Ogawa
发明人： Shinji Irifune , Masahiko Ogawa
IPC分类号： C08G7708
摘要： The invention discloses a method for the preparation of an organopolysiloxane having a branched molecular structure which comprises the steps of: (A) Mixing (A1) an organopolysiloxane represented by the average unit formula [R13SiO½]m[R1SiO{fraction (3/2)}]n[R1(R2O)SiO]q, in which R1 is a monovalent hydrocarbon group, R2 is a hydrogen atom, methyl group or ethyl group and the subscripts m, n and q are each 0 or a positive number with the proviso that (n+q)/m is from 0.6 to 1.5 and q/(m+n) is 0 or a positive number not exceeding 0.05; (A2) a cyclic dialkylsiloxane oligomer, and (A3) a polyorganosiloxane represented by the structural formula R33Si—O—(—SiR32—O—)r—SiR33, In which R3 is a monovalent hydrocarbon group and the subscript r is 0 or a positive integer not exceeding 100, to give a siloxane mixture; (B) admixing the siloxane mixture with an alkaline compound; and (C) heating the siloxane mixture to effect siloxane rearrangement polymerization of the organopolysiloxanes.
摘要翻译： 本发明公开了一种制备具有支链分子结构的有机聚硅氧烷的方法，该方法包括以下步骤：（A）将由平均单元形式表示的有机聚硅氧烷（A1为R1为一价烃基），R2为氢原子 ，甲基或乙基，下标m，n和q各自为0或正数，条件是（n + q）/ m为0.6至1.5，q /（m + n）为0或正 数量不超过0.05;（A2）环状二烷基硅氧烷低聚物，（A3）由结构式表示的聚有机硅氧烷，其中R3为一价烃基，下标r为0或不超过100的正整数，得到硅氧烷混合物 ;（B）将硅氧烷混合物与碱性化合物混合; 和（C）加热硅氧烷混合物以实现有机聚硅氧烷的硅氧烷重排聚合。
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