公开(公告)号：US20090118425A1

公开(公告)日：2009-05-07

申请号：US11664994

申请日：2005-09-28

申请人： Shinobu Ochikoshi ,  Takao Shibata

发明人： Shinobu Ochikoshi ,  Takao Shibata

IPC分类号： C08L25/08 ,  C08L83/04

CPC分类号： C08L25/06 ,  C08L25/08 ,  C08L51/085 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/24

摘要： An object of the present invention is to provide a modifier for styrene resins that has excellent powder characteristics and that can provide a styrene resin composition for a styrene resin having high impact resistance and formability when the modifier is contained in a small amount.A modifier (C) for styrene resins that has improved powder characteristics can be obtained by mixing, in advance or in advance in latex form, 1 to 400 parts by weight of a styrene copolymer (B) with 100 parts by weight of a polyorganosiloxane-containing graft copolymer (A) having a polyorganosiloxane backbone produced by polymerizing an organosiloxane and a grafting agent, and then granulating the resulting mixture. Thus, the above-described object can be achieved.

摘要翻译： 本发明的目的是提供一种具有优异粉末特性的苯乙烯树脂改性剂，并且当改性剂含量少时，可提供具有高抗冲击性和成形性的苯乙烯树脂的苯乙烯树脂组合物。 具有改善的粉末特性的苯乙烯树脂的改性剂（C）可以预先或预先以胶乳形式混合1至400重量份的苯乙烯共聚物（B）与100重量份的聚有机硅氧烷 - 含有通过聚合有机硅氧烷和接枝剂制备的聚有机硅氧烷骨架的接枝共聚物（A），然后将所得混合物造粒。 因此，可以实现上述目的。

公开(公告)号：US06627668B2

公开(公告)日：2003-09-30

申请号：US09916315

申请日：2001-07-30

申请人： Shinobu Ochikoshi ,  Yutaka Yanagihara ,  Naruhiko Akamatsu

发明人： Shinobu Ochikoshi ,  Yutaka Yanagihara ,  Naruhiko Akamatsu

IPC分类号： C08J922

CPC分类号： B29C44/3453 ,  B29C44/3461 ,  C08J9/18 ,  C08J2203/06 ,  C08J2323/02

摘要： Pre-expanded particles of polyolefin resin having less fluctuation in expansion ratio, uniform particle size and low expansion ratio are provided without using any volatile foaming agent. The low expansion ratio means 2 to 10 times, preferably 3 to 8 times. Resin particles to be released are uniformly contacted with saturated vapor at the time of pre-expanding polyolefin resin particles by dispersing the resin particles into an aqueous dispersion medium in a closed vessel, heating the resin particles to temperature of at least the softening point of the polyolefin resin and releasing the particles from the closed vessel into an atmosphere of lower pressure than the inner pressure of the closed vessel.

公开(公告)号：US6136918A

公开(公告)日：2000-10-24

申请号：US68014

申请日：1998-04-30

申请人： Ikuhiro Mishima ,  Norito Doi ,  Youichi Matsumura ,  Shigemi Matsumoto ,  Shinobu Ochikoshi ,  Kazuhito Wada ,  Hiroki Yoshino

发明人： Ikuhiro Mishima ,  Norito Doi ,  Youichi Matsumura ,  Shigemi Matsumoto ,  Shinobu Ochikoshi ,  Kazuhito Wada ,  Hiroki Yoshino

IPC分类号： C08C1/07 ,  C08F265/04 ,  C08F279/02 ,  C08L21/02 ,  C08L51/04 ,  C08F291/02 ,  C08L33/06

CPC分类号： C08L21/02 ,  C08C1/07 ,  C08F265/04 ,  C08F279/02 ,  C08L51/04

摘要： A rubber latex with its particles grown through cohesion by adding 100 weight parts of (B) a rubber latex (solid), 0.1-15 weight parts (solid) of (A) an acid group-containing latex having an average particle size of 50-500 nm prepared by polymerizing a monomer mixture comprising (a), (b), (c) and (d) [wherein (a)+(b)+(c)+(d)=100 weight %]: (a) 5-25 weight % of at least one of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and crotonic acid, (b) 20-95 weight % of at least one of alkyl methacrylates with its alkyl group 1-12 in carbon number, (c) 0-30 weight % of at least one of alkyl acrylates with its alkyl group 1-12 in carbon number, (d) 0-40 weight % of at least one selected from the group consisting of aromatic vinyls, compounds having at least two polymerizable functional groups in a molecule and vinyl cyanides, copolymerizable with the aforementioned (a), (b) and (c) is provided. The rubber latex and a graft copolymer containing it and thermoplastic resins incorporating said graft copolymer are excellent in impact strength, heat resistance and workability.

摘要翻译： PCT No.PCT / JP95 / 02548 Sec。 371日期：1998年4月30日 102（e）1998年4月30日PCT 1995年12月13日PCT PCT。 出版物WO97 / 21770 日期：1996年6月19日通过加入100重量份（B）橡胶胶乳（固体），0.1-15重量份（固体）（A）含酸基胶乳的胶乳（其具有 通过聚合包含（a），（b），（c）和（d）[其中（a）+（b）+（c）+（d））= 100重量的单体混合物制备的平均粒径为50-500nm ％）：（a）5-25重量％的选自丙烯酸，甲基丙烯酸，衣康酸和巴豆酸的不饱和酸中的至少一种，（b）20-95重量％的至少一种烷基 其碳原子数为1-12的甲基丙烯酸酯，（c）0-30重量％的碳原子数为1-12的烷基丙烯酸烷基酯中的至少一种，（d）0-40重量％的至少一种 选自芳族乙烯基，分子中具有至少两个可聚合官能团的化合物和可与上述（a），（b）和（c）共聚的乙烯基氰化物）。 橡胶胶乳和含有它的接枝共聚物和结合所说接枝共聚物的热塑性树脂具有优异的冲击强度，耐热性和可加工性。

公开(公告)号：US5821272A

公开(公告)日：1998-10-13

申请号：US339

申请日：1998-01-20

申请人： Shinobu Ochikoshi ,  Hisatoshi Fukui ,  Kyoichi Nakamura ,  Hideya Mizuike ,  Naruhiko Akamatsu

发明人： Shinobu Ochikoshi ,  Hisatoshi Fukui ,  Kyoichi Nakamura ,  Hideya Mizuike ,  Naruhiko Akamatsu

IPC分类号： B29C44/34 ,  B29C44/56 ,  C08J9/22

CPC分类号： C08J9/22 ,  B29C44/3461 ,  B29C44/5609 ,  C08J2323/02 ,  Y10S264/09 ,  Y10S521/918

摘要： Post-treatment method of polyolefin resin pre-expanded particles comprising: introducing the polyolefin resin pre-expanded particles foamed by using an inflammable blowing agent into an extraction vessel filled with steam previously; feeding an additional steam into the extraction vessel; extracting the inflammable blowing agent gas from the polyolefin resin pre-expanded particles; discharging the resulting steam which contains the extracted inflammable blowing agent gas from the extraction vessel continuously or intermittently; and liquefying the steam to separate and recover the inflammable blowing agent gas. According to the post-treatment method of polyolefin resin pre-expanded particles, the inflammable blowing agent can be extracted from the pre-expanded particles in a short period of time and the extracted inflammable blowing agent can be re-used.

摘要翻译： PCT No.PCT / JP97 / 02074 Sec。 371日期1998年1月20日 102（e）日期1998年1月20日PCT提交1997年6月16日PCT公布。 第WO97 / 48759号公报 日期1997年12月24日聚烯烃树脂预发泡粒子的后处理方法包括：将通过使用可燃性发泡剂发泡的聚烯烃树脂预发泡颗粒引入预先装有蒸汽的萃取容器中; 将额外的蒸汽进料到提取容器中; 从聚烯烃树脂预发泡颗粒中提取易燃发泡剂气体; 从提取容器中连续或间歇地排出含有提取的易燃发泡剂气体的所得蒸汽; 并使蒸汽液化以分离和回收易燃发泡剂气体。 根据聚烯烃树脂预发泡颗粒的后处理方法，可以在短时间内从预发泡颗粒中提取易燃发泡剂，并且可以重新使用提取的可燃性发泡剂。