公开(公告)号：US5990240A

公开(公告)日：1999-11-23

申请号：US893556

申请日：1997-07-11

申请人： Ikuhiro Mishima ,  Yo-ichi Matsumura ,  Yoshihiko Hashimoto ,  Shigemi Matsumoto

发明人： Ikuhiro Mishima ,  Yo-ichi Matsumura ,  Yoshihiko Hashimoto ,  Shigemi Matsumoto

IPC分类号： C08L15/00 ,  C08F2/22 ,  C08L21/02 ,  C08L25/00 ,  C08L25/12 ,  C08L51/04 ,  C08L55/00 ,  C08L55/02 ,  C08L9/00

CPC分类号： C08L25/12 ,  C08L55/02

摘要： A rubber-containing resin composition suitable as an impact modifier for styrene resins (such as styrene homopolymer and copolymers and polymer alloys thereof with other thermoplastic resins), which comprises (A) a graft copolymer having a graft ratio of 10 to 80% by weight wherein a graft component comprising 15 to 60% by mole of at least one vinyl cyanide compound, 40 to 85% by mole of at least one aromatic vinyl compound and 0 to 30% by mole of at least one other monomer copolymerizable with them is graft-copolymerized onto a diene rubber having a volume average particle size of 100 to 1,000 nm by an emulsion polymerization method, and (B) an emulsion-polymerized copolymer of 15 to 60% by mole of at least one vinyl cyanide compound, 40 to 85% by mole of at least one aromatic vinyl compound and 0 to 30% by mole of at least one other monomer copolymerizable with them, which has a weight average molecular weight of 5,000 to 90,000 and a ratio of weight average molecular weight to number average molecular weight of 1.5 to 4.5, in which the ratio of the graft copolymer (A) to the copolymer (B) is from 50/50 to 95/5 by weight. A styrene resin composition comprising the rubber-containing resin composition and a styrene resin provides molded articles having excellent properties such as impact resistance, mechanical property, heat resistance and surface appearance with good processability.

摘要翻译： 适合作为苯乙烯类树脂（例如苯乙烯均聚物及其与其它热塑性树脂的共聚物及其聚合物合金）的抗冲改性剂的含橡胶的树脂组合物，其包含（A）接枝率为10〜80重量％ 其中，含有15〜60摩尔％的至少一种乙烯基氰化合物，40〜85摩尔％的至少一种芳族乙烯基化合物和0〜30摩尔％的与其共聚的至少一种其他单体的接枝成分是接枝 通过乳液聚合法共聚到体积平均粒径为100〜1000nm的二烯系橡胶上，（B）15〜60摩尔％的至少一种乙烯基氰化合物的乳液聚合共聚物，40〜85 摩尔％的至少一种芳族乙烯基化合物和0至30摩尔％的至少一种可与其共聚的其它单体，其重均分子量为5,000至90,000，重均分子量与数量的比率 平均分子量为1.5至4.5，其中接枝共聚物（A）与共聚物（B）的比例为50/50至95/5重量比。 包含含橡胶的树脂组合物和苯乙烯树脂的苯乙烯树脂组合物提供了具有优异的性能如耐冲击性，机械性能，耐热性和表面外观的加工性能优异的模制品。

公开(公告)号：US5741860A

公开(公告)日：1998-04-21

申请号：US652476

申请日：1996-06-18

申请人： Shigemi Matsumoto ,  Akinaga Goda

发明人： Shigemi Matsumoto ,  Akinaga Goda

IPC分类号： C08L23/08 ,  C08L33/06 ,  C08L55/02

CPC分类号： C08L23/08 ,  C08L33/062 ,  C08L55/02

摘要： A thermoplastic resin composition is disclosed, which comprizes 5-55 weight % of a copolymer (A) whose glass transition temperature is not more than 0.degree. C., and 95-45 weight % of a high .alpha.-methylstyrene-content ABS resin (B) and/or a maleimide-type ABS resin (C), both (B) and (C) being not less than 100.degree. C. in thermal deformation temperature (load 18.6 kg/cm.sup.2), and said resin composition being not less than 10 kg.cm/cm in Izod impact strength (23.degree. C.). The resin composition provides molded articles less deformable at high temperatures, low in impact-induced stress, i.e, high in impact energy absorptivity, and thus is suitable for trim parts for use in interior decoration of automobiles.

摘要翻译： PCT No.PCT / JP95 / 02237 Sec。 371日期1996年6月18日 102（e）1996年6月18日PCT 1995年11月1日PCT PCT。 出版物WO96 / 15190 日期：1996年5月23日公开了一种热塑性树脂组合物，其含有5-55重量％的玻璃化转变温度不高于0℃的共聚物（A）和95-45重量％的高α-甲基苯乙烯 - 含量ABS树脂（B）和/或马来酰亚胺型ABS树脂（C），（B）和（C）在热变形温度（负荷18.6kg / cm 2）下不低于100℃，所述树脂 组合物的悬臂梁式冲击强度（23℃）不小于10kg·cm / cm。 树脂组合物提供在高温下变形较小，冲击诱发应力低的冲击能量吸收性的模塑制品，因此适合用于汽车的室内装饰的装饰部件。

公开(公告)号：US4761463A

公开(公告)日：1988-08-02

申请号：US843358

申请日：1986-03-24

申请人： Shigemi Matsumoto ,  Fumiya Nagoshi

发明人： Shigemi Matsumoto ,  Fumiya Nagoshi

IPC分类号： C08L25/00 ,  C08F279/02 ,  C08L7/00 ,  C08L21/00 ,  C08L25/02 ,  C08L25/12 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L37/00

CPC分类号： C08L25/12 ,  C08F279/02 ,  C08L51/04

摘要： A thermoplastic resin composition having a matte appearance comprising:(A) 80-5 parts by weight of a graft copolymer obtained by grafting 40-95 parts by weight of diene rubber with 60-5 parts by weight of vinyl compounds consisting of0.1-40 weight % of at least one glycidyl ester of an .alpha.- and .beta.-unsaturated acid as an essential component,10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, and(B) 20-95 parts by weight of a copolymer obtained through reaction of10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, the intrinsic viscosity of the resin composition in terms of its components which are soluble in methyl ethyl ketone being 0.25-1.5 dl/g (N,N'-dimethyl formamide solution, 30.degree. C.).

摘要翻译： 具有无光泽外观的热塑性树脂组合物包含：（A）80-5重量份通过将40-95重量份二烯橡胶与60-5重量份由0.1-40重量份组成的乙烯基化合物接枝而获得的接枝共聚物 至少一种作为必需组分的α-和β-不饱和酸的缩水甘油酯的重量％，10-40重量％的至少一种乙烯基氰化合物，60-90重量％的至少一种芳族乙烯基化合物和0 -30重量％的其它可共聚的乙烯基化合物，和（B）20-95重量份通过将10-40重量％的至少一种乙烯基氰化合物，60-90重量％的至少一种芳族化合物 乙烯基化合物和0-30重量％的其它可共聚乙烯基化合物，根据可溶于甲基乙基酮的组分，树脂组合物的特性粘度为0.25-1.5dl / g（N，N'-二甲基甲酰胺溶液 ，30℃）。

公开(公告)号：US06482456B1

公开(公告)日：2002-11-19

申请号：US09596201

申请日：2000-06-16

申请人： Yoshiaki Yokoo ,  Shigemi Matsumoto ,  Yoshiko Hino ,  Nobuya Matsumoto

发明人： Yoshiaki Yokoo ,  Shigemi Matsumoto ,  Yoshiko Hino ,  Nobuya Matsumoto

IPC分类号： A23B420

CPC分类号： A23L2/44 ,  A23C9/1542 ,  A23C9/1544 ,  A23V2002/00 ,  A23V2250/511

摘要： A method for producing a low acid beverage in which a deterioration in quality associated with a pH decrease during heat sterilization or long-term storage in a heated condition is eliminated or minimized, and which is characterized by adding at least one of chitosan, chitosan oligosaccharide and glucosamine.

摘要翻译： 一种生产低酸饮料的方法，其中消除或最小化在加热灭菌或加热条件下的长期保存中与pH降低相关的质量劣化，其特征在于，将至少一种壳聚糖，壳聚糖寡糖 和葡糖胺。

公开(公告)号：US6136918A

公开(公告)日：2000-10-24

申请号：US68014

申请日：1998-04-30

申请人： Ikuhiro Mishima ,  Norito Doi ,  Youichi Matsumura ,  Shigemi Matsumoto ,  Shinobu Ochikoshi ,  Kazuhito Wada ,  Hiroki Yoshino

发明人： Ikuhiro Mishima ,  Norito Doi ,  Youichi Matsumura ,  Shigemi Matsumoto ,  Shinobu Ochikoshi ,  Kazuhito Wada ,  Hiroki Yoshino

IPC分类号： C08C1/07 ,  C08F265/04 ,  C08F279/02 ,  C08L21/02 ,  C08L51/04 ,  C08F291/02 ,  C08L33/06

CPC分类号： C08L21/02 ,  C08C1/07 ,  C08F265/04 ,  C08F279/02 ,  C08L51/04

摘要： A rubber latex with its particles grown through cohesion by adding 100 weight parts of (B) a rubber latex (solid), 0.1-15 weight parts (solid) of (A) an acid group-containing latex having an average particle size of 50-500 nm prepared by polymerizing a monomer mixture comprising (a), (b), (c) and (d) [wherein (a)+(b)+(c)+(d)=100 weight %]: (a) 5-25 weight % of at least one of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and crotonic acid, (b) 20-95 weight % of at least one of alkyl methacrylates with its alkyl group 1-12 in carbon number, (c) 0-30 weight % of at least one of alkyl acrylates with its alkyl group 1-12 in carbon number, (d) 0-40 weight % of at least one selected from the group consisting of aromatic vinyls, compounds having at least two polymerizable functional groups in a molecule and vinyl cyanides, copolymerizable with the aforementioned (a), (b) and (c) is provided. The rubber latex and a graft copolymer containing it and thermoplastic resins incorporating said graft copolymer are excellent in impact strength, heat resistance and workability.

摘要翻译： PCT No.PCT / JP95 / 02548 Sec。 371日期：1998年4月30日 102（e）1998年4月30日PCT 1995年12月13日PCT PCT。 出版物WO97 / 21770 日期：1996年6月19日通过加入100重量份（B）橡胶胶乳（固体），0.1-15重量份（固体）（A）含酸基胶乳的胶乳（其具有 通过聚合包含（a），（b），（c）和（d）[其中（a）+（b）+（c）+（d））= 100重量的单体混合物制备的平均粒径为50-500nm ％）：（a）5-25重量％的选自丙烯酸，甲基丙烯酸，衣康酸和巴豆酸的不饱和酸中的至少一种，（b）20-95重量％的至少一种烷基 其碳原子数为1-12的甲基丙烯酸酯，（c）0-30重量％的碳原子数为1-12的烷基丙烯酸烷基酯中的至少一种，（d）0-40重量％的至少一种 选自芳族乙烯基，分子中具有至少两个可聚合官能团的化合物和可与上述（a），（b）和（c）共聚的乙烯基氰化物）。 橡胶胶乳和含有它的接枝共聚物和结合所说接枝共聚物的热塑性树脂具有优异的冲击强度，耐热性和可加工性。

公开(公告)号：US5367016A

公开(公告)日：1994-11-22

申请号：US980008

申请日：1992-11-23

申请人： Osamu Miyama ,  Katsutoyo Fujita ,  Hayato Nishimura ,  Shigemi Matsumoto ,  Satoshi Tonoki

发明人： Osamu Miyama ,  Katsutoyo Fujita ,  Hayato Nishimura ,  Shigemi Matsumoto ,  Satoshi Tonoki

IPC分类号： C08L23/06 ,  C08L23/12 ,  C08L51/04 ,  C08L67/02 ,  C08L69/00

CPC分类号： C08L67/02 ,  C08L69/00 ,  C08L23/06 ,  C08L23/12 ,  C08L51/04 ,  C08L67/025

摘要： A reinforced resin composition comprising 100 parts by weight of a resin component comprising a polycarbonate resin, a thermoplastic polyester resin and an impact modifier in a ratio, by weight, of 90-10:10-90:0-40 and 0.5 to 100 parts by weight of kaolin with a mean particle diameter of 0.1 to 4.0 .mu.m. The composition can be molded by conventional techniques such as injection molding and extrusion molding into automotive parts, electrical or electronic parts and other products excellent in heat resistance, impact resistance, rigidity, dimensional stability, chemical resistance, moldability, weather resistance and thermal stability with a low linear coefficient of expansion and excellent surface gloss and appearance.

摘要翻译： 一种增强树脂组合物，其包含100重量份的树脂组分，其包含聚碳酸酯树脂，热塑性聚酯树脂和抗冲改性剂，其重量比为90-10：10-90：0-40和0.5至100份 的平均粒径为0.1〜4.0μm的高岭土。 组合物可以通过常规技术如注射成型和挤出成型成型为汽车部件，电气或电子部件以及耐热性，耐冲击性，刚性，尺寸稳定性，耐化学性，成型性，耐候性和热稳定性优异的其它产品 线性膨胀系数低，表面光泽和外观优异。

公开(公告)号：US07195816B2

公开(公告)日：2007-03-27

申请号：US10531282

申请日：2002-12-19

申请人： Norito Doi ,  Takao Shibata ,  Yoichi Matsumura ,  Shigemi Matsumoto

发明人： Norito Doi ,  Takao Shibata ,  Yoichi Matsumura ,  Shigemi Matsumoto

IPC分类号： B32B5/16 ,  B32B27/30 ,  C08G63/48 ,  C08L31/02 ,  C08L33/06

CPC分类号： C08L33/10 ,  C08J5/18 ,  C08J2333/10 ,  C08J2351/04 ,  C08L33/12 ,  C08L51/04 ,  Y10T428/254 ,  Y10T428/31935 ,  C08L2666/24

摘要： To provide an acrylic film, composed of a resin composition (C) that includes an acrylic graft copolymer (A) containing an acrylic ester rubber-like polymer and a methacrylic polymer (B) containing 80% by weight or more of methyl methacrylate, wherein (1) the content of the acrylic ester rubber-like polymer in the resin composition (C) is 5% by weight or more and 30% by weight or less, (2) the average particle size of the acrylic ester rubber-like polymer is 500 to 2000 Å, (3) the relationship between the average particle size d (Å) of the acrylic ester rubber-like polymer and the amount w (% by weight) of crosslinking agent used in the acrylic ester rubber-like polymer satisfies the following equation: 0.002d≦w≦0.005d, (4) the graft ratio of the acrylic graft copolymer (A) is 30% or more and 200% or less, and (5) the reduced viscosity of methyl ethyl ketone soluble matter in the resin composition (C) is 0.2 to 0.8 dl/g.

摘要翻译： 为了提供一种由含有丙烯酸酯类橡胶状聚合物的丙烯酸接枝共聚物（A）和含有80重量％以上的甲基丙烯酸甲酯的甲基丙烯酸系聚合物（B）的树脂组合物（C）构成的丙烯酸系膜，其中， （1）树脂组合物（C）中丙烯酸酯类橡胶状聚合物的含量为5重量％以上且30重量％以下，（2）丙烯酸酯类橡胶状聚合物的平均粒径 为500〜2000埃，（3）丙烯酸酯类橡胶状聚合物的平均粒径d（）与丙烯酸酯类橡胶状聚合物中使用的交联剂的w（重量％）的量之间的关系满足 以下等式：0.002d <= w <= 0.005d，（4）丙烯酸接枝共聚物（A）的接枝率为30％以上且200％以下，（5）甲基乙基酮的比浓粘度 树脂组合物（C）中的可溶物质为0.2〜0.8dl / g。

公开(公告)号：US4518742A

公开(公告)日：1985-05-21

申请号：US546596

申请日：1983-10-28

申请人： Eiichi Muramatsu ,  Shigemi Matsumoto ,  Fumiya Nagoshi

发明人： Eiichi Muramatsu ,  Shigemi Matsumoto ,  Fumiya Nagoshi

IPC分类号： C08F285/00 ,  C08L51/00 ,  C08L51/04 ,  C08L69/00

CPC分类号： C08L51/00 ,  C08L69/00

摘要： A thermoplastic resin composition having excellent impact resistance, heat distortion resistance and processability which comprises an aromatic polycarbonate and a thermoplastic resin prepared by polymerizing a monomer mixture containing mainly acrylonitrile and styrene in the presence of a diene rubber, adding .alpha.-methylstyrene or a monomer mixture containing mainly .alpha.-methylstyrene to the system, and continuing the polymerization, while gradually adding acrylonitrile or a monomer mixture containing mainly acrylonitrile.

摘要翻译： 一种具有优异的耐冲击性，耐热变形性和加工性的热塑性树脂组合物，其包含芳族聚碳酸酯和通过在二烯橡胶的存在下主要包含丙烯腈和苯乙烯的单体混合物聚合制备的热塑性树脂，加入α-甲基苯乙烯或单体混合物 其中主要含有α-甲基苯乙烯，并继续聚合，同时逐渐加入丙烯腈或主要是丙烯腈的单体混合物。

公开(公告)号：US06309739B1

公开(公告)日：2001-10-30

申请号：US09135022

申请日：1998-08-17

申请人： Keishi Koizumi ,  Shigemi Matsumoto ,  Takao Okimi ,  Juuichi Nishimura

发明人： Keishi Koizumi ,  Shigemi Matsumoto ,  Takao Okimi ,  Juuichi Nishimura

IPC分类号： C08J518

CPC分类号： C08J5/18 ,  C08J2333/10 ,  C08L33/10 ,  C08L51/003 ,  Y10T428/254 ,  Y10T428/31931 ,  C08L2666/24

摘要： A methacrylate, resin composition having an excellent processability and capable of providing films having excellent impact resistance, transparency, weatherability, solvent resistance and plasticizer migration resistance, which comprises (A) 5 to 50% by weight of a crosslinked acrylate elastomer having a two layer structure of a crosslinked polymer component (a-1) having a glass transition temperature of −30 to 10° C. and a crosslinked polymer component (a-2) having a glass transition temperature of less than −30° C. wherein the component (a-1) is located on the inner side or the outer side and the component (a-2) is located on the outer side or the inner side, and (B) 95 to 50% by weight of an alkyl methacrylate polymer prepared by polymerizing an acrylic monomer containing 80 to 100% by weight of an alkyl methacrylate and 20 to 0% by weight of an alkyl acrylate in the presence of a chain transfer agent and in the presence or absence of the elastomer (A). The composition may further contain a core-shell polymer prepared by graft-polymerizing a monomer containing a major amount of an alkyl methacrylate onto a crosslinked acrylate polymer, whereby molded articles having a matt surface and an excellent flex whitening resistance are obtained.

摘要翻译： 具有优异的加工性的甲基丙烯酸酯树脂组合物，其能够提供耐冲击性，透明性，耐候性，耐溶剂性和耐增塑剂迁移性优异的膜，其包含（A）5〜50重量％的具有两层的交联丙烯酸酯弹性体 玻璃化转变温度为-30〜10℃的交联聚合物组分（a-1）的结构和玻璃化转变温度低于-30℃的交联聚合物组分（a-2）。其中组分 （a-1）位于内侧或外侧，成分（a-2）位于外侧或内侧，（B）95〜50重量％的制备的甲基丙烯酸烷基酯聚合物 通过在链转移剂的存在下和在弹性体（A）的存在或不存在下聚合含有80至100重量％的甲基丙烯酸烷基酯和20至0重量％的丙烯酸烷基酯的丙烯酸类单体。 组合物还可以含有通过将含有主要量的甲基丙烯酸烷基酯的单体接枝聚合到丙交酯交联聚合物上制备的核 - 壳聚合物，由此获得具有无光泽表面和优异的抗弯白美白性的模塑制品。

公开(公告)号：US5955541A

公开(公告)日：1999-09-21

申请号：US984988

申请日：1997-12-04

申请人： Kazuhito Wada ,  Ikuhiro Mishima ,  Shigemi Matsumoto

发明人： Kazuhito Wada ,  Ikuhiro Mishima ,  Shigemi Matsumoto

IPC分类号： C08L25/08 ,  C08L25/12 ,  C08L33/06 ,  C08L33/08 ,  C08L35/06 ,  C08L51/04

CPC分类号： C08L51/04 ,  C08L25/12 ,  C08L33/06

摘要： A thermoplastic resin composition which has low rigidity such as bending strength, bending modulus and tensile strength, high impact resistance, and further low stress and large energy absorption at the time of impact, high heat deformation resistance and excellent moldability and comprises 5 to 65 by weight of the copolymer (I) having Tg (glass transition temperature) of not more than 20.degree. C., 20 to 80 parts by weight of the maleimide copolymer (II) and 15 to 75 part by weight of the graft copolymer (III) having a graft ratio of 10 to 70% so that the total amount of the copolymers (I), (II) and (III) becomes 100 parts by weight, can be obtained.

摘要翻译： 一种热塑性树脂组合物，其弯曲强度，弯曲模量和拉伸强度等低刚性，高抗冲击性，冲击时的低应力和较大的能量吸收，高耐热变形性和优异的成型性，并且包括5至65 Tg（玻璃化转变温度）为20℃以下的共聚物（I）的重量，马来酰亚胺共聚物（II）20〜80重量份，接枝共聚物（III）15〜75重量份， 接枝率为10〜70％，可以得到共聚物（I），（II）和（III）的总量为100重量份。