公开(公告)号：US09259726B2

公开(公告)日：2016-02-16

申请号：US14114717

申请日：2012-05-25

Applicant: Srikant Gopal ,  Lakshmi N. Vutukuru Murthy ,  Arun G. Basrur

Inventor： Srikant Gopal ,  Lakshmi N. Vutukuru Murthy ,  Arun G. Basrur

IPC: B01J31/00 ,  B01J27/055 ,  B01J23/32 ,  B01J31/22 ,  B01J23/00 ,  B01J23/68 ,  B01J37/02 ,  C07D301/10 ,  C07C29/10 ,  C07C41/02 ,  C07C68/00 ,  C07C213/02 ,  C07D301/04 ,  C07D301/03

CPC classification number: C07D301/04 ,  B01J23/002 ,  B01J23/688 ,  B01J27/055 ,  B01J31/2213 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/024 ,  B01J2523/00 ,  C07C29/106 ,  C07C41/02 ,  C07C68/00 ,  C07C213/02 ,  C07D301/10 ,  Y02P20/52 ,  B01J2523/11 ,  B01J2523/12 ,  B01J2523/15 ,  B01J2523/18 ,  B01J2523/72 ,  B01J2523/74

Abstract: A method for producing epoxidation catalysts is provided. The catalyst comprises a support, a catalytic species, maganese and at least one alkali metal and/or promoter. The catalytic species may be silver. The catalyst is prepared by a method wherein at least a portion of the manganese is impregnated in a step separate from the at least one alkali metal and/or promoter. Advantageously, catalysts produced by the present method may exhibit greater efficiencies than catalysts produced by conventional methods. A method for the epoxidation of alkylenes using the catalysts so produced is provided as is a method for using the alkylene oxides for the production of 1,2-diols, 1,2-carbonates, 1,2-diol ethers, or alka-nolamines.

Abstract translation: 提供了制备环氧化催化剂的方法。 催化剂包括载体，催化物质，锰和至少一种碱金属和/或助催化剂。 催化物质可以是银。 催化剂通过一种方法制备，其中至少一部分锰以与至少一种碱金属和/或助催化剂分离的步骤浸渍。 有利地，通过本方法生产的催化剂可以表现出比通过常规方法生产的催化剂更高的效率。 提供使用如此制备的催化剂来环氧化亚烷基的方法，就是使用环氧烷生产1,2-二醇，1,2-碳酸酯，1,2-二醇醚或烷醇胺的方法 。

公开(公告)号：US20140107356A1

公开(公告)日：2014-04-17

申请号：US14114717

申请日：2012-05-25

Applicant: Srikant Gopal ,  Lakshmi N. Vutukuru Murthy ,  Arun G. Basrur

Inventor： Srikant Gopal ,  Lakshmi N. Vutukuru Murthy ,  Arun G. Basrur

IPC: B01J31/22 ,  C07C213/02 ,  C07C41/02 ,  C07C68/00 ,  C07D301/04 ,  C07C29/10

CPC classification number: C07D301/04 ,  B01J23/002 ,  B01J23/688 ,  B01J27/055 ,  B01J31/2213 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/024 ,  B01J2523/00 ,  C07C29/106 ,  C07C41/02 ,  C07C68/00 ,  C07C213/02 ,  C07D301/10 ,  Y02P20/52 ,  B01J2523/11 ,  B01J2523/12 ,  B01J2523/15 ,  B01J2523/18 ,  B01J2523/72 ,  B01J2523/74

Abstract: A method for producing epoxidation catalysts is provided. The catalyst comprises a support, a catalytic species, maganese and at least one alkali metal and/or promoter. The catalytic species may be silver. The catalyst is prepared by a method wherein at least a portion of the manganese is impregnated in a step separate from the at least one alkali metal and/or promoter. Advantageously, catalysts produced by the present method may exhibit greater efficiencies than catalysts produced by conventional methods. A method for the epoxidation of alkylenes using the catalysts so produced is provided as is a method for using the alkylene oxides for the production of 1,2-diols, 1,2-carbonates, 1,2-diol ethers, or alka-nolamines.

Abstract translation: 提供了制备环氧化催化剂的方法。 催化剂包括载体，催化物质，锰和至少一种碱金属和/或助催化剂。 催化物质可以是银。 催化剂通过一种方法制备，其中至少一部分锰以与至少一种碱金属和/或助催化剂分离的步骤浸渍。 有利地，通过本方法生产的催化剂可以表现出比通过常规方法生产的催化剂更高的效率。 提供使用如此制备的催化剂来环氧化亚烷基的方法，就是使用环氧烷生产1,2-二醇，1,2-碳酸酯，1,2-二醇醚或烷醇胺的方法 。

公开(公告)号：US08987483B2

公开(公告)日：2015-03-24

申请号：US13994233

申请日：2011-12-01

Applicant: Arun G. Basrur ,  Ravindra R. Tupe ,  Hwaili Soo ,  Paul V. Hinman

Inventor： Arun G. Basrur ,  Ravindra R. Tupe ,  Hwaili Soo ,  Paul V. Hinman

IPC: C07D301/03 ,  C07D301/10

CPC classification number: C07D301/10 ,  Y02P20/582

Abstract: A method for starting-up a high efficiency alkylene oxide catalyst is described. A feed gas comprising an alkylene, oxygen, and at least one organic chloride is introduced to the catalyst. The molar ratio of oxygen to alkylene, reaction temperature, and overall chloriding effectiveness are adjusted to specified ranges of values within a specified catalyst aging period.

Abstract translation: 描述了一种启动高效环氧烷催化剂的方法。 将包含亚烷基，氧和至少一种有机氯化物的进料气体引入催化剂中。 氧气与亚烷基的摩尔比，反应温度和总氯化效果在规定的催化剂老化时段内调整到规定的数值范围。

公开(公告)号：US20140024846A1

公开(公告)日：2014-01-23

申请号：US13994233

申请日：2011-12-01

Applicant: Arun G. Basrur ,  Ravindra R. Tupe ,  Hwaili Soo ,  Paul V. Hinman

Inventor： Arun G. Basrur ,  Ravindra R. Tupe ,  Hwaili Soo ,  Paul V. Hinman

IPC: C07D301/10

CPC classification number: C07D301/10 ,  Y02P20/582

Abstract: A method for starting-up a high efficiency alkylene oxide catalyst is described. A feed gas comprising an alkylene, oxygen, and at least one organic chloride is introduced to the catalyst. The molar ratio of oxygen to alkylene, reaction temperature, and overall chloriding effectiveness are adjusted to specified ranges of values within a specified catalyst aging period.

Abstract translation: 描述了一种启动高效环氧烷催化剂的方法。 将包含亚烷基，氧和至少一种有机氯化物的进料气体引入催化剂中。 氧气与亚烷基的摩尔比，反应温度和总氯化效果在规定的催化剂老化时段内调整到规定的数值范围。