摘要:
The present invention relates to hybrid organic-inorganic polyisocyanates based on polyfunctional organosilanes, metal alkoxides and alkoxysilane-containing blocked polyisocyanates for the preparation of organic-inorganic coating compositions and adhesives.
摘要:
The present invention relates to weathering-stable mixtures for preparing organic-inorganic (hybrid) transparent topcoat materials. The hybrid composition comprises an inorganic binder based on polyfunctional organosilanes which contain at least 2 silicon atoms having in each case 1 to 3 alkoxy or hydroxyl groups, the silicon atoms being attached by in each case at least one Si—C bond to a structural unit that links the silicon unit; (semi)metal alkoxides and/or hydrolysis and concentration products of these; inorganic UV absorbers selected from the group consisting of ZnO and CeO2; an organic polyol; and one or more solvents.
摘要:
The present invention relates to hybrid organic-inorganic polyisocyanates for the preparation of organic-inorganic coating compositions and adhesives.
摘要:
Coating compositions comprising polyisocyanates, aliphatic oligocarbonate polyols and polyacrylate polyols are provided. The compositions comprise A) a polyol component composed of a) 1% to 50% by weight of aliphatic oligocarbonate polyols having a number-average molecular weight Mn of 200 to 5000 g/mol and b) 50% to 99% by weight of hydroxy-functional polyacrylate polyols; and B) one or more OH-reactive (poly)isocyanate crosslinkers having an average NCO functionality of ≧2.0. A process for preparing the coatings are also provided.
摘要:
The invention relates to a primer containing a solvent-containing two-component polyurethane binder comprising I) a curing component (A), comprising an addition product of at least one organic polyisocyanate (B) with an average NCO functionality of 2.5 to 5.0 and an isocyanate content of 8 to 27 wt. % and an alkoxysilane (C) of formula (I) with at least one isocyanate-reactive group, Q—Z—SiXaY3−a (I), in which Q represents an isocyanate-reactive group, Z represents a linear or branched C1-C12 alkylene group, X represents a hydrolyzable group, Y represents identical or different C1-C4 alkyl groups and a is an integer from 1 to 3, and II) a lacquer resin (D) which can react with isocyanate groups as adhesion promoter.
摘要:
The present invention relates to aqueous copolymer dispersions containing A) one or more hydroxy-functional copolymers synthesized from a) one or more OH-free (meth)acrylic esters and/or vinylaromatics, b) one or more hydroxy-functional (meth)acrylic esters, c) one or more ionic and/or potential ionic monomers capable of free-radical copolymerization, and d) one or more optionally monomers other than components a) to c) that are capable of free-radical copolymerization, and B) one or more hydroxy-functional polycarbonate polyols as reactive diluent. The present invention also relates to a process for preparing these aqueous copolymer dispersions and to their use in coating compositions.
摘要:
The present invention relates to aqueous copolymer dispersions containing A) one or more hydroxy-functional copolymers synthesized from a) one or more OH-free (meth)acrylic esters and/or vinylaromatics, b) one or more hydroxy-functional (meth)acrylic esters, c) one or more ionic and/or potential ionic monomers capable of free-radical copolymerization, and d) one or more optionally monomers other than components a) to c) that are capable of free-radical copolymerization, and B) one or more hydroxy-functional polycarbonate polyols as reactive diluent. The present invention also relates to a process for preparing these aqueous copolymer dispersions and to their use in coating compositions.
摘要:
Processes for preparing siloxane-modified polyisocyanates, the processes comprising: providing a polyisocyanate reactant; and reacting the polyisocyanate reactant with a hydroxyl-containing siloxane having a number-average molecular weight of 200 to 3000 g/mol and an average OH functionality of greater than or equal to 1.8, and corresponding to the general formula (I): wherein X represents an aliphatic, unbranched or branched C1 to C20 radical optionally containing ether groups; R represents a hydroxyl-functional radical; R1 represents a hydrogen or an optionally heteroatom-containing C1 to C20 hydrocarbon radical; and n is 1 to 40; siloxane-modified polyisocyanates prepared thereby, and uses therefor.
摘要:
The present invention relates to innovative, nanoparticle-modified polyisocyanates, a process for their preparation and to their use in coating compositions and adhesives. The process comprises the steps of 1) reacting A) polyisocyanates with B) alkoxysilanes, and subsequently 2) incorporating by dispersion inorganic particles, optionally surface modified, having an average particle size of less than 200 nm as determined by means of dynamic light scattering in dispersion, where the alkoxysilanes are according to formula (I) Q-Z—SiXaY3-a (I) in which Q is an isocyanate-reactive group, X is a hydrolysable group, Y is identical or different alkyl groups, Z is a C1-C12 alkylene group and a is an integer from 1 to 3.
摘要:
The present invention relates to nanoparticle-modified polyisocyanates which have been modified by a special siloxane unit and consequently have improved performance properties and also storage stabilities.