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1.发明授权Triazine compounds, polymers comprising triazine structural units, and method 有权三嗪化合物，包含三嗪结构单元的聚合物和方法公开(公告)号：US07547749B2
公开(公告)日：2009-06-16
申请号：US11766122
申请日：2007-06-21
CPC分类号： C07D405/12 , C07D251/26 , C07D251/34 , C07D405/14 , C08G65/485
摘要： In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.
摘要翻译： 在各种实施方案中，本发明包含2,4,6-三取代-1,3,5-三嗪封端剂，其包含一个，两个或三个离去基团作为取代基，其中任何残留的取代基基本上与在亲核基团上反应的惰性基团 聚合物或单体，或者与聚合物或单体上的亲核基团以比任何离去基团更慢的速率反应。 本发明还包括具有用三嗪部分封端的亲核基团的聚合物或单体。 本发明的其它实施方案包括在聚合物或单体中封端亲核基团的方法，其包括将聚合物或单体与含三嗪的封端剂混合并使其反应。
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2.发明授权Triazine compounds, polymers comprising triazine structural units, and method 有权三嗪化合物，包含三嗪结构单元的聚合物和方法公开(公告)号：US07235611B2
公开(公告)日：2007-06-26
申请号：US10672789
申请日：2003-09-26
CPC分类号： C07D405/12 , C07D251/26 , C07D251/34 , C07D405/14 , C08G65/485
摘要： In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.
摘要翻译： 在各种实施方案中，本发明包含2,4,6-三取代-1,3,5-三嗪封端剂，其包含一个，两个或三个离去基团作为取代基，其中任何残留的取代基基本上与在亲核基团上反应的惰性基团 聚合物或单体，或者与聚合物或单体上的亲核基团以比任何离去基团更慢的速率反应。 本发明还包括具有用三嗪部分封端的亲核基团的聚合物或单体。 本发明的其它实施方案包括在聚合物或单体中封端亲核基团的方法，其包括将聚合物或单体与含三嗪的封端剂混合并使其反应。
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公开(公告)号：US06653434B2
公开(公告)日：2003-11-25
申请号：US10026276
申请日：2001-12-19
IPC分类号： C08G6400
CPC分类号： G06F11/0793 , G06F11/0709 , H04L41/0631 , H04L41/0659 , H04L41/0893
摘要： A process for the production of polycarbonate by melt-polycondensing an aromatic dihydroxy compound and diphenylcarbonate, the process comprising adding the to polycarbonate under melt conditions a compound of the formula (1): wherein R1 and R3 may be the same or different and are selected from the group consisting of alkoxy, phenoxy, benzoxy, aryloxy, phenyl and aryl groups, R2 is selected from the group consisting of alkyl, phenyl, aryl, or aralkyl groups.
摘要翻译： 一种通过使芳族二羟基化合物和二苯基碳酸酯熔融缩聚制备聚碳酸酯的方法，该方法包括在熔融条件下向聚碳酸酯中加入式（1）化合物：其中R 1和R 3可以相同或不同并被选择 苯氧基，苯氧基，芳氧基，苯基和芳基，R2选自烷基，苯基，芳基或芳烷基。
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公开(公告)号：US06590068B2
公开(公告)日：2003-07-08
申请号：US09683064
申请日：2001-11-14
IPC分类号： C08F600
CPC分类号： C08G64/307
摘要： Polycarbonate resin containing reduced levels of reaction by-products can be prepared by adding to the polycarbonate a scavenging agent having the formula: wherein R1 is alkoxy, phenoxy, benzyloxy or phenyl, and R2 is a substituted or unsubstituted C1-C30 alkyl group, C6-C30 aryl group, C7-C30 aralkyl group or C6-C30 aryloxy group and processing the resulting mixture at an elevated temperature and for a period of time such that the scavenging agent reacts with linear Fries products to produce capped linear Fries products, and with residual phenols (monohydric or dihydric) to produce capped phenols and ortho-substituted phenols.
摘要翻译： 含有降低反应副产物含量的聚碳酸酯树脂可以通过向聚碳酸酯中加入具有下式的清除剂来制备：其中R1是烷氧基，苯氧基，苄氧基或苯基，R2是取代或未取代的C1-C30烷基，C6 -C30芳基，C7-C30芳烷基或C6-C30芳氧基，并在升高的温度下处理所得混合物一段时间，使得清除剂与线性Fries产物反应以产生封端的线性Fries产品，并且 残留酚（一元或二元）以产生封端的酚和邻位取代的酚。
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公开(公告)号：US07259223B2
公开(公告)日：2007-08-21
申请号：US10802705
申请日：2004-03-17
IPC分类号： C08G64/00
CPC分类号： C08G64/14 , C08G64/307
摘要： A process for the production of polycarbonate having increased end-cap levels, the process comprising adding a terminal blocking agent of the formula: wherein R1 is a propoxy or butoxy and R2 is selected from the group consisting of C1-C30 alkyl, C1-C30 alkoxy, C6-C30 aryl, C7-C30 aralkyl, and C6-C30 aryloxy.
摘要翻译： 一种生产具有增加的端帽水平的聚碳酸酯的方法，该方法包括加入下式的封端剂：其中R 1是丙氧基或丁氧基，R 2是 >选自C 1 -C 30烷基，C 1 -C 30烷氧基，C 1 -C 30烷基， C 6 -C 30芳基，C 7 -C 30芳烷基和C 6 - 仲-C 30芳氧基。
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6.发明授权公开(公告)号：US06500914B1
公开(公告)日：2002-12-31
申请号：US09682724
申请日：2001-10-10
IPC分类号： C08G6400
摘要： A method for end-capping polycarbonate resins, comprising the step of processing a mixture comprising a polycarbonate having free hydroxyl-end groups and an end-capping reagent in a melt transesterification reaction to produce a polycarbonate resin, wherein the end-capping reagent comprises a mixture of:(a) at least one species of a symmetrical activated aromatic carbonate, and (b) at least one species of a symmetrical non-activated aromatic carbonate, whereby said end-capping reagent reacts with at least some of the free hydroxyl end-groups of the polycarbonate to produce an end-capped polycarbonate resin.
摘要翻译： 一种封端聚碳酸酯树脂的方法，包括在熔融酯交换反应中处理包含游离羟基端基的聚碳酸酯和封端剂的混合物以制备聚碳酸酯树脂的步骤，其中封端剂包括 混合物：（a）至少一种对称活性芳族碳酸酯，和（b）至少一种对称非活化芳族碳酸酯，其中所述封端剂与至少一些游离羟基末端反应 的聚碳酸酯组，以制备端封聚碳酸酯树脂。
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公开(公告)号：US06620902B2
公开(公告)日：2003-09-16
申请号：US10063282
申请日：2002-04-08
申请人： Tomoaki Shimoda , Akio Ikeda , Takato Kimura , Ken Tamada , Hans-Peter Brack , Dennis Karlik , Lina Prada , Hendricus Franciscus Zirkzee , James Anthony Cella
发明人： Tomoaki Shimoda , Akio Ikeda , Takato Kimura , Ken Tamada , Hans-Peter Brack , Dennis Karlik , Lina Prada , Hendricus Franciscus Zirkzee , James Anthony Cella
IPC分类号： C08G6400
CPC分类号： C08G64/14 , C08G64/205 , C08G64/307 , C08G64/42
摘要： A process for preparing an end-capped polycarbonate comprises melt reacting an aromatic dihydroxy compound, a carbonic acid diester, and optionally a catalyst in a prepolymerization vessel to form a polycarbonate product; transferring the polycarbonate product from the prepolymerization vessel; mixing the polycarbonate product with an end-capping agent under hermetic seal at a pressure of at least about 760 mm Hg; and transferring the polycarbonate product and end-capping agent mixture to a postpolymerization vessel to endcap the polycarbonate product. An apparatus for preparing an end-capped polycarbonate comprises a prepolymerization vessel having and inlet and an outlet; a postpolymerization vessel having an inlet and an outlet; a mixer in fluid communication with the outlet of the prepolymerization vessel and the inlet of the postpolymerization vessel; and a charging port through which an end-capping agent is charged to the mixer, wherein the mixer is hermetically sealed at greater than or equal to 760 mm Hg.
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公开(公告)号：US07645851B2
公开(公告)日：2010-01-12
申请号：US11688551
申请日：2007-03-20
申请人： Sjef Berndsen , Hans Peter Brack , Bernd Jansen , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Dennis Karlik , Gerardo Hidalgo Llinas
发明人： Sjef Berndsen , Hans Peter Brack , Bernd Jansen , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Dennis Karlik , Gerardo Hidalgo Llinas
摘要： A method of making polycarbonate includes the steps of forming polycarbonate by a melt transesterification method using an activated diaryl carbonate, and compounding the polycarbonate with a phosphorus-containing compound that has an abstractable proton or hydrolyzable group. The phosphorus-containing compound is compounded with the polycarbonate in an amount sufficient to result in an improvement in the color properties of the polycarbonate as compared to pellets formed from the same polycarbonate without addition of the phosphorus-containing compound.
摘要翻译： 制备聚碳酸酯的方法包括通过使用活化的碳酸二芳基酯的熔体酯交换法形成聚碳酸酯的步骤，并将聚碳酸酯与具有可抽提的质子或可水解基团的含磷化合物混合。 含磷化合物与聚碳酸酯混合，其量足以导致与不加入含磷化合物相同的聚碳酸酯形成的粒料相比，聚碳酸酯的着色性能得到改善。
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公开(公告)号：US20060074216A1
公开(公告)日：2006-04-06
申请号：US10938337
申请日：2004-09-10
申请人： Hans-Peter Brack , Dennis Karlik , Jan Lens
发明人： Hans-Peter Brack , Dennis Karlik , Jan Lens
IPC分类号： C08G64/00
CPC分类号： C08G64/42 , C08G2650/04
摘要： Alkyl ester end-capped polycarbonates have improved release properties and may be produced by a method comprising the step of combining a polycarbonate having free terminal OH groups with an end-capping reagent comprising a symmetrical activated carbonate and an alkyl ester, whereby the end-capping reagent reacts with at least some of the free hydroxyl end groups of the polycarbonate to produce an end-capped polycarbonate comprising optionally substituted aliphatic ester end groups.
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10.发明授权Method and system for preparing a polycarbonate, copolymerization reagent and polycarbonate 失效制备聚碳酸酯，共聚试剂和聚碳酸酯的方法和系统公开(公告)号：US06747119B2
公开(公告)日：2004-06-08
申请号：US10107149
申请日：2002-03-28
IPC分类号： C08G6400
CPC分类号： C08G63/64 , C08G64/307
摘要： A method for preparing a polycarbonate comprises preparing a free hydroxyl-containing polycarbonate and reacting the hydroxyl-containing polycarbonate with a mixture of (B) a symmetrical optionally activated aromatic carbonic acid diester and (C) an optionally substituted aromatic hihydroxy compound, diol or diacid. A copolymerization reagent comprises a mixture of (B) a symmetrical optionally activated aromatic carbonic acid diester and (C) an optionally substituted aromatic hihydroxy compound, diol or diacid. A copolymer comprises [polycarbonate]x moieties; (B) [symmetrical optionally activated aromatic carbonic acid diester]y moieties and (C) [optionally substituted aromatic hihydroxy compound, diol or diacid]z moieties, wherein x, y and z are mole percents of the copolymer.
摘要翻译： 制备聚碳酸酯的方法包括制备游离含羟基的聚碳酸酯并使含羟基的聚碳酸酯与（B）对称的任选活化的芳族碳酸二酯和（C）任选取代的芳族羟基化合物，二醇或二酸的混合物 。 共聚试剂包括（B）对称的任选活化的芳族碳酸二酯和（C）任选取代的芳族羟基化合物，二醇或二酸的混合物。 共聚物包含[聚碳酸酯] x部分; （B）[对称任选活化的芳族碳酸二酯] y部分和（C）[任选取代的芳族羟基化合物，二醇或二酸] z部分，其中x，y和z是共聚物的摩尔百分比。
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