公开(公告)号：US20160297838A1

公开(公告)日：2016-10-13

申请号：US15037954

申请日：2014-11-19

Applicant: THE TRUSTEES OF PRINCETON UNIVERSITY

Inventor： Paul J. CHIRIK ,  Tianning DIAO ,  Renyuan YU

IPC: C07F5/02 ,  C07F15/06 ,  B01J31/18

CPC classification number: C07F5/025 ,  B01J31/183 ,  B01J31/2295 ,  B01J2231/14 ,  B01J2231/323 ,  B01J2531/845 ,  C07F7/0838 ,  C07F7/0879 ,  C07F7/1804 ,  C07F7/1876 ,  C07F15/06 ,  C07F19/00

Abstract: In one aspect, cobalt complexes are described herein. In some embodiments, such cobalt complexes are operable as catalysts for hydroboration and borylation applications.

Abstract translation: 在一个方面，本文描述了钴络合物。 在一些实施方案中，这种钴络合物可用作用于硼氢化和硼化应用的催化剂。

公开(公告)号：US20170266648A1

公开(公告)日：2017-09-21

申请号：US15329919

申请日：2015-07-29

Applicant: THE TRUSTEES OF PRINCETON UNIVERSITY

Inventor： Paul CHIRIK ,  Renyuan YU

IPC: B01J31/22 ,  C07F15/02 ,  C07B59/00 ,  B01J31/18

CPC classification number: B01J31/2295 ,  B01J31/1805 ,  B01J31/181 ,  B01J2231/46 ,  B01J2531/842 ,  B01J2531/845 ,  C07B59/00 ,  C07B59/004 ,  C07B2200/05 ,  C07F15/02

Abstract: Methods of isotopic labeling are described herein. For example, a method of isotopically labeling an organic compound, in some embodiments, comprises providing a reaction mixture including the organic compound, an iron complex or a cobalt complex and a source of deuterium or tritium. The organic compound is labeled with deuterium or tritium in the presence of the iron complex or cobalt complex or derivative of the iron complex or cobalt complex.