Abstract:
An object of the present invention is to provide a positive electrode mixture capable of conducting stable charging and discharging with a less amount of gasses generated which has an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium. The present invention relates to a positive electrode mixture comprising carbon black having a bulk density of not more than 0.1 g/cm3, a crystallite size of 10 to 40 Å, an iodine adsorption of 1 to 150 mg/g, a volatile content of not more than 0.1% and a metal impurity content of not more than 20 ppm, and a positive electrode active substance having an operating voltage or an initial crystal phase transition voltage of not less than 4.5 V on the basis of lithium.
Abstract translation:本发明的目的是提供一种正极混合物,其能够以较少量的气体进行稳定的充放电,其具有基于锂的工作电压或不小于4.5V的初始晶体相变电压 。 本发明涉及包含炭黑的正极混合物,其堆积密度不大于0.1g / cm 3,微晶尺寸为10至40,碘吸附为1至150mg / g,挥发物含量不为 大于0.1%,金属杂质含量为20ppm以下,以锂为基准的工作电压或初期晶体相变电压为4.5V以上的正极活性物质。