METHOD FOR PRODUCING ISOBUTYLENE FROM ISOBUTANOL
    4.
    发明申请
    METHOD FOR PRODUCING ISOBUTYLENE FROM ISOBUTANOL 审中-公开
    从ISOBUTANOL生产异丁烯的方法

    公开(公告)号:US20170050896A1

    公开(公告)日:2017-02-23

    申请号:US15307614

    申请日:2015-05-01

    IPC分类号: C07C1/24

    摘要: The purpose of the present invention is to provide a method that can produce, with high yield or high selectivity isobutylene by means of isobutanol dehydration-reaction. An isobutylene production method of a first embodiment of the present invention is a method for producing isobutylene by means of isobutanol dehydration-reaction, wherein isobutanol is reacted using a catalyst for which the BET specific surface area is within the range of 60 m2/g-175 m2/g, and the reaction is carried out under a reaction pressure of 50 kPa-750 kPa as the absolute pressure. An isobutylene production method of a second embodiment of the present invention includes: using a catalyst which is filled into a reaction chamber and for which the particle diameters of at least 90 mass % of the catalyst are within the range of 700 μm-1000 μm; setting the isobutanol concentration within a supplied reaction gas to 30 vol %-85 vol %; setting the weight hourly velocity (WHSV) of the isobutanol to 0.175 h−1˜20 h−1; and reacting isobutanol under a reaction pressure of 50 kPa-750 kPa as the absolute pressure.

    摘要翻译: 本发明的目的是提供一种通过异丁醇脱水反应生产高产率或高选择性的异丁烯的方法。 本发明的第一实施方式的异丁烯制造方法是通过异丁醇脱水反应制造异丁烯的方法,其中异丁醇与BET比表面积在60m 2 / g〜 175m 2 / g,反应在绝对压力50kPa-750kPa的反应压力下进行。 本发明的第二实施方式的异丁烯制造方法包括:使用填充到反应室中的催化剂,其催化剂的至少90质量%的粒径在700μm〜1000μm的范围内; 将所提供的反应气体中的异丁醇浓度设定为30vol%-85vol%; 将异丁醇的重量小时速度(WHSV)设定为0.175h -1〜20h -1; 并在50kPa-750kPa的反应压力下使异丁醇作为绝对压力。