公开(公告)号：US10071339B2

公开(公告)日：2018-09-11

申请号：US14402559

申请日：2013-05-23

申请人： TOTAL S.A.

发明人： Claire Weiss ,  Renaud Cadours ,  Jing Zhao ,  Virenkumar Shah

IPC分类号： B01D53/14 ,  B01D53/52 ,  C10L3/10 ,  C10L3/12

CPC分类号： B01D53/1493 ,  B01D53/1425 ,  B01D53/1462 ,  B01D2252/103 ,  B01D2252/2023 ,  B01D2252/20431 ,  B01D2252/20447 ,  B01D2252/20489 ,  B01D2252/2056 ,  B01D2252/504 ,  B01D2252/602 ,  B01D2257/306 ,  B01D2257/308 ,  C10L3/102 ,  C10L3/103 ,  C10L3/104 ,  C10L3/12 ,  C10L2290/541

摘要： A process is disclosed for purifying a gaseous mixture containing acidic gases, such as a natural gas, including contacting the gaseous mixture with an absorbent solution including: from 35% to 45% by weight of at least one tertiary amine relative to the total weight of the absorbent solution; from 4% to 12% by weight of at least one activator relative to the total weight of the absorbent solution selected from the primary amines and the secondary amines, the total content of tertiary amine and activator being from 38% to 50% by weight relative to the total weight of the absorbent solution, and the total concentration of tertiary amine and activator being between 3.8 and 4.2 mol/L; from 17% to 25% by weight of at least one C2 to C4 thioalkanol relative to the total weight of the absorbent solution; and the remainder being water to reach 100% by weight.

公开(公告)号：US20150139877A1

公开(公告)日：2015-05-21

申请号：US14402559

申请日：2013-05-23

申请人： TOTAL S.A.

发明人： Claire Weiss ,  Renaud Cadours ,  Jing Zhao ,  Virenkumar Shah

IPC分类号： B01D53/14 ,  C10L3/10

CPC分类号： B01D53/1493 ,  B01D53/1425 ,  B01D53/1462 ,  B01D2252/103 ,  B01D2252/2023 ,  B01D2252/20431 ,  B01D2252/20447 ,  B01D2252/20489 ,  B01D2252/2056 ,  B01D2252/504 ,  B01D2252/602 ,  B01D2257/306 ,  B01D2257/308 ,  C10L3/102 ,  C10L3/103 ,  C10L3/104 ,  C10L3/12 ,  C10L2290/541

摘要： A process is disclosed for purifying a gaseous mixture containing acidic gases, such as a natural gas, including contacting the gaseous mixture with an absorbent solution including: from 35% to 45% by weight of at least one tertiary amine relative to the total weight of the absorbent solution; from 4% to 12% by weight of at least one activator relative to the total weight of the absorbent solution selected from the primary amines and the secondary amines, the total content of tertiary amine and activator being from 38% to 50% by weight relative to the total weight of the absorbent solution, and the total concentration of tertiary amine and activator being between 3.8 and 4.2 mol/L; from 17% to 25% by weight of at least one C2 to C4 thioalkanol relative to the total weight of the absorbent solution; and the remainder being water to reach 100% by weight.

摘要翻译： 公开了一种用于纯化含有酸性气体（例如天然气）的气体混合物的方法，包括使气体混合物与吸收剂溶液接触，包括：相对于 吸收剂溶液; 相对于选自伯胺和仲胺的吸收剂溶液的总重量，4重量％至12重量％的至少一种活化剂，叔胺和活化剂的总含量相对于38重量％至50重量％ 相对于吸收剂溶液的总重量，叔胺和活化剂的总浓度在3.8和4.2mol / L之间; 相对于吸收剂溶液的总重量，17重量％至25重量％的至少一种C2至C4硫代链烷醇; 其余为水达到100重量％。

公开(公告)号：US20150147254A1

公开(公告)日：2015-05-28

申请号：US14402515

申请日：2013-05-23

申请人： TOTAL S.A.

发明人： Claire Weiss ,  Renaud Cadours ,  Jing Zhao ,  Virenkumar Shah ,  Serge Capdeville

IPC分类号： B01D53/14 ,  C10L3/10 ,  B01D53/52

CPC分类号： B01D53/1468 ,  B01D53/1425 ,  B01D53/1462 ,  B01D53/1493 ,  B01D53/52 ,  B01D2252/20405 ,  B01D2252/20431 ,  B01D2252/20484 ,  B01D2252/20489 ,  B01D2252/2056 ,  B01D2252/504 ,  B01D2252/60 ,  B01D2252/602 ,  B01D2257/304 ,  B01D2257/306 ,  B01D2257/308 ,  C10L3/103 ,  C10L2290/12 ,  C10L2290/541 ,  Y02C10/06

摘要： A process for selectively removing hydrogen sulphide relative to carbon dioxide from a gaseous mixture containing at least hydrogen sulphide H2S and carbon dioxide CO2, includes a step of contacting the gaseous mixture with an absorbent solution including at least one amine, water, and at least one C2 to C4 thioalkanol. A use of the absorbent solution for selectively removing hydrogen sulphide relative to carbon dioxide from a gaseous mixture containing at least hydrogen sulphide and carbon dioxide, is disclosed. Disclosed is a use of at least one C2 to C4 thioalkanol as an additive in an absorbent solution including at least one amine, and water, for increasing the selectivity of the absorbent solution for the removal of hydrogen sulphide relative to carbon dioxide from a gaseous mixture containing at least hydrogen sulphide and carbon dioxide.

摘要翻译： 从至少包含硫化氢H 2 S和二氧化碳CO 2的气体混合物中相对于二氧化碳选择性除去硫化氢的方法包括使气体混合物与包含至少一种胺，水和至少一种 C2至C4硫烷醇。 公开了使用吸收剂溶液从至少包含硫化氢和二氧化碳的气体混合物中相对于二氧化碳选择性地除去硫化氢。 公开了至少一种C2至C4硫代链烷醇作为添加剂在包含至少一种胺和水的吸收剂溶液中的用途，用于提高吸收剂溶液相对于二氧化碳从气体混合物中除去硫化氢的选择性 至少含有硫化氢和二氧化碳。