摘要:
The present invention relates to a nonaqueous electrolyte secondary battery, and more particularly to its separator, and it is an object thereof to prevent electrolyte leakage accident due to elevation of cell internal pressure even if the cell is exposed to high temperature without sacrificing the cell capacity. To achieve the object, by using the polyolefin group separator large in endothermic calorie per unit area by the heat of fusion in a temperature range of 70 to 150° C., and selecting appropriate graphite powder for negative electrode and organic solvent in nonaqueous electrolyte, the electrolyte leakage accident can be successfully eliminated by suppressing the reaction between the cell active substance and organic solvent, thereby suppressing elevation of cell internal pressure.
摘要:
Graphite powder for a negative electrode in prior arts, which allows lithium ions to repeat intercalation and deintercalation reversibly by charge and discharge, has failed to attain a specific capacity close to the theoretical capacity of 372 mAh per 1 g. Also, there was a problem in storage property at a high temperature when it is attempted to improve the high rate charge and discharge characteristics. An object of the present invention is to solve these problems. In the process of pulverizing flaky graphite particles of which plane interval (d002) of (002) plane is 3.350 to 3.360 angstroms, and crystallite size (Lc) in the C-axis direction is at least 1000 angstroms or more, the graphite particles are chamfered into disk- or tablet-like form, which are then sifted, so as to obtain a graphite powder, of which mean particle size is defined within the range of 10 to 30 microns, mean thickness of thinnest portion is defined to be 3 to 9 microns, and X-ray diffraction peak intensity ratio of (110)/(004) by a wide angle X-ray diffraction method is defined to be 0.015 or more. By using this powder, the conventional problems are solved in a favorable balance, and, while achieving high energy density, the high rate discharge performance and reliability when left at a high temperature can be enhanced.
摘要:
The present invention relates to a lithium ion secondary battery using as the negative active material thereof a carbon material that enables the absorption and release of lithium ions and has volume resistivity not exceeding 5.0×10−3 ohmcm, thereby preventing battery temperatures from increasing abruptly due to low volume resistivity of the carbon material even when short-circuiting takes place inside of the battery.
摘要:
The present invention relates to an apparatus for evaluating an internal short circuit of a battery. An object of the invention is to provide an apparatus capable of evaluating whether or not an internal short circuit has occurred in an electrode group in consideration of pressure applied to the electrode group. An internal short circuit evaluation apparatus according to one embodiment of the invention includes at least a pressure member capable of operating independently and applying pressure to at least a predetermined position of the surface of the electrode group, and a short-circuiting member that is pressed into the predetermined position. An internal short circuit evaluation apparatus according to another embodiment of the invention includes a pressure member having an integrated short-circuiting member.
摘要:
Disclosed is a battery 10 including: an electrode group including a positive electrode, a negative electrode, and a separator; an electrolyte; and a battery container accommodating the electrode group and the electrolyte. The battery container includes an accommodating portion 16 having an opening, and a lid sealing the opening of the accommodating portion 16. The battery container includes a liquid-retaining portion 16a retaining the electrolyte therein below the liquid surface of the electrolyte, and a gas-retaining portion 16b retaining gas therein above the liquid surface of the electrolyte. The liquid-retaining portion 16a of the side portion of the battery container is thinner than the gas-retaining portion 16b of the battery container. This suppresses scattering of fragments etc. in the event of rupture of a secondary battery due to an increase in the internal pressure. The safety of the secondary battery is thus increased.
摘要:
A lithium secondary battery including: an electrode group, a non-aqueous electrolyte and a battery case housing the electrode group and the non-aqueous electrolyte, the electrode group including a positive electrode, a negative electrode and a separator layer interposed between the positive electrode and the negative electrode, wherein an end-of-charge voltage and an end-of-discharge voltage are set in such a manner that the electrode group has an energy density of not less than 700 Wh/L, the separator layer includes a porous heat-resistant layer, and a short circuit area A produced when an internal short circuit has occurred between the positive electrode and the negative electrode, and a reduced area B of the porous heat-resistant layer that is produced by heat generation satisfy 1≦(A+B)/A≦10.
摘要:
An electric power equipment has a main body case, a plurality of power supply elements provided in the main body case, and a fire-extinguishing agent discharge space disposed facing the plurality of power supply elements. The fire-extinguishing agent discharge space includes fire-extinguishing agent spray space having a plurality of fire-extinguishing agent spray holes for spraying a fire-extinguishing agent toward the plurality of power supply elements, and a fire-extinguishing agent supply space coupled to the fire-extinguishing agent spray space via a plurality of fire-extinguishing supply holes. A fire-extinguishing agent tank is coupled to the fire-extinguishing agent supply space via a shutoff valve.
摘要:
A non-aqueous electrolyte secondary battery including: a positive electrode having a positive electrode material mixture containing a composite lithium oxide; a negative electrode; a polyolefin separator; a non-aqueous electrolyte; and a heat-resistant insulating layer interposed between the positive and negative electrodes. The positive electrode active material mixture has an estimated heat generation rate at 200° C. of not greater than 50 W/kg. The estimated heat generation rate is determined by obtaining a relation between absolute temperature T and heat generation rate V of the positive electrode material mixture using an accelerating rate calorimeter; plotting a relation between the inverse of absolute temperature T and the logarithm of heat generation rate V according to the Arrhenius law; obtaining a straight line fitted to the plotted points in a heat generation temperature range of T
摘要:
An object of the present invention is to provide an electrode for a lithium ion secondary battery that can ensure a high level of safety even when exposed to severe conditions such as a nail penetration test or crush test, and exhibit excellent output characteristics.The present invention relates to an electrode for a lithium ion secondary battery having a material mixture containing active material particles capable of reversibly absorbing and desorbing lithium, and a current collector that carries the material mixture, wherein a surface of the current collector has recessed portions, and an area occupied by the recessed portions accounts for not less than 30% of an a material mixture carrying area of the current collector. The present invention further relates to an electrode for a lithium ion secondary battery wherein, in a cut surface obtained by simultaneously cutting a material mixture and a current collector vertically to an electrode plane, the maximum depth of recessed portions is not less than 1 μm, or a difference between an average thickness of a current collector and a maximum thickness of the current collector is not less than 0.35 μm.
摘要:
An evaluation method for evaluating safety of a battery having an electrode group including a positive electrode plate, a negative electrode plate and a separator inserted between said electrode plates. The method includes the steps of charging the battery to a predetermined voltage; incorporating conductive foreign matter into the charged battery such that the conductive foreign matter is in contact with the positive electrode plate, and not in contact with the negative electrode plate; immersing said battery into which the conductive foreign matter has been incorporated in an electrolyte to dissolve and deposit the conductive foreign matter, thereby causing an internal short circuit to occur in the battery; and evaluating a thermal behavior of the battery in which the internal short circuit has occurred, and outputting results of the evaluation as safety indices.