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公开(公告)号:US20110135990A1
公开(公告)日:2011-06-09
申请号:US13056912
申请日:2009-07-29
申请人: Taketsugu Yamamoto , Hideaki Nakajima , Hiroshi Inukai , Shigekazu Ohmori , Chikara Murakami , Daisuke Nakaji , Hidekazu Yoshida , Maiko Saka
发明人: Taketsugu Yamamoto , Hideaki Nakajima , Hiroshi Inukai , Shigekazu Ohmori , Chikara Murakami , Daisuke Nakaji , Hidekazu Yoshida , Maiko Saka
CPC分类号: H01M4/136 , H01M4/58 , H01M4/587 , H01M10/0569 , Y10T29/49108
摘要: Disclosed is a sodium secondary battery. The sodium secondary battery comprises a first electrode and a second electrode comprising a carbonaceous material. The carbonaceous material satisfies one or more requirements selected from the group consisting of requirements 1, 2, 3 and 4. Requirement 1: R value (=ID/IG) obtained by Raman spectroscopic measurement is 1.07 to 3. Requirement 2: A value and σA value obtained by small angle X-ray scattering measurement are −0.5 to 0 and 0 to 0.010, respectively. Requirement 3: for an electrode comprising an electrode mixture obtained by mixing 85 parts by weight of the carbonaceous material with 15 parts by weight of poly(vinylidene fluoride), the carbonaceous material in the electrode after being doped and dedoped with sodium ions is substantially free from pores having a size of not less than 10 nm. Requirement 4: Q1 value obtained by a calorimetric differential thermal analysis is not more than 800 joules/g.
摘要翻译: 公开了钠二次电池。 钠二次电池包括第一电极和包含碳质材料的第二电极。 碳质材料满足从要求1,2,3和4所选择的一个或多个要求。要求1:通过拉曼光谱测量获得的R值(= ID / IG)为1.07至3.要求2:A值和 &sgr。通过小角度X射线散射测量获得的值分别为-0.5至0和0至0.010。 要求3:对于包含通过将85重量份的碳质材料与15重量份的聚(偏二氟乙烯)混合而获得的电极混合物的电极,掺杂并掺杂了钠离子的电极中的碳质材料基本上不含 来自具有不小于10nm的尺寸的孔。 要求4:通过量热差热分析获得的Q1值不超过800焦耳/ g。
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公开(公告)号:US09899665B2
公开(公告)日:2018-02-20
申请号:US13056912
申请日:2009-07-29
申请人: Taketsugu Yamamoto , Hideaki Nakajima , Hiroshi Inukai , Shigekazu Ohmori , Chikara Murakami , Daisuke Nakaji , Hidekazu Yoshida , Maiko Saka
发明人: Taketsugu Yamamoto , Hideaki Nakajima , Hiroshi Inukai , Shigekazu Ohmori , Chikara Murakami , Daisuke Nakaji , Hidekazu Yoshida , Maiko Saka
IPC分类号: H01M4/136 , H01M4/58 , H01M4/04 , H01M4/587 , H01M10/0569
CPC分类号: H01M4/136 , H01M4/58 , H01M4/587 , H01M10/0569 , Y10T29/49108
摘要: Disclosed is a sodium secondary battery. The sodium secondary battery comprises a first electrode and a second electrode comprising a carbonaceous material. The carbonaceous material satisfies one or more requirements selected from the group consisting of requirements 1, 2, 3 and 4. Requirement 1: R value (=ID/IG) obtained by Raman spectroscopic measurement is 1.07 to 3. Requirement 2: A value and σA value obtained by small angle X-ray scattering measurement are −0.5 to 0 and 0 to 0.010, respectively. Requirement 3: for an electrode comprising an electrode mixture obtained by mixing 85 parts by weight of the carbonaceous material with 15 parts by weight of poly(vinylidene fluoride), the carbonaceous material in the electrode after being doped and dedoped with sodium ions is substantially free from pores having a size of not less than 10 nm. Requirement 4: Q1 value obtained by a calorimetric differential thermal analysis is not more than 800 joules/g.
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