公开(公告)号：US20110065871A1

公开(公告)日：2011-03-17

申请号：US12991715

申请日：2009-05-19

申请人： Tatsuya Nagano ,  Tomoko Nasuno ,  Hiroyuki Ome ,  Yong He ,  Bo Yu ,  Kexin Zhu ,  Xiao Guo ,  Pujing Zuo

发明人： Tatsuya Nagano ,  Tomoko Nasuno ,  Hiroyuki Ome ,  Yong He ,  Bo Yu ,  Kexin Zhu ,  Xiao Guo ,  Pujing Zuo

IPC分类号： C08G63/06 ,  C08L67/04

CPC分类号： C08G63/80 ,  C08G63/06 ,  C08G63/08 ,  C08G63/823 ,  C08G63/87

摘要： A method for producing an aliphatic polyester resin including a melt polymerization step and a subsequent solid phase polymerization step, using a sulfonic acid group-containing compound as a catalyst, wherein the addition amount of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a raw material monomer calculated as sulfer atoms, the content of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a produced polymer calculated as sulfer atoms, and a residual rate of the sulfonic acid group-containing compound after solid phase at polymerization is more than 50%.

摘要翻译： 一种包含熔融聚合步骤和随后的固相聚合步骤的脂族聚酯树脂的制备方法，其中使用含磺酸基化合物作为催化剂，其中在熔融聚合期间含磺酸基的化合物的加入量为300 相对于作为硫原子计算出的原料单体为3000ppm，熔融聚合时的含磺酸基的化合物的含量相对于以硫醇原子计算的制造聚合物为300〜3000ppm，残留率为 含有磺酸基团的化合物在聚合后固相超过50％。

公开(公告)号：US08173753B2

公开(公告)日：2012-05-08

申请号：US12991715

申请日：2009-05-19

申请人： Tatsuya Nagano ,  Tomoko Nasuno ,  Hiroyuki Ome ,  Yong He ,  Bo Yu ,  Kexin Zhu ,  Xiao Guo ,  Pujing Zuo

发明人： Tatsuya Nagano ,  Tomoko Nasuno ,  Hiroyuki Ome ,  Yong He ,  Bo Yu ,  Kexin Zhu ,  Xiao Guo ,  Pujing Zuo

IPC分类号： C08G63/91

CPC分类号： C08G63/80 ,  C08G63/06 ,  C08G63/08 ,  C08G63/823 ,  C08G63/87

摘要： A method for producing an aliphatic polyester resin including a melt polymerization step and a subsequent solid phase polymerization step, using a sulfonic acid group-containing compound as a catalyst, wherein the addition amount of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a raw material monomer calculated as sulfur atoms, the content of the sulfonic acid group-containing compound during melt polymerization is 300 to 3000 ppm with respect to a produced polymer calculated as sulfer atoms, and a residual rate of the sulfonic acid group-containing compound after solid phase at polymerization is more than 50.

摘要翻译： 一种包含熔融聚合步骤和随后的固相聚合步骤的脂族聚酯树脂的制备方法，其中使用含磺酸基化合物作为催化剂，其中在熔融聚合期间含磺酸基的化合物的加入量为300 相对于作为硫原子计算的原料单体，为3000ppm，熔融聚合时的含磺酸基的化合物的含量相对于作为硫原子计算出的聚合度为300〜3000ppm，残留率为 含有磺酸基团的化合物在聚合后固相超过50。