公开(公告)号：US20190055332A1

公开(公告)日：2019-02-21

申请号：US15677507

申请日：2017-08-15

申请人： The Goodyear Tire & Rubber Company

发明人： Stefan MECKING ,  Margaret Flook VIELHABER ,  Hannes LEICHT ,  Julia BAUER ,  Inigo Gottker genannt SCHNETMANN

IPC分类号： C08F36/14 ,  C08F36/06 ,  C08F36/08

CPC分类号： C08F36/14 ,  C08F4/52 ,  C08F36/06 ,  C08F36/08 ,  C08F136/06 ,  C08F136/08 ,  C08F236/045 ,  C08F236/06 ,  C08F236/08 ,  C08F236/14 ,  C08F2500/21 ,  C08F2800/20 ,  C08F2810/20 ,  G01R33/46 ,  C08F36/04 ,  C08F4/545

摘要： The present invention is directed to a stereoregular functionalized elastomer represented by poly(M1 co M2), wherein the functionalized elastomer comprises a microstructure selected from the group consisting of microstructures having at least 90 percent by weight of monomer residues in trans 1,4-configuration, and microstructures having at least 80 percent by weight of monomer residues in cis 1,4-configuration; wherein M1 is selected from the group consisting of isoprene and 1,3-butadiene; and M2 is of formula 4 wherein R6 is a covalent bond, phenylene, a linear or branched alkane diyl group containing 1 to 10 carbon atoms, or a combination of one or more phenylene groups and one or more linear or branched alkane diyl groups containing 1 to 10 carbon atoms; R7 is hydrogen or a linear or branched alkyl group containing 1 to 10 carbon atoms; X1 is selected from formulas 5 and 6 wherein R8 and R9 are independently trialkylsilyl, phenyl or a linear or branched alkyl group containing 1 to 10 carbon atoms, or one of R8 and R9 is hydrogen and the other is phenyl or a linear or branched alkyl group containing 1 to 10 carbon atoms, or R8 and R9 taken together with the nitrogen atom represent a nitrogen containing heterocyclic group containing from 4 to 12 carbon atoms; and X2 is a sulfur atom or a structure of formula 7 or 8 wherein when X2 is of formula 8, the S atom of formula 8 is adjacent to the phenyl ring of formula 6 and the N atom of formula 8 is adjacent to R6.