公开(公告)号：US20220213262A1

公开(公告)日：2022-07-07

申请号：US17703729

申请日：2022-03-24

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Jawad Naciri ,  Banahalli R. Ratna

IPC分类号： C08G61/12 ,  C08G81/00 ,  H01B1/12

摘要： An interpenetrating network (IPN) polymer membrane material includes a soft polyurethane interspersed with a crosslinked conducting polymer. The material can be reversibly “switched” between its oxidized and reduced states by the application of a small voltage, ˜1 to 4 volts, thus modulating its diffusivity.

公开(公告)号：US11299582B2

公开(公告)日：2022-04-12

申请号：US16860330

申请日：2020-04-28

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Jawad Naciri ,  Banahalli R. Ratna

IPC分类号： C08G61/12 ,  C08G81/00 ,  H01B1/12

摘要： An interpenetrating network (IPN) polymer membrane material includes a soft polyurethane interspersed with a crosslinked conducting polymer. The material can be reversibly “switched” between its oxidized and reduced states by the application of a small voltage, ˜1 to 4 volts, thus modulating its diffusivity.

公开(公告)号：US20210388162A1

公开(公告)日：2021-12-16

申请号：US17347050

申请日：2021-06-14

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Jeffrey R. Deschamps ,  Jeffrey C. DePriest ,  Ian D. Giles

IPC分类号： C08G69/12

摘要： A new, thermally stable conducting material, poly(3-amino-1H-pyrazole-4-carboxylate), can be used in a variety of applications such as thermoelectrics, electron acceptors in light-harvesting (photovoltaic) materials, and thermally stable conducting energetic materials. Related compounds include poly 3-amino-5-chloro-1H-pyrazole-4-carboxylate, poly 3-amino-5-bromo-1H-pyrazole-4-carboxylate, poly 3-amino-5-fluoro-1H-pyrazole-4-carboxylate, poly 3-amino-5-iodo-1H-pyrazole-4-carboxylate, poly 3, 5-diamino-1H-pyrazole-4-carboxylate, poly 3-amino-5-NHR1-1H-pyrazole-4-carboxylate, poly 3-amino-5-NR2-1H-pyrazole-4-carboxylate, or poly 3-amino-5-hydroxy-1H-pyrazole-4-carboxylate.

公开(公告)号：US20210070998A1

公开(公告)日：2021-03-11

申请号：US16950905

申请日：2020-11-18

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Ian D. Giles ,  Jawad Naciri ,  Paul T. Charles ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jeffrey C. Depriest

IPC分类号： C08L79/04 ,  C08G73/06 ,  C07D231/38

摘要： This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.

公开(公告)号：US11920035B2

公开(公告)日：2024-03-05

申请号：US17972968

申请日：2022-10-25

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Ian D. Giles ,  Jawad Naciri ,  Paul T. Charles ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jeffrey C. Depriest

IPC分类号： H01B1/12 ,  C07D231/38 ,  C08G61/12 ,  C08G73/06 ,  C08L79/04

CPC分类号： C08L79/04 ,  C07D231/38 ,  C08G73/0616 ,  C08L2203/204 ,  H01B1/127 ,  C08L79/04 ,  C08L65/00

摘要： This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.

公开(公告)号：US20230054994A1

公开(公告)日：2023-02-23

申请号：US17972968

申请日：2022-10-25

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Ian D. Giles ,  Jawad Naciri ,  Paul T. Charles ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jeffrey C. Depriest

IPC分类号： C08L79/04 ,  C08G73/06 ,  C07D231/38

摘要： This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.

公开(公告)号：US11608409B2

公开(公告)日：2023-03-21

申请号：US17703693

申请日：2022-03-24

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Jawad Naciri ,  Banahalli R. Ratna

IPC分类号： C08G61/12 ,  C08G81/00 ,  H01B1/12

摘要： An interpenetrating network (IPN) polymer membrane material includes a soft polyurethane interspersed with a crosslinked conducting polymer. The material can be reversibly “switched” between its oxidized and reduced states by the application of a small voltage, ˜1 to 4 volts, thus modulating its diffusivity.

公开(公告)号：US20240182714A1

公开(公告)日：2024-06-06

申请号：US18435961

申请日：2024-02-07

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Ian D. Giles ,  Jawad Naciri ,  Paul T. Charles ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jeffrey C. Depriest

IPC分类号： C08L79/04 ,  C07D231/38 ,  C08G73/06 ,  H01B1/12

CPC分类号： C08L79/04 ,  C07D231/38 ,  C08G73/0616 ,  C08L2203/204 ,  H01B1/127

摘要： This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.

公开(公告)号：US11618821B2

公开(公告)日：2023-04-04

申请号：US16950905

申请日：2020-11-18

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Ian D. Giles ,  Jawad Naciri ,  Paul T. Charles ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jeffrey C. Depriest

IPC分类号： H01B1/12 ,  C08G61/12 ,  C08L79/04 ,  C08G73/06 ,  C07D231/38

摘要： This disclosure concerns electrically conducting poly(pyrazoles). The concept of oligomerizing and polymerizing substituted aminopyrazole derivatives combined with a monomer activation procedure involving base-mediated conversion of the protonated pyrazole ring nitrogen to amine salt was developed. This disclosure concerns the specific chemistries needed for the synthesis of a pyrazole monomer used in the polymer synthesis. The procedure used for blending the novel polypyrazoles with other compounds needed for construction of solar cells for testing was developed. This disclosure concerns the concept of using these types of heteroatom-rich, electron-deficient oligomers or polymers as n-dopable or p-dopable electron acceptors in photovoltaic cells. This disclosure concerns synthesizing the starting monomer compounds and polypyrazoles.

公开(公告)号：US11584826B2

公开(公告)日：2023-02-21

申请号：US17703729

申请日：2022-03-24

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Jawad Naciri ,  Banahalli R. Ratna

IPC分类号： C08G61/12 ,  C08G81/00 ,  H01B1/12

摘要： An interpenetrating network (IPN) polymer membrane material includes a soft polyurethane interspersed with a crosslinked conducting polymer. The material can be reversibly “switched” between its oxidized and reduced states by the application of a small voltage, ˜1 to 4 volts, thus modulating its diffusivity.