公开(公告)号：US20210388162A1

公开(公告)日：2021-12-16

申请号：US17347050

申请日：2021-06-14

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Jeffrey R. Deschamps ,  Jeffrey C. DePriest ,  Ian D. Giles

IPC分类号： C08G69/12

摘要： A new, thermally stable conducting material, poly(3-amino-1H-pyrazole-4-carboxylate), can be used in a variety of applications such as thermoelectrics, electron acceptors in light-harvesting (photovoltaic) materials, and thermally stable conducting energetic materials. Related compounds include poly 3-amino-5-chloro-1H-pyrazole-4-carboxylate, poly 3-amino-5-bromo-1H-pyrazole-4-carboxylate, poly 3-amino-5-fluoro-1H-pyrazole-4-carboxylate, poly 3-amino-5-iodo-1H-pyrazole-4-carboxylate, poly 3, 5-diamino-1H-pyrazole-4-carboxylate, poly 3-amino-5-NHR1-1H-pyrazole-4-carboxylate, poly 3-amino-5-NR2-1H-pyrazole-4-carboxylate, or poly 3-amino-5-hydroxy-1H-pyrazole-4-carboxylate.

公开(公告)号：US11028053B2

公开(公告)日：2021-06-08

申请号：US16295720

申请日：2019-03-07

申请人： The Government of the United States of America, as represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jawad Naciri ,  Jeffrey C. DePriest

IPC分类号： C07D231/38

摘要： An electrically conducting organic oligomer made from the steps of preparing an acidic aqueous solution with a monomer; preparing the acidic aqueous solution by mixing a solution of about 1.6 wt % HCl in DI water with a monomer; forming about a 0.3 M solution preparing a second aqueous solution with a sodium persulfate oxidant; mixing the acidic aqueous solution with the second aqueous solution; and allowing a reaction to proceed at about 40° C.

公开(公告)号：US20190202792A1

公开(公告)日：2019-07-04

申请号：US16295720

申请日：2019-03-07

申请人： The Government of the United States of America, as Represented by the Secretary of the Navy

发明人： Brett D. Martin ,  Scott A. Trammell ,  Jeffrey R. Deschamps ,  Jawad Naciri ,  Jeffrey C. DePriest

IPC分类号： C07D231/38

CPC分类号： C07D231/38

摘要： An electrically conducting organic oligomer made from the steps of preparing an acidic aqueous solution with a monomer; preparing the acidic aqueous solution by mixing a solution of about 1.6 wt % HCl in DI water with a monomer; forming about a 0.3 M solution preparing a second aqueous solution with a sodium persulfate oxidant; mixing the acidic aqueous solution with the second aqueous solution; and allowing a reaction to proceed at about 40° C.