公开(公告)号：US20120232292A1

公开(公告)日：2012-09-13

申请号：US13415412

申请日：2012-03-08

申请人： Thomas SCHAUB ,  Boris BUSCHHAUS ,  Marion Kristina BRINKS ,  Mathias SCHELWIES ,  Rocco PACIELLO ,  Johann-Peter MELDER ,  Martin MERGER

发明人： Thomas SCHAUB ,  Boris BUSCHHAUS ,  Marion Kristina BRINKS ,  Mathias SCHELWIES ,  Rocco PACIELLO ,  Johann-Peter MELDER ,  Martin MERGER

IPC分类号： C07D307/52 ,  C07C209/16

CPC分类号： C07C209/16 ,  C07C213/02 ,  C07D207/04 ,  C07D207/20 ,  C07D295/023 ,  C07D307/52 ,  C07C211/07 ,  C07C211/09 ,  C07C215/08 ,  C07C217/08

摘要： Process for the preparation of primary amines which have at least one functional group of the formula (—CH2—NH2) by alcohol amination of starting materials which have at least one functional group of the formula (—CH2—OH), with ammonia, with the elimination of water, where the alcohol amination is carried out under homogeneous catalysis in the presence of at least one complex catalyst which comprises at least one element selected from groups 8 and 9 of the Periodic Table of the Elements, and also at least one phosphorus donor ligand of the general formula (I).

摘要翻译： 具有至少一个式（-CH 2 -NH 2）官能团的伯胺的方法，其通过具有至少一个式（-CH 2 -OH）官能团的起始原料与氨进行醇胺化反应，与 消除水，其中在均相催化下，在至少一种包含至少一种选自元素周期表第8和9族的元素的复合催化剂的存在下进行醇胺化，以及至少一种磷 通式（I）的供体配体。