公开(公告)号：US08981140B1

公开(公告)日：2015-03-17

申请号：US13210915

申请日：2011-08-16

申请人： Timothy Haddad ,  Joseph Mabry ,  Gregory Yandek ,  Vandana Vij

发明人： Timothy Haddad ,  Joseph Mabry ,  Gregory Yandek ,  Vandana Vij

IPC分类号： C07F7/00

CPC分类号： C08G73/1082 ,  C07F7/00 ,  C07F7/0838 ,  C07F7/087 ,  C07F7/0874 ,  C07F7/21 ,  C08G59/1477 ,  C08G69/48 ,  C08G71/02 ,  C08G73/06 ,  C08G77/04 ,  C08G77/045 ,  C08G77/26 ,  C08G77/388

摘要： Novel POSS mono- and dianiline compounds, their synthesis procedures, and applications in host materials for the purposes of property enhancement are described. This class of POSS compounds features completely aromatic peripheries and partial amine functionality for facile and controlled reactive incorporation into a variety of polymers, and further utility may be derived from reactions of the available amine groups with anhydrides such as phenylethynyl phthalic anhydride (PEPA) to form reactive imide-type oligomers for incorporation into high performance thermosetting polymers. Modification of polymer hosts with the subject nanoparticles can result in a variety of property improvements including mechanical, thermal, tribological, electrical, as well as improved moisture resistance.

摘要翻译： 描述了新型POSS单 - 和二苯胺化合物，它们的合成方法以及用于物质增强目的在主体材料中的应用。 这类POSS化合物具有完全芳香族周边和部分胺官能团，用于容易控制反应性掺入各种聚合物中，并且还可以得到可用的胺基与酸酐如苯乙炔基邻苯二甲酸酐（PEPA）的反应形成 用于掺入高性能热固性聚合物的反应性酰亚胺型低聚物。 具有目标纳米颗粒的聚合物主体的改性可导致各种性能改进，包括机械，热，摩擦学，电学以及改善的耐湿性。