公开(公告)号：US20080226912A1

公开(公告)日：2008-09-18

申请号：US11955547

申请日：2007-12-13

申请人： Tyson Dean NORLIN ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Tyson Dean NORLIN ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/00 ,  B32B17/10 ,  C03C25/34

CPC分类号： C09D175/08 ,  C03C25/1065 ,  C03C25/326 ,  C08G18/672 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964 ,  C08G18/48

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The present invention provides a radiation curable Primary Coating composition comprising: an oligomer; first diluent monomer; a second diluent monomer; a third diluent monomer; a first light stabilizer; a first photoinitiator; a second photoinitiator; an antioxidant; a second light stabilizer; and an adhesion promoter; wherein said oligomer is the reaction product of hydroxyl-containing acrylate; an isocyanate; a polyether polyol; a polymerization inhibitor; a catalyst; and a diluent; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein said catalyst is selected from the group consisting of copper naphthenate; cobalt naphthenate; zinc naphthenate; triethylamine; triethylenediamine; 2-methyltriethyleneamine; dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to, 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl) phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan □ Tg of from about −25° C. to about −55° C.; and a modulus of from about 0.85 MPa to about 1.10 MPa.

摘要翻译： 用作光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 本发明提供了一种可辐射固化的初级涂料组合物，其包含：低聚物; 第一稀释剂单体; 第二稀释剂单体; 第三稀释剂单体; 第一光稳定剂; 第一种光引发剂; 第二光引发剂; 抗氧化剂 第二种光稳定剂; 和粘合促进剂; 其中所述低聚物是含羟基的丙烯酸酯的反应产物; 异氰酸酯; 聚醚多元醇; 阻聚剂; 催化剂 和稀释剂; 其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述催化剂选自环烷酸铜; 环烷酸钴; 环烷酸锌; 三乙胺 三亚乙基二胺 2-甲基三亚乙基胺; 二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述可辐射固化的初级涂层组合物的固化膜具有约-25℃至约-55℃的峰值tanδTg。 和约0.85MPa至约1.10MPa的模量。