公开(公告)号：US20080241535A1

公开(公告)日：2008-10-02

申请号：US11955838

申请日：2007-12-13

申请人： Wendell Wayne CATTRON ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne CATTRON ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

摘要： The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

摘要翻译： 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US20080226912A1

公开(公告)日：2008-09-18

申请号：US11955547

申请日：2007-12-13

申请人： Tyson Dean NORLIN ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Tyson Dean NORLIN ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/00 ,  B32B17/10 ,  C03C25/34

CPC分类号： C09D175/08 ,  C03C25/1065 ,  C03C25/326 ,  C08G18/672 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964 ,  C08G18/48

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The present invention provides a radiation curable Primary Coating composition comprising: an oligomer; first diluent monomer; a second diluent monomer; a third diluent monomer; a first light stabilizer; a first photoinitiator; a second photoinitiator; an antioxidant; a second light stabilizer; and an adhesion promoter; wherein said oligomer is the reaction product of hydroxyl-containing acrylate; an isocyanate; a polyether polyol; a polymerization inhibitor; a catalyst; and a diluent; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein said catalyst is selected from the group consisting of copper naphthenate; cobalt naphthenate; zinc naphthenate; triethylamine; triethylenediamine; 2-methyltriethyleneamine; dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to, 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl) phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan □ Tg of from about −25° C. to about −55° C.; and a modulus of from about 0.85 MPa to about 1.10 MPa.

摘要翻译： 用作光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 本发明提供了一种可辐射固化的初级涂料组合物，其包含：低聚物; 第一稀释剂单体; 第二稀释剂单体; 第三稀释剂单体; 第一光稳定剂; 第一种光引发剂; 第二光引发剂; 抗氧化剂 第二种光稳定剂; 和粘合促进剂; 其中所述低聚物是含羟基的丙烯酸酯的反应产物; 异氰酸酯; 聚醚多元醇; 阻聚剂; 催化剂 和稀释剂; 其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述催化剂选自环烷酸铜; 环烷酸钴; 环烷酸锌; 三乙胺 三亚乙基二胺 2-甲基三亚乙基胺; 二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述可辐射固化的初级涂层组合物的固化膜具有约-25℃至约-55℃的峰值tanδTg。 和约0.85MPa至约1.10MPa的模量。

公开(公告)号：US5334456A

公开(公告)日：1994-08-02

申请号：US888919

申请日：1992-05-26

申请人： Gerry K. Noren ,  John J. Krajewski ,  Sami A. Shama ,  John M. Zimmerman ,  Danny C. Thompson ,  John T. Vandeberg

发明人： Gerry K. Noren ,  John J. Krajewski ,  Sami A. Shama ,  John M. Zimmerman ,  Danny C. Thompson ,  John T. Vandeberg

IPC分类号： C08F2/50 ,  C08F265/04 ,  C08F299/04 ,  C08L67/06 ,  C09D167/06 ,  C09D167/07 ,  C14C11/00 ,  D21H19/16 ,  D21H19/48 ,  G03F7/027 ,  G03F7/029 ,  B32B27/06 ,  B32B27/36 ,  C08F16/32

CPC分类号： C08F265/04 ,  C08F299/0485 ,  C08L67/06 ,  C09D167/06 ,  C09D167/07 ,  C14C11/003 ,  D21H19/16 ,  D21H19/48 ,  G03F7/027 ,  G03F7/029 ,  Y10T428/3162 ,  Y10T428/31681 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/31794 ,  Y10T428/31826

摘要： A free-radical radiation curable composition comprising:a) at least one compound containing from one to about six vinyl ether groups; andb) at least one compound containing a saturated backbone and at least one maleate or fumarate end group per molecule,wherein the ratio of vinyl ether groups to maleate or fumarate groups in the composition is in the range of about 5:1 to about 1:5.

摘要翻译： 一种自由基可辐射固化组合物，其包含：a）至少一种含有1至约6个乙烯基醚基团的化合物; 和b）每分子含有饱和骨架和至少一种马来酸盐或富马酸酯端基的至少一种化合物，其中组合物中乙烯基醚基团与马来酸盐或富马酸盐基团的比例在约5:1至约1的范围内 ：5。

公开(公告)号：US5219896A

公开(公告)日：1993-06-15

申请号：US859344

申请日：1992-03-27

申请人： Clive J. Coady ,  Erwin S. Poklacki ,  John M. Zimmerman ,  Timothy E. Bishop ,  John L. Derer

发明人： Clive J. Coady ,  Erwin S. Poklacki ,  John M. Zimmerman ,  Timothy E. Bishop ,  John L. Derer

IPC分类号： C03C25/10 ,  C08F8/30 ,  C08F299/06 ,  C08G18/81

CPC分类号： C08F8/30 ,  C03C25/106 ,  C03C25/1065 ,  C08F299/065 ,  C08G18/8175 ,  Y10S525/92

摘要： Photocurable liquid coating compositions adapted to provide primary coatings for optical glass fibers are disclosed. These compositions comprise polycarbonate-based acrylate-terminated polyurethane, an acrylate of an unsubstituted or C.sub.1 -C.sub.10 alkyl substituted phenol that is alkoxylated with a C.sub.2 -C.sub.4 alkylene oxide and at least one alkylacrylate having a T.sub.g below about -45.degree. C. Films produced from these ultraviolet light curable compositions are flexible and possess good water resistance and good wet adhesion.

摘要翻译： 公开了适用于提供光学玻璃纤维初级涂层的光固化液体涂料组合物。 这些组合物包含基于聚碳酸酯的丙烯酸酯封端的聚氨酯，未被取代的C 1 -C 10烷基取代的苯酚的丙烯酸酯，其用C 2 -C 4烯化氧烷氧基化，和至少一种Tg至低于-45℃的丙烯酸烷基酯。 这些紫外光固化性组合物是柔性的，具有良好的耐水性和良好的湿粘合性。

公开(公告)号：US4690501A

公开(公告)日：1987-09-01

申请号：US752582

申请日：1985-07-08

申请人： John M. Zimmerman ,  Gerry K. Noren ,  Timothy E. Bishop

发明人： John M. Zimmerman ,  Gerry K. Noren ,  Timothy E. Bishop

IPC分类号： C03C25/24 ,  C03C25/10 ,  C08F2/48 ,  C08F2/50 ,  C08F20/00 ,  C08F20/42 ,  C08F290/00 ,  C08F299/06 ,  C08G18/10 ,  C08G18/50 ,  C08G18/67 ,  C08G18/81 ,  C09D5/00 ,  C09D175/14 ,  G02B6/44 ,  C08F26/02 ,  C08F126/02 ,  G02B6/22

CPC分类号： C08G18/8175 ,  C03C25/106 ,  C03C25/1065 ,  C08F299/065 ,  C08G18/10 ,  C08G18/5024 ,  C08G18/672 ,  Y10T428/2938

摘要： Ultraviolet curing oligomers and liquid coating compositions based thereon are disclosed which cure with ultraviolet light in the presence of a photoinitiator. The coating compositions can provide either a single coating for optical glass fiber which resists microbending difficulties down to around -40.degree. C., or a topcoat for overcoating softer buffer coatings which resist microbending down to around -60.degree. C. The coating compositions consist essentially of the linear polyacrylate-terminated polyurethane polyurea oligomer in admixture with an ultraviolet curable liquid acrylate or polyacrylate to provide the liquidity needed for application and to adjust the hardness or softness of the cured coating for the selected single coat or topcoat utility. The oligomer contains a linear polyurethane core terminated by urea formation with a polyhydroxy-functional amine containing a single isocyanate-reactive amino hydrogen atom. The plurality of hydroxy-terminated branches provided by the amine are capped with an acrylate-functional compound, and the several acrylate-functional branches increase the toughness and the cure speed.

摘要翻译： 公开了基于其的紫外线固化低聚物和液体涂料组合物，其在光引发剂存在下用紫外光固化。 涂料组合物可以提供单一的光学玻璃纤维涂层，其抗微弯曲难度低至约-40℃;或用于外涂柔软的缓冲涂层的顶涂层，其抗微弯曲至约-60℃。涂层组合物基本上 的线性聚丙烯酸酯封端的聚氨酯聚脲低聚物与紫外线可固化液体丙烯酸酯或聚丙烯酸酯混合以提供所需的流动性，并调节所选择的单一涂层或面漆实用程序的固化涂层的硬度或柔软度。 低聚物含有由含有单个异氰酸酯反应性氨基氢原子的多羟基官能胺形成脲形成的线性聚氨酯芯。 由胺提供的多个羟基封端的分支用丙烯酸酯官能化合物封端，并且几个丙烯酸酯官能的分支增加韧性和固化速度。

公开(公告)号：US08426021B2

公开(公告)日：2013-04-23

申请号：US13233670

申请日：2011-09-15

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B9/00 ,  D02G3/00 ,  C08F283/10 ,  C08F20/22

CPC分类号： G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

摘要： The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

摘要翻译： 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US08426020B2

公开(公告)日：2013-04-23

申请号：US11955541

申请日：2007-12-13

申请人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： C08F2/50 ,  B05D5/06 ,  D02G3/00 ,  G02B6/00

CPC分类号： G02B1/14 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B1/10 ,  G02B6/02395 ,  Y10T428/24942 ,  Y10T428/2933 ,  Y10T428/2942 ,  Y10T428/2947 ,  C08G18/48

摘要： The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%;B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; andC) a Tube Tg, of from about −25° C. to about −55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

摘要翻译： 本发明提供涂覆有超涂层的光纤，其中超涂层包括至少两层，其中第一层是与光纤的外表面接触的主涂层，第二层是接触的第二涂层 其中主要涂层的外表面，其中光纤上的固化的一次涂层在初始固化后和在85℃和85％相对湿度下老化一个月后具有以下性质：A）约84％的％RAU， 至约99％; B）约0.15MPa至约0.60MPa的原位模量; 和C）管Tg，约-25℃至约-55℃; 其中光纤上的固化的二次涂层在初始固化之后和在85℃和85％相对湿度下老化一个月后具有以下性能：A）约80％至约98％的％RAU; B）原位模量在约0.60GPa和约1.90GPa之间; 和C）管Tg，为约50℃至约80℃

公开(公告)号：US20100274276A1

公开(公告)日：2010-10-28

申请号：US12427910

申请日：2009-04-22

申请人： Ricky Chow ,  John Schreiner ,  William K. Durfee ,  John M. Zimmerman

发明人： Ricky Chow ,  John Schreiner ,  William K. Durfee ,  John M. Zimmerman

IPC分类号： A61F2/01

CPC分类号： A61F2/91 ,  A61B8/0841 ,  A61F2/915 ,  A61F2/95 ,  A61F2002/823 ,  A61F2002/91575 ,  A61F2002/9665 ,  A61F2230/0054 ,  A61F2250/0098

摘要： An occlusion system, method, and apparatus which treats an aneurysm in a primary vessel such as an intracranial vessel. Aneurysm types treatable by means of this invention include bulge (sometimes referred to as a true aneurysm), dissecting aneurysms in which the layers of vessel wall are partially delaminated, and what are referred to a “false” aneurysm defined by a relatively small opening in the parent vessel wall fluridically coupled to a bulb-shaped sac, also defined by the vessel wall. The system includes an occlusion device configured for deployment in the parent vessel that restricts fluid flow to the aneurysm. A patch on the device covers the neck of the aneurysm. The system includes a marker in a defined relationship with the patch, which allows for axial and rotational positioning of the device.

摘要翻译： 用于治疗诸如颅内血管的主血管中的动脉瘤的闭塞系统，方法和装置。 通过本发明可治疗的动脉瘤类型包括隆起（有时称为真正的动脉瘤），其中血管壁层被部分分层的解剖动脉瘤，以及由相对小的开口限定的“假”动脉瘤 母体血管壁与血管壁也限定了一个球形囊。 该系统包括被配置用于部署在母体血管中的阻塞装置，其限制流体流向动脉瘤。 设备上的补丁覆盖了动脉瘤的颈部。 该系统包括与贴片具有限定关系的标记，其允许装置的轴向和旋转定位。

公开(公告)号：US20080226914A1

公开(公告)日：2008-09-18

申请号：US11955614

申请日：2007-12-13

申请人： Tyson Dean Norlin ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Tyson Dean Norlin ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： G02B6/036 ,  C03B37/01262 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964 ,  C08G18/48

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes for coating optical fibers. The radiation curable Primary Coating composition of the instant claimed invention includes an oligomer, a diluent monomer; a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/μmol; and wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan delta Tg of from about −25° C. to about −45° C. and a modulus of from about 0.50 MPa to about 1.2 MPa.

摘要翻译： 用作光纤的主要涂层的可辐射固化涂层，涂覆有所述涂层的光纤和用于涂覆光纤的工艺。 本发明的可辐射固化的初级涂料组合物包括低聚物，稀释剂单体; 光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物：丙烯酸羟乙酯; 芳香族异氰酸酯; 脂族异氰酸酯; 多元醇 催化剂 和抑制剂，其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mumol; 并且其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于：1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述可辐射固化的初级涂料组合物的固化膜的峰值tanδTg为约-25℃至约-45℃，模量为约0.50MPa至约1.2MPa。

公开(公告)号：US20080226913A1

公开(公告)日：2008-09-18

申请号：US11955604

申请日：2007-12-13

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： C03C25/1065 ,  C08G18/6674 ,  C08G18/672 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964

摘要： A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: α) an Omega Oligomer; and β) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of α1) a hydroxyl-containing (meth)acrylate; α2) an isocyanate; α3) a polyether polyol; and α4) tripropylene glycol; in the presence of α5) a polymerization inhibitor; and α6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein said Upsilon Oligomer is an epoxy diacrylate.

摘要翻译： 描述和要求保护的用于光纤的新的可辐射固化的二次涂层，其中所述组合物包含与第一稀释剂单体混合的第二涂料低聚物混合物; 第二稀释剂单体; 任选地，第三稀释剂单体; 抗氧化剂 第一种光引发剂; 第二光引发剂; 和任选的滑爽添加剂或滑爽添加剂的混合物; 其中所述第二涂料低聚物共混物包含：α）ω-低聚物; 和β）Upsilon低聚物; 其中所述欧米加低聚物通过α1）含羟基的（甲基）丙烯酸酯的反应合成; α2）异氰酸酯; α3）聚醚多元醇; 和α4）三丙二醇; 在α5的存在下）聚合抑制剂; 和α6）催化剂; 产生欧米茄低聚物; 其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于：1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述Upsilon低聚物是环氧二丙烯酸酯。