公开(公告)号：US10646855B2

公开(公告)日：2020-05-12

申请号：US16177833

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US20190126256A1

公开(公告)日：2019-05-02

申请号：US16177840

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/96 ,  B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  B01J38/02 ,  C07C5/333

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US20190126249A1

公开(公告)日：2019-05-02

申请号：US16177833

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US10737244B2

公开(公告)日：2020-08-11

申请号：US16177848

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US20190126251A1

公开(公告)日：2019-05-02

申请号：US16177849

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J23/96 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  B01J38/02 ,  C07C5/333

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US10682629B2

公开(公告)日：2020-06-16

申请号：US16177849

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J21/04 ,  B01J23/62 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US10682628B2

公开(公告)日：2020-06-16

申请号：US16177840

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333 ,  B01J23/96 ,  B01J38/02

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.

公开(公告)号：US20190126250A1

公开(公告)日：2019-05-02

申请号：US16177848

申请日：2018-11-01

申请人： UOP LLC

发明人： Manuela Serban ,  Matthew C. Cole ,  Ellen Arnold ,  Guanghui Zhu

IPC分类号： B01J23/62 ,  B01J21/04 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  C07C5/333

摘要： A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.