公开(公告)号：US4769449A

公开(公告)日：1988-09-06

申请号：US11103

申请日：1987-02-05

申请人： Ulrich Buhler ,  Manfred Hahnke ,  Michael Kunze ,  Albert Bode

发明人： Ulrich Buhler ,  Manfred Hahnke ,  Michael Kunze ,  Albert Bode

IPC分类号： C09B29/085 ,  C09B29/01 ,  C09B29/08 ,  C09B67/22 ,  D06P1/18

CPC分类号： C09B67/0051 ,  C09B29/0003 ,  C09B29/0813 ,  D06P1/18 ,  Y10S534/01

摘要： Azo dyes of the formula ##STR1## wherein R.sup.1 is alkyl having 1 to 4 carbon atoms; R.sup.2 is alkyl having 1 to 3 carbon atoms; R.sup.3 is alkylcarbonyloxyethyl having 1 to 3 carbon atoms in the alkyl moiety, alkoxycarbonyloxyethyl having 1 to 4 carbon atoms in the alkoxy moiety, methoxyethoxycarbonyloxyethyl or ethoxyethoxycarbonyloxyethyl; and R.sup.4 is one of the definitions of R.sup.3 or cyanoethyl; or mixtures of at least two species of said formula are used for dyeing and printing hydrophobic fiber materials.

摘要翻译： 其中R 1是具有1至4个碳原子的烷基的式“IMAGE”的偶氮染料; R2是具有1至3个碳原子的烷基; R3是在烷基部分具有1至3个碳原子的烷基羰氧基乙基，在烷氧基部分具有1至4个碳原子的烷氧基羰氧基乙基，甲氧基乙氧基羰基氧基乙基或乙氧基乙氧基羰基氧基乙基; R4是R3或氰乙基的定义之一; 或至少两种所述配方的混合物用于染色和印刷疏水纤维材料。

公开(公告)号：US4908042A

公开(公告)日：1990-03-13

申请号：US177419

申请日：1988-04-04

申请人： Ulrich Buhler ,  Manfred Hahnke ,  Michael Kunze ,  Albert Bode

发明人： Ulrich Buhler ,  Manfred Hahnke ,  Michael Kunze ,  Albert Bode

IPC分类号： C09B29/085 ,  C09B29/01 ,  C09B29/08 ,  C09B67/22 ,  D06P1/18

CPC分类号： C09B67/0051 ,  C09B29/0003 ,  C09B29/0813 ,  D06P1/18 ,  Y10S534/01

摘要： Azo dyes of the formula ##STR1## wherein R.sup.1 is alkyl having 1 to 4 carbon atoms; R.sup.2 is alkyl having 1 to 3 carbon atoms; R.sup.3 is alkylcarbonyloxyethyl having 1 to 3 carbon atoms in the alkyl moiety, alkoxycarbonyloxyethyl having 1 to 4 carbon atoms in the alkoxy moiety, methoxyethoxycarbonyloxyethyl or ethoxyethoxycarbonyloxyethyl; and R.sup.4 is one of the definitions of R.sup.3 or cyanoethyl; or mixtures of at least two species of said formula are used for dyeing and printing hydrophobic fiber materials.

公开(公告)号：US4902786A

公开(公告)日：1990-02-20

申请号：US196323

申请日：1988-05-20

申请人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal

发明人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal

IPC分类号： C09B62/51 ,  G01R31/36 ,  C09B62/085 ,  C09B62/45 ,  D06P1/384

CPC分类号： G01R19/16542 ,  C09B62/51

摘要： Water-soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl;the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.

摘要翻译： 具有符合式（1）＆lt; IMAGE＆gt;的式（1）的具有纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。 新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

公开(公告)号：US4740592A

公开(公告)日：1988-04-26

申请号：US913485

申请日：1986-09-30

申请人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

发明人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

IPC分类号： C07D251/52 ,  C07D251/70 ,  C09B62/51 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66 ,  C09B62/507

CPC分类号： C09B62/51

摘要： Water soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;Y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl; the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.

摘要翻译： 具有符合式（1）＆lt; IMAGE＆gt;的式（1）的具有纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; Y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。 新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

公开(公告)号：US4731441A

公开(公告)日：1988-03-15

申请号：US841542

申请日：1986-03-19

申请人： Marcos Segal ,  Michael Kunze

发明人： Marcos Segal ,  Michael Kunze

IPC分类号： C09B62/08 ,  C09B62/44 ,  C09B62/507 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66 ,  C09B62/026

CPC分类号： C09B62/4411 ,  D06P1/38

摘要： Water-soluble monoazo and disazo compounds having fiber-reactive dye properties which are suitable for dyeing carbamoyl- and hydroxyl-containing materials, in particular cellulose fiber materials, and containing as diazo components an optionally substituted phenyl radical or naphthyl radical or a phenylazophenyl, phenylazonaphthyl, naphthylazophenyl or naphthylazonaphthyl radical, one of these radicals containing bonded in the diazo component a vinylsulfonyl, .beta.-thiosulfatoethylsulfonyl, .beta.-phosphatoethylsulfonyl, .beta.-chloroethylsulfonyl or .beta.-sulfatoethylsulfonyl group, and as coupling component that of a naphthol, aminonaphthaline or aminobenzene having a fiber-reactive grouping of the general formula ##STR1## in which the two R.sup.1 s, identical to or different from each other, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents the vinyl group, a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl or .beta.-sulfatoethyl group.

摘要翻译： 具有纤维反应性染料性质的水溶性单偶氮和双偶氮化合物，其适用于染色含氨基甲酰基和羟基的材料，特别是纤维素纤维材料，并且作为重氮组分含有任选取代的苯基或萘基或苯基偶氮苯基，苯基氮杂萘基 ，萘基氮苯基或萘基萘基，其中一个基团包含键合在重氮组分中的乙烯基磺酰基，β-硫代亚磺酰基乙基磺酰基，β-磷酰基乙基磺酰基，β-氯乙基磺酰基或β-磺基乙基磺酰基，以及作为萘酚，氨基萘或氨基苯的偶联组分， 两个R1相同或不同的通式为“IMAGE”的纤维反应性分子表示氢原子或任意取代的1-4个碳原子的烷基，R是氢原子或磺基 基团，Y代表乙烯基，β-硫代硫代乙基，β-磷酸酯 庚基，β-氯乙基或β-磺基乙基。

公开(公告)号：US4757136A

公开(公告)日：1988-07-12

申请号：US913534

申请日：1986-09-30

申请人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

发明人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

IPC分类号： C07D251/52 ,  C07D251/70 ,  C09B62/51 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66

CPC分类号： C09B62/51

摘要： Water-soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl;the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.

摘要翻译： 具有符合式（1）＆lt; IMAGE＆gt;的式（1）的具有纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。 新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

公开(公告)号：US4703111A

公开(公告)日：1987-10-27

申请号：US849066

申请日：1986-04-07

申请人： Marcos Segal ,  Michael Kunze

发明人： Marcos Segal ,  Michael Kunze

IPC分类号： C09B62/513 ,  C09B62/08 ,  C09B62/44 ,  C09B62/507 ,  D06P1/38 ,  D06P3/66 ,  C09B62/085 ,  C09B62/09 ,  C09B62/51

CPC分类号： C09B62/4411

摘要： Water-soluble monoazo and disazo compounds having fiber-reactive dye properties which are suitable for dyeing carboxamido and/or hydroxy-containing materials, in particular cellulose fiber materials, and contain as coupling component that of a naphthol, aminonaphthalene or aminobenzene and as diazo component an optionally chlorine-, alkyl-, alkoxy- and/or sulfo-substituted phenyl radical or an optionally substituted phenylazophenyl or phenylazonaphthyl radical having the fiber-reactive group of the general formula ##STR1## in which the two R.sup.1, identical to or different from each other, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents the vinyl group or a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl or .beta.-sulfatoethyl group, as substituent, and a further such fiber-reactive grouping can be bonded to the radical of the coupling component.

摘要翻译： 具有纤维反应性染料性质的水溶性单偶氮和双偶氮化合物，其适用于染色甲酰氨基和/或含羟基材料，特别是纤维素纤维材料，并且含有作为萘酚，氨基萘或氨基苯的偶联组分和作为重氮组分 任选的氯，烷基，烷氧基和/或磺基取代的苯基或任选取代的具有通式“IMAGE”的纤维反应性基团的苯基偶氮苯基或苯基二萘基，其中两个R 1，相同或不同 彼此表示氢原子或任选取代的1至4个碳原子的烷基，R是氢原子或磺基，Y代表乙烯基或β-硫代硫代乙基，β-磷酰乙基，β-氯乙基或β - 磺基乙基作为取代基，并且另外的这种纤维反应性基团可以结合到偶联组分的基团上。

公开(公告)号：US4775746A

公开(公告)日：1988-10-04

申请号：US913693

申请日：1986-09-30

申请人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

发明人： Hartmut Springer ,  Michael Kunze ,  Marcos Segal ,  Werner H. Russ

IPC分类号： C07D251/52 ,  C07D251/70 ,  C09B62/51 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66 ,  C09B62/507

CPC分类号： C09B62/51

摘要： Water-soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally mononsubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;Y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl;the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.

摘要翻译： 具有符合式（1）的纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; Y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。 新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

公开(公告)号：US4725674A

公开(公告)日：1988-02-16

申请号：US841290

申请日：1986-03-19

申请人： Marcos Segal ,  Michael Kunze

发明人： Marcos Segal ,  Michael Kunze

IPC分类号： C09B62/08 ,  C09B62/44 ,  C09B62/507 ,  C09B62/51 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66 ,  C09B62/028 ,  C09B62/03 ,  C09B62/513

CPC分类号： C09B62/4411

摘要： Water-soluble monoazo and disazo compounds which have fiber-reactive dyestuff properties and containing as diazo component an optionally substituted phenyl radical or naphthyl radical or an optionally substituted phenylazophenyl, phenylazonaphthyl, naphthylazophenyl or naphthylazonaphthyl radical, and as coupling component that of a naphthol, aminonaphthaline or aminobenzene and as fiber-reactive group a group of the formula ##STR1## in which both R.sup.1 s, identical to or different from one another, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents a vinyl group or a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl or .beta.-sulfatoethyl group, this fiber-reactive grouping being bonded to the radical of the coupling component. These azo compounds have fibre-reactive dyestuff properties and are suitable for dyeing carboxamide and/or hydroxy-containing materials, such as wool and synthetic polyamide fibers, in particular cellulose fibres, in deep and fast shades, when applied according to the usual methods of application and fixation, suitable for fibre-reactive dyestuffs.

摘要翻译： 具有纤维反应性染料性质并且作为重氮组分含有任选取代的苯基或萘基或任选取代的苯基偶氮苯基，苯基偶氮萘基，萘基苯基或萘基萘基的水溶性单偶氮和双偶氮化合物，以及作为萘酚，氨基萘的偶联组分 或氨基苯，并且作为纤维反应性基团，其中两个R 1彼此相同或不同的式“IMAGE”的基团表示氢原子或任选取代的具有1至4个碳原子的烷基，R是氢 原子或磺基，Y表示乙烯基或β-硫代硫代乙基，β-磷酸乙基，β-氯乙基或β-磺基乙基，该纤维反应性基团键合到偶联组分的基团上。 这些偶氮化合物具有纤维反应性染料性质，并且适用于以深色和快速色调染色羧酰胺和/或含羟基材料，例如羊毛和合成聚酰胺纤维，特别是纤维素纤维，当根据常规方法 应用和固定，适用于纤维反应性染料。

公开(公告)号：US4808193A

公开(公告)日：1989-02-28

申请号：US198991

申请日：1988-05-26

申请人： Ludwig Schlafer ,  Hartmut Springer ,  Michael Kunze

发明人： Ludwig Schlafer ,  Hartmut Springer ,  Michael Kunze

IPC分类号： C09B62/44 ,  D06P1/384 ,  C09B35/02 ,  C09B43/40 ,  C09B62/01 ,  D06P1/38

CPC分类号： C09B62/4415 ,  D06P1/384 ,  Y10S8/918

摘要： Water-soluble compounds having fiber-reactive dye properties of the general formula ##STR1## in which A is an alkylene of 2 to 6 carbon atoms or a phenylene which can be substituted by 1 or 2 substituents, or is a radical of the formula ##STR2## in which W is a direct bond or a bridge member and the R' and R* each denote hydrogen, chlorine, methyl, methoxy, ethoxy, carboxy or sulfo;B is chlorine or fluorine;R is hydrogen, chlorine, an alkyl of 1 to 4 carbon atoms or an alkoxy of 1 to 4 carbon atoms;M is hydrogen or an alkali metal;n stands for the number zero, 1 or 2,K is a radical of the formula ##STR3## in which D is phenylene which can be substituted by chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, carboxy or sulfo, or is naphthalene with optionally 1 or 2 sulfo groups,R.sup.1 denotes hydrogen, chlorine, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms,R.sup.2 is hydrogen or alkyl of 1 to 4 carbon atoms,G is carboxy, methyl or carbalkoxy of 2 to 5 carbon atoms,Y denotes vinyl, .beta.-sulfatoethyl, .beta.-phosphatoethyl, .beta.-thiosulfatoethyl or .beta.-chloroethyl,Z is the .alpha.- or .beta.-bromoacryloyl or .beta.-chloropropionyl or a radical of the formula ##STR4## with B, D and Y of the abovementioned meanings. The novel dyes are suitable for dyeing hydroxyl- and/or carbamoyl-containing material; on hydroxyl-containing material, such as cellulose fibers, they become fixed not only in the alkaline but also in the weakly acid to neutral range, so that they can be used together with disperse dyes for dyeing blend material composed of cellulose and polyester fibers by the dyeing methods for disperse dyes.

摘要翻译： 具有通式的纤维反应性染料性质的水溶性化合物，其中A是2至6个碳原子的亚烷基或可被1或2个取代基取代的亚苯基，或者是式 IMAGE>其中W是直接键或桥连构件，R'和R *各自表示氢，氯，甲基，甲氧基，乙氧基，羧基或磺基; B是氯或氟; R是氢，氯，1至4个碳原子的烷基或1至4个碳原子的烷氧基; M是氢或碱金属; n表示数字零，1或2，K是式为其中D为可被氯，溴，烷基取代的亚苯基的式 + TR 的基团， 1-4个碳原子的烷氧基，1至4个碳原子的烷氧基，羧基或磺基，或具有任选1或2个磺基的萘，R 1表示氢，氯，1至4个碳原子的烷基或1至4个碳原子的烷氧基，R 2 是氢或1至4个碳原子的烷基，G是2至5个碳原子的羧基，甲基或烷氧基，Y表示乙烯基，β-磺基乙基，β-磷酰乙基，β-硫代硫代乙基或β-氯乙基，Z是α- 或β-溴丙烯酰或β-氯丙酰基或具有上述含义的B，D和Y的式（IMAGE）基团。 新型染料适用于染色羟基和/或氨基甲酰基的材料; 在含羟基的材料如纤维素纤维上，它们不仅在碱性中而且在弱酸至中性范围内变得固定，因此它们可以与分散染料一起用于染色由纤维素和聚酯纤维组成的共混材料 分散染料的染色方法。