Preparation of anilino azo carbazole dyestuffs prepared by diazotization
by nitrosylsulphuric acid in acetic acid
    1.
    发明授权
    Preparation of anilino azo carbazole dyestuffs prepared by diazotization by nitrosylsulphuric acid in acetic acid 失效
    通过硝酸基硫酸在乙酸中重氮化制备的苯胺基偶氮咔唑染料

    公开(公告)号:US4472307A

    公开(公告)日:1984-09-18

    申请号:US410138

    申请日:1982-08-20

    IPC分类号: C09B29/40 C09B41/00 C09B29/01

    CPC分类号: C09B29/3608 C09B41/002

    摘要: An improved process for the preparation of azo dyestuffs of the formula ##STR1## comprising diazotizing a 2-halo-4-nitroaniline at 10.degree. to 35.degree. C. in 70 to 100 percent by weight strength acetic acid by means of nitrosylsulphuric acid, adjusting the acetic acid content of the resulting diazo solution to 60 to 85% by the addition of water, and at a temperature from 15.degree. to 45.degree. C. adding an appropriate carbazole to the diazo solution as a solid or in the form of a suspension in 60 to 100 percent strength by weight acetic acid and coupling the carbazole to the diazotized amine to produce said azo dyestuff and isolating the dyestuff.

    摘要翻译: 一种改进的制备式“偶氮染料”的方法,其包括在10-35℃下在70-100重量份浓度的乙酸中通过亚硝酰基硫酸重氮化2-卤代-4-硝基苯胺,调节 所得重氮溶液的乙酸含量通过加入水至60至85%,并在15至45℃的温度下加入合适的咔唑作为固体或悬浮​​液形式的重氮溶液 在60至100重量%的乙酸中,将咔唑偶联到重氮化胺上以制备所述偶氮染料并分离染料。