公开(公告)号：US06933399B2

公开(公告)日：2005-08-23

申请号：US10429206

申请日：2003-05-02

Applicant: Ulrich T. Mueller-Westerhoff ,  Richard W. Sanders

Inventor： Ulrich T. Mueller-Westerhoff ,  Richard W. Sanders

IPC: C07C323/29 ,  C07F15/04 ,  C07F17/02 ,  C07F15/00 ,  C07F19/00

CPC classification number: C07C323/29 ,  C07F15/045 ,  C07F17/02

Abstract: Described herein are metal complexes having the formula wherein M is nickel, palladium, or platinum; Q1-Q4 are each independently sulfur, selenium, or tellurium; X1-X4 are each independently a divalent linking group having 1 to about 125 carbons; m1 to m4 are each independently 0 or 1; and W1-W4 are each independently hydrogen, carboxylic acid, carboxylic acid anhydride, carboxylic acid chloride, sulfonic acid, or sulfonyl chloride, with the proviso that W1-W4 are not all hydrogen. The complexes have strong absorptions in the near infrared.

Abstract translation: 本文描述的是具有下式的金属络合物：其中M是镍，钯或铂; Q 1至4 4各自独立地为硫，硒或碲; X 1〜X 4各自独立地为具有1〜约125个碳的二价连接基团; m1〜m4各自独立地为0或1; 和W 1 -W 4各自独立地为氢，羧酸，羧酸酐，羧酸酰氯，磺酸或磺酰氯，条件是W ^{1 -W 4不是全部是氢。 复合物在近红外线具有很强的吸收。}

公开(公告)号：US4379740A

公开(公告)日：1983-04-12

申请号：US390085

申请日：1982-06-21

Applicant: Adel I. Nazzal ,  Ulrich T. Mueller-Westerhoff

Inventor： Adel I. Nazzal ,  Ulrich T. Mueller-Westerhoff

IPC: C25B11/06 ,  C25B1/00 ,  C25B1/02 ,  C25B11/04

CPC classification number: C25B1/003 ,  Y02E60/368

Abstract: Hydrogen is generated from water containing acid by passing electric current through it, using as the cathode a semiconductor exposed to light and having a transition metal metallocenophane compound attached to the surface of the cathode by means of a polymer.

Abstract translation: 通过使电流通过电流从氢产生氢气，使用暴露于光的半导体并且具有通过聚合物附着到阴极表面的过渡金属茂金属化合物作为阴极。