公开(公告)号：US09844771B2

公开(公告)日：2017-12-19

申请号：US14775331

申请日：2014-03-10

申请人： UniZeo Co., Ltd. ,  THE UNIVERSITY OF TOKYO

发明人： Masaru Ogura ,  Keiji Itabashi ,  Tatsuya Okubo ,  Kiyofumi Monma ,  Palani Elangovan Shanmugam

IPC分类号： B01J29/76 ,  B01J35/00 ,  B01J35/10 ,  B01D53/94 ,  B01D53/86 ,  B01J20/18 ,  C01B39/46

CPC分类号： B01J29/7615 ,  B01D53/864 ,  B01D53/94 ,  B01D53/944 ,  B01D2253/1085 ,  B01D2255/2025 ,  B01D2255/20738 ,  B01D2255/502 ,  B01J20/186 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J2229/186 ,  B01J2229/37 ,  C01B39/46

摘要： To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO2/Al2O3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO2/Al2O3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.

公开(公告)号：US20160030933A1

公开(公告)日：2016-02-04

申请号：US14775331

申请日：2014-03-10

申请人： UNIZEO CO., LTD. ,  THE UNIVERSITY OF TOKYO

发明人： Masaru Ogura ,  Keiji Itabashi ,  Tatsuya Okubo ,  Kiyofumi Monma ,  Palani Elangovan Shanmugam

IPC分类号： B01J29/76 ,  B01D53/86 ,  B01J35/10 ,  B01D53/94 ,  C01B39/46 ,  B01J20/18

CPC分类号： B01J29/7615 ,  B01D53/864 ,  B01D53/94 ,  B01D53/944 ,  B01D2253/1085 ,  B01D2255/2025 ,  B01D2255/20738 ,  B01D2255/502 ,  B01J20/186 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J2229/186 ,  B01J2229/37 ,  C01B39/46

摘要： To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO2/Al2O3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO2/Al2O3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.

摘要翻译： 提供能够吸附和重整烃的烃重整/捕获材料。 本发明的烃重整/捕集材料的SiO 2 / Al 2 O 3比例为7-12，并含有Fe（II） - 取代的β沸石，其被Fe（II）离子离子交换。 相对于Fe（II）取代的β沸石，负载的Fe（II）的量优选为0.001-0.5mmol / g。 这种Fe（II）取代的β沸石通过在二价铁的水溶性化合物的水溶液中分散并混合SiO 2 / Al 2 O 3比率为7至12的β沸石，并且将该溶液 ，使得Fe（II）离子负载在β沸石上。