ZIEGLER-NATTA CATALYST COMPOSITIONS FOR PRODUCING POLYETHYLENES WITH A HIGH MOLECULAR WEIGHT TAIL AND METHODS OF MAKING THE SAME
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    发明申请
    ZIEGLER-NATTA CATALYST COMPOSITIONS FOR PRODUCING POLYETHYLENES WITH A HIGH MOLECULAR WEIGHT TAIL AND METHODS OF MAKING THE SAME 审中-公开
    用于生产具有高分子量尾的聚乙烯的ZIEGLER-NATTA催化剂组合物及其制备方法

    公开(公告)号:US20150183906A1

    公开(公告)日:2015-07-02

    申请号:US14657841

    申请日:2015-03-13

    IPC分类号: C08F210/16

    摘要: Methods of preparing a polymerization catalyst component is provided, in which a magnesium component, a Lewis acid solubilizing component, a titanium compound, optionally a transition metal compound different than the titanium compound, and typically an inert filler are combined in a slurrying agent and spray-dried to produce a catalyst precursor in the form of a substantially spherical and porous solid particle. The methods and catalysts of this disclosure can provide ethylene homopolymer and copolymer resins having a high molecular weight tail and a broadened molecular weight distribution as compared to more traditional Ziegler-Natta catalysts.

    摘要翻译: 提供制备聚合催化剂组分的方法,其中将镁组分,路易斯酸增溶组分,钛化合物,任选的不同于钛化合物的过渡金属化合物,通常为惰性填料组合在制浆剂和喷雾中 干燥以产生呈基本球形和多孔固体颗粒形式的催化剂前体。 与更传统的齐格勒 - 纳塔催化剂相比,本公开的方法和催化剂可以提供具有高分子量尾部和扩展的分子量分布的乙烯均聚物和共聚物树脂。