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公开(公告)号:US20230264970A1
公开(公告)日:2023-08-24
申请号:US18003776
申请日:2021-07-02
发明人: Masaru KUNO , Michael BRENNAN , Anthony RUTH , Ilia PAVLOVETC , Jeffrey A. CHRISTIANS , Taylor Hennessey MOOT , Joseph Matthew LUTHER
CPC分类号: C01G21/16 , B05D1/005 , B05D3/007 , H10K30/10 , H10K30/50 , C01P2002/34 , B05D2601/28
摘要: Compositions comprise a perovskite and a non-perovskite. Perovskites comprise AxA′yA″(1−x−y)BX3, and non-perovskites may comprise A″, B and X, where A is a first cation, A′ is a second cation, A″ is a third cation, B is a fourth cation, X is an anion. In some instances, A, A′, and A″ are each independently (NH2)2CH+, CH3NH3+, Cs+, Rb+, or (NH2)2(C═NH2)+, with the proviso that A, A′, and A″ are each different. The perovskite may have a first crystal structure in which the anion is corner-sharing, the non-perovskite may have a second crystal structure comprising at least one of an orthorhombic structure, a hexagonal structure, or a perovskite-like structure, and 1−x−y may be greater than about 0.15.