公开(公告)号：US20130245322A1

公开(公告)日：2013-09-19

申请号：US13889404

申请日：2013-05-08

Applicant: UNIVERSITY OF SOUTHAMPTON

Inventor： Robert Raja ,  Alexander James Patterson

IPC: C07C249/04 ,  B01J27/187 ,  B01J27/185

CPC classification number: C07C249/04 ,  B01J27/1853 ,  B01J27/187 ,  B01J29/84 ,  B01J35/002 ,  C01B37/065 ,  C07C249/08 ,  C07C2601/14 ,  C07C251/44

Abstract: A redox ammoximation process in which a ketone or aldehyde is reacted with ammonia and oxygen in the presence of a catalyst, wherein: the catalyst is an aluminophosphate based redox catalyst having the qualitative general formula (I) M1M2AlPO-5 (I) in which M1 is at least one transition metal atom having redox catalytic capability; M2 is at least one metal atom in the (IV) oxidation state; M1 and M2 are different from each other; and a proportion of the phosphorous atoms in the M1M2AlPO-5 type structure are replaced by M2 atoms.

Abstract translation: 一种氧化还原氨肟化方法，其中酮或醛在催化剂存在下与氨和氧反应，其中：该催化剂是具有定性通式（I）M1M2AlPO-5（I）的磷酸铝基氧化还原催化剂，其中M1 是至少一种具有氧化还原催化能力的过渡金属原子; M2是（IV）氧化态中的至少一个金属原子; M1和M2彼此不同; M1M2AlPO-5型结构中的一部分磷原子被M2原子取代。

公开(公告)号：US08779124B2

公开(公告)日：2014-07-15

申请号：US13889404

申请日：2013-05-08

Applicant: University of Southampton

Inventor： Robert Raja ,  Alexander James Patterson

IPC: C07C249/04 ,  C07C251/32 ,  C07D201/04

CPC classification number: C07C249/04 ,  B01J27/1853 ,  B01J27/187 ,  B01J29/84 ,  B01J35/002 ,  C01B37/065 ,  C07C249/08 ,  C07C2601/14 ,  C07C251/44

Abstract: A redox ammoximation process in which a ketone or aldehyde is reacted with ammonia and oxygen in the presence of a catalyst, wherein: the catalyst is an aluminophosphate based redox catalyst having the qualitative general formula (I) M1M2AlPO-5 (I) in which M1 is at least one transition metal atom having redox catalytic capability; M2 is at least one metal atom in the (IV) oxidation state; M1 and M2 are different from each other; and a proportion of the phosphorous atoms in the M1M2AlPO-5 type structure are replaced by M2 atoms.

Abstract translation: 一种氧化还原氨肟化方法，其中酮或醛在催化剂存在下与氨和氧反应，其中：该催化剂是具有定性通式（I）M1M2AlPO-5（I）的磷酸铝基氧化还原催化剂，其中M1 是至少一种具有氧化还原催化能力的过渡金属原子; M2是（IV）氧化态中的至少一个金属原子; M1和M2彼此不同; M1M2AlPO-5型结构中的一部分磷原子被M2原子取代。