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    Oxo-Nitrogenated Iron Complex, Catalytic System Comprising Said Oxo-Nitrogenated Iron Complex and Process for the (Co)Polymerization of Conjugated Dienes
    1.
    发明申请
    Oxo-Nitrogenated Iron Complex, Catalytic System Comprising Said Oxo-Nitrogenated Iron Complex and Process for the (Co)Polymerization of Conjugated Dienes 有权

    公开(公告)号：US20210292354A1

    公开(公告)日：2021-09-23

    申请号：US16345015

    申请日：2018-01-18

    申请人： Versalis S.P.A.

    发明人： Anna Sommazzi ,  Pampaloni Guido ,  Giovanni Ricci ,  Francesco Masi ,  Filippo Renili

    IPC分类号： C07F15/02 ,  C08F136/08 ,  C08F136/06 ,  C07C251/08

    摘要： Oxo-nitrogenated iron complex having general formula (I): in which: R1 and R2, identical or different, represent a hydrogen atom; or they are selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R3 represents a hydrogen atom, or it is selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15 alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; X, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine, preferably chlorine; or they are selected from. linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR4 groups or —OR4 groups in which R4 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups; n is 2 or 3. Said oxo-nitrogenated iron complex having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

    Process for the preparation of (co) polymers of conjugated dienes in the presence of a catalytic system comprising a bis-imine complex of cobalt
    3.
    发明授权
    Process for the preparation of (co) polymers of conjugated dienes in the presence of a catalytic system comprising a bis-imine complex of cobalt 有权

    公开(公告)号：US09617360B2

    公开(公告)日：2017-04-11

    申请号：US14443093

    申请日：2013-12-19

    申请人： Versalis S.P.A.

    发明人： Giovanni Ricci ,  Anna Sommazzi ,  Giuseppe Leone ,  Francesco Masi ,  Aldo Boglia

    IPC分类号： C08F4/80 ,  C08F36/00 ,  C08F36/06 ,  C08F136/06 ,  C08F4/70

    CPC分类号： C08F36/06 ,  C08F4/7096 ,  C08F136/06 ,  C08F4/7006

    摘要： Process for the preparation of (co) polymers of conjugated dienes which comprises polymerizing at least one conjugated diene in the presence of a catalytic system comprising at least one bis-imine complex of cobalt having general formula (I) wherein: —n is 0 or 1; —Y represents a group —CR′R″— wherein R′ and R″, equal to or different from each other, represent a hydrogen atom; or a linear or branched C1-C20, preferably C1-C15, alkyl group; or a divalent aromatic group optionally substituted; —R1 and R2, equal to or different from each other, represent a hydrogen atom; or they are selected from a linear or branched Ci-C2o/preferably C1-C15, alkyl group optionally halogenated, cycloalkyl groups optionally substituted; or R1 and R2 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C1-C20, preferably C1-C15, alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 and R4, equal to or different from each other, represent a hydrogen atom; or they are selected from a linear or branched Ci-C20, preferably C1-C15, alkyl groups optionally halogenated, cycloalkyl groups optionally substituted, aryl groups optionally substituted; or R2 and R4 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched Ci-C2o, preferably C1-C15 alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R1 and R3 can be optionally bound to each other to form, together with the other atoms to which they are bound, a cycle containing from 3 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with linear or branched C1-C20, preferably C1-C15, alkyl groups, said cycle optionally containing other heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; X1 and X2, equal to or different from each other, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C1-C20 preferably C1-C15, alkyl groups, —OCOR5 groups or —OR3 groups wherein R5 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups.

    Bis-imine titanium complex, catalytic system comprising said bis-imine titanium complex and process for the (co)polymertzation of conjugated dienes
    5.
    发明授权
    Bis-imine titanium complex, catalytic system comprising said bis-imine titanium complex and process for the (co)polymertzation of conjugated dienes 有权

    公开(公告)号：US11299505B2

    公开(公告)日：2022-04-12

    申请号：US16649131

    申请日：2018-09-28

    申请人： Versalis S.P.A.

    发明人： Guido Pampaloni ,  Giovanni Ricci ,  Anna Sommazzi ,  Massimo Guelfi ,  Giuseppe Leone ,  Francesco Masi

    IPC分类号： C07F7/28 ,  C08F4/64 ,  C08F4/642 ,  C08F36/06

    摘要： Bis-imine titanium complex having general formula (I): wherein: R1 and R2, mutually identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated, C1-C20 alkyl groups, preferably C1-C15, optionally substituted cycloalkyl groups; R3 and R4, mutually identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated, C1-C20 alkyl groups, preferably C1-C15, optionally substituted cycloalkyl groups, optionally substituted aryl groups; X1, X2, X3 and X4, mutually identical or different, represent a halogen atom such as chlorine, bromine, iodine; or are selected from linear or branched C1-C20 alkyl groups, preferably C1-C15, —OCOR5 groups or —OR5 groups wherein R5 is selected from linear or branched C1-C20 alkyl groups, preferably C1-C15; or represent an acetylacetonate group (acac); provided that when R1 and R2 represent a methyl group and X1, X2, X3 and X4 represent a chlorine atom, R3 and R4 are different from 2,6-di-isopropylphenyl.

    Process for preparing conjugated diene (co)polymers in the presence of a catalytic system comprising a pyridyl iron (III) complex
    6.
    发明授权
    Process for preparing conjugated diene (co)polymers in the presence of a catalytic system comprising a pyridyl iron (III) complex 有权

    公开(公告)号：US10793653B2

    公开(公告)日：2020-10-06

    申请号：US16343716

    申请日：2017-10-20

    申请人： Versalis S.p.A.

    发明人： Giovanni Ricci ,  Guido Pampaloni ,  Anna Sommazzi ,  Massimo Guelfi ,  Francesco Masi

    IPC分类号： C08F36/06 ,  C07F15/02 ,  C08F36/08 ,  C08F136/08 ,  C08F136/06 ,  C08F236/06 ,  C08F4/70 ,  C08L9/00 ,  C08F236/08

    摘要： A process for preparing conjugated diene (co)polymers comprising polymerizing at least one conjugated diene in the presence of a catalytic system comprising: (a) at least one pyridyl iron (III) complex having general formula (I) or (II): wherein: —R1, R2, R3 and R4, identical or different, represent a hydrogen atom; or are selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; —R5 represents a hydrogen atom, or is selected from linear or branched, optionally halogenated C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; —X, identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine; or are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR6 groups or —OR6 groups wherein R6 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups. —n is 3; (b) at least one co-catalyst selected from organo-aluminum derivatives, preferably from: (b1) aluminum compounds having general formula (III): Al(R7)(R8)(R9) (IIl) wherein R7 represents a hydrogen atom, or is selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups, alkoxy groups; R8 and R9, identical or different, are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups; (b2) aluminoxanes having general formula (IV): (R10)2—Al—O—[-AI(R11)—O-]m-AI-(R12)2 (IV), wherein R10, R11 and R12, identical or different, represent a hydrogen atom, or a halogen atom such as chlorine, bromine, iodine, fluorine; or are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, said groups being optionally substituted with one or more silicon or germanium atoms; and m is an integer ranging from 0 to 1000; (b3) partially hydrolyzed organo-aluminum derivatives; (b4) haloaluminum alkyls having general formula (V) or (VI): AI(R13)p(X′)3-p (V) AI2(R13)q(X′)3-q (VI) wherein p is 1 or 2; q is an integer ranging from 1 to 5; R13, identical or different, are selected from linear or branched C1-C20 alkyl groups; X′ represents a chlorine or bromine atom, preferably chlorine; provided that said co-catalyst (b) is not selected from organo-boron derivatives.

    PROCESS FOR THE PREPARATION OF POLYISOPRENE WITH A MAINLY ALTERNATING CIS-1,4- ALT-3,4 STRUCTURE IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A PYRIDYL IRON COMPLEX
    9.
    发明申请
    PROCESS FOR THE PREPARATION OF POLYISOPRENE WITH A MAINLY ALTERNATING CIS-1,4- ALT-3,4 STRUCTURE IN THE PRESENCE OF A CATALYTIC SYSTEM COMPRISING A PYRIDYL IRON COMPLEX 审中-公开

    公开(公告)号：US20200369805A1

    公开(公告)日：2020-11-26

    申请号：US16962056

    申请日：2019-01-16

    申请人： VERSALIS S.P.A.

    发明人： Giovanni Ricci ,  Anna Sommazzi ,  Guido Pampaloni ,  Giuseppe Leone ,  Francesco Masi

    IPC分类号： C08F136/08 ,  C07F15/02 ,  B60C1/00 ,  A43B1/10

    摘要： Process for the preparation of polyisoprene with a mainly alternating cis-1,4-alt-3,4 structure comprising polymerizing isoprene in the presence of a catalytic system comprising: (a) at least one pyridyl iron complex having general formula (I): wherein: R1 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups; R2 is selected from linear or branched C1-C10, preferably C1-C3, alkyl groups; X, mutually identical or different, represent a halogen atom such as, for example, chlorine, bromine, iodine; or they are selected from linear or branched C1-C20, preferably C1-C15, alkyl groups, —OCOR3 groups or —OR3 groups wherein R3 is selected from linear or branched C1-C20, preferably C1-C15, alkyl groups. n is 2 or 3; (b) at least one co-catalyst selected from organo-derivative compounds of aluminum, preferably from (b1) aluminoxanes having general formula (II): (R4)2—Al—O—[—Al(R5)—O—]m—Al—(R6)2  (II) wherein R4, R5 and R6, mutually identical or different, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, bromine, iodine, fluorine; or they are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, said groups being optionally substituted with one or more silicon or germanium atoms; and m is an integer ranging from 0 to 1000; (b2) aluminum compounds having general formula (III): Al(R7)(R8)(R9)  (III) wherein R7 is a hydrogen atom, or is selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups, alkoxy groups; R8 and R9, mutually identical or different, are selected from linear or branched C1-C20 alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, arylalkyl groups; wherein the molar ratio between the aluminum present in the co-catalyst and the iron present in the iron pyridyl complex having general formula (I) is ranging from 5 to 60, preferably from 8 to 55.