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公开(公告)号：US4386965A
公开(公告)日：1983-06-07
申请号：US223174
申请日：1981-01-07
申请人： Werner Fringeli , Max Flubacher , Alain Lauton
发明人： Werner Fringeli , Max Flubacher , Alain Lauton
IPC分类号： D21H19/10 , D21H19/36 , D21H19/38 , D21H19/62 , D21H21/30 , C09D3/20 , C09K11/06 , D06P3/852
摘要： A process is disclosed for obtaining coating compositions of improved whiteness for coating paper or cardboard using fluorescent whitening agents of the bis-triazinylaminostilbene-2,2'-disulfonic acid series, which process comprises adding to the coating compositions, in addition to the respective fluorescent whitening agent, an acid phosphoric acid ester of an oxyalkylated fatty amine of the formula ##STR1## or an alkali metal salt, ammonium salt or amine salt thereof, wherein R is an aliphatic hydrocarbon radical of 8 to 22 carbon atoms, Y.sub.1 and Y.sub.2 are both hydrogen, or one of Y.sub.1 and Y.sub.2 is hydrogen and the other is methyl, X is the acid radical of phosphoric acid, the acid hydrogen atoms of which radical can be replaced by alkali metal ions, ammonium ions or amine salt ions, and m and n are integers, the sum of which is 2 to 30. To the coating compositions can also be added organic solubilizers, non-ionic or anionic surfactants and/or polar organic compounds. Coating compositions which contain the above fluorescent whitening agents and assistants are also disclosed.
摘要翻译： 公开了一种用于获得使用双 - 三嗪基氨基芪-2,2'-二磺酸系列的荧光增白剂涂布纸或纸板的改善白度的涂料组合物的方法，该方法包括向各涂料组合物中加入除了各自的荧光 增白剂，式（1）的烷氧基化脂肪胺的酸式磷酸酯或其碱金属盐，铵盐或胺盐，其中R是8-22个碳原子的脂族烃基，Y1 和Y2都是氢，Y1和Y2之一是氢，另一个是甲基，X是磷酸的酸基，其自由基的酸性氢原子可以被碱金属离子，铵离子或胺盐离子代替 ，m和n为整数，其总和为2至30.对于涂料组合物，还可以加入有机增溶剂，非离子或阴离子表面活性剂和/或极性有机化合物。 还公开了含有上述荧光增白剂和助剂的涂料组合物。
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公开(公告)号：US4339238A
公开(公告)日：1982-07-13
申请号：US223173
申请日：1981-01-07
申请人： Werner Fringeli , Alain Lauton
发明人： Werner Fringeli , Alain Lauton
CPC分类号： D06L3/1264 , D21H21/30
摘要： The invention relates to formulations which are stable to metal ions and contain a stilbene fluorescent whitening agent which is substituted by sulfo groups, and an acid phosphoric acid ester of an oxyalkylated fatty amine of the formula ##STR1## wherein R is an aliphatic hydrocarbon radical of 8 to 22 carbon atoms, Y.sub.1 and Y.sub.2 are preferably hydrogen, X is the acid radical of phosphoric acid and the sum of n+m is 2 to 30, preferably 4 to 20. The formulations can additionally contain various assistants such as non-ionic or anionic surfactants and/or organic solvents or polar compounds. The formulations are used for whitening natural and synthetic fabrics, e.g. made from polyamide, cellulose and blended fabrics, as well as paper.
摘要翻译： 本发明涉及对金属离子稳定并含有被磺基取代的茋荧光增白剂的制剂，以及下式的烷氧基化脂肪胺的酸式磷酸酯，其中R是脂族烃基 8〜22个碳原子，Y1和Y2优选为氢，X为磷酸的酸基，n + m的和为2〜30，优选为4〜20。配方可另外含有各种辅助剂，如非离子型 或阴离子表面活性剂和/或有机溶剂或极性化合物。 该制剂用于增白天然和合成织物，例如， 由聚酰胺，纤维素和混纺织物制成，以及纸。
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公开(公告)号：US5518657A
公开(公告)日：1996-05-21
申请号：US278708
申请日：1994-07-22
申请人： Werner Fringeli , Josef Zelger
发明人： Werner Fringeli , Josef Zelger
IPC分类号： C07D251/54 , C07C309/32 , C07C309/39 , C09B67/46 , C11D3/42 , D06L3/12 , C09K11/06
CPC分类号： D06L3/1214 , C11D3/42 , D06L3/1264
摘要： Storage-stable formulations of whitening mixtures comprising at least two anionic fluorescent whiteners, which preferably contain at least one sulfonic acid radical; an anionic polysaccharide; dispersants and water, and if appropriate auxiliaries. These formulations are particularly suitable for the preparation of liquid washing agents.
摘要翻译： 含有至少两种阴离子荧光增白剂的美白混合物的储存稳定配方，其优选含有至少一个磺酸基; 阴离子多糖; 分散剂和水，以及适当的助剂。 这些制剂特别适用于制备液体洗涤剂。
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公开(公告)号：US5051111A
公开(公告)日：1991-09-24
申请号：US275231
申请日：1988-11-22
CPC分类号： D06L3/1264 , D06L3/125 , Y10S8/922
摘要： There are disclosed aqueous dispersions comprising water-insoluble or sparingly soluble fluorescent whitening agents, water-soluble fluorescent whitening agents, dispersants, optional solubilizers, further optional assistants and a copolymer of 2-vinylpyrrolidone and 3-vinylpropionic acid, their preparation and the use thereof for whitening polyester/cellulose fiber material. These novel dispersions are storage-stable and temperature-stable.
摘要翻译： 公开了包含水不溶性或微溶性荧光增白剂，水溶性荧光增白剂，分散剂，任选的增溶剂，其它任选助剂和2-乙烯基吡咯烷酮和3-乙烯基丙酸的共聚物的水分散体，其制备及其用途 用于增白聚酯/纤维素纤维材料。 这些新型分散体是储存稳定和温度稳定的。
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公开(公告)号：US5423905A
公开(公告)日：1995-06-13
申请号：US276282
申请日：1994-07-18
申请人： Werner Fringeli
发明人： Werner Fringeli
CPC分类号： D06M16/006 , A01N47/30 , C14C9/00
摘要： The invention relates to a formulation for protecting keratinous material from attack by pests that feed on keratin, comprising (A) at least one diphenylurea of formula ##STR1## wherein R.sub.1 is hydrogen or 4-chlorophenoxy-6-sulfonate,R.sub.2 is hydrogen or chloro,R.sub.3 is chloro or trifluoromethyl,R.sub.4 is hydrogen or chloro, andR.sub.5 is hydrogen or trifluoromethyl, and(B) at least one glycol, and to a process for protecting keratinous material against attack by pests that feed on keratin with the novel formulation.
摘要翻译： 本发明涉及一种用于保护角质材料免于受角蛋白侵袭的害虫的制剂，其包含（A）至少一种式（1）的二苯基脲，其中R1是氢或4-氯苯氧基-6-磺酸盐，R2是 氢或氯，R 3是氯或三氟甲基，R 4是氢或氯，R 5是氢或三氟甲基，和（B）至少一种二醇，以及保护角质材料免受害虫攻击的方法， 新颖的配方。
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公开(公告)号：US5053055A
公开(公告)日：1991-10-01
申请号：US275236
申请日：1988-11-22
申请人： Werner Fringeli , Martin Jollenbeck
发明人： Werner Fringeli , Martin Jollenbeck
CPC分类号： E21B43/247 , D06L3/125 , D06L3/1264 , Y10S8/922
摘要： There are disclosed aqueous dispersions comprising water-insoluble or sparingly soluble fluorescent whitening agents, dispersants, further optional assistants and a copolymer of 2-vinylpyrrolidone and 3-vinylpropionic acid, their preparation and the use thereof for whitening textile fibre materials. These novel dispersions are storage-stable.
摘要翻译： 公开了包含水不溶性或微溶性荧光增白剂，分散剂，其它任选的助剂和2-乙烯基吡咯烷酮和3-乙烯基丙酸的共聚物的水分散体，它们的制备及其用于增白织物纤维材料的用途。 这些新型分散体是储存稳定的。
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公开(公告)号：US4605511A
公开(公告)日：1986-08-12
申请号：US397273
申请日：1982-07-12
申请人： Werner Fringeli
发明人： Werner Fringeli
CPC分类号： D06L3/1264 , C09B69/04
摘要： Stilbene fluorescent brightener solutions which are stable to metal ions and metal catalysts and contain a stilbene fluorescent brightener substituted by sulfo groups and a fatty amine oxyalkylation product of the formula ##STR1## in which Q is an aliphatic hydrocarbon radical having 12 to 22 carbon atoms, M is hydrogen or an alkali metal ion, ammonium ion or amine salt ion and m and n are integers, the sum of m and n being at least 2 and not more than 50, and their use for the fluorescent brightening of natural and synthetic fibrous materials.
摘要翻译： 对金属离子和金属催化剂稳定并含有被磺基取代的茋荧光增白剂和式为“IMAGE”的脂肪胺烷氧基化产物的二苯乙烯荧光增白剂溶液，其中Q是具有12-22个碳原子的脂族烃基， M是氢或碱金属离子，铵离子或胺盐离子，m和n是整数，m和n之和至少为2并且不大于50，它们用于天然和合成纤维的荧光增白 材料
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8.发明授权
公开(公告)号：US4298490A
公开(公告)日：1981-11-03
申请号：US102056
申请日：1979-12-10
CPC分类号： C11D3/42
摘要： The invention relates to the production of washing powders of stabilized or enhanced appearance which contain a fluorescent whitening agent of the formula ##STR1## wherein X.sub.1 is hydrogen, chlorine, bromine, alkyl or alkoxy, X.sub.2 is hydrogen or alkyl and M is hydrogen, an alkali metal or ammonium ion. The stabilizing or enhancement of the appearance is effected by first dissolving or dispersing the fluorescent whitening agent in a mixture of water and a polyvinyl alcohol or polyvinyl pyrrolidone which is soluble or is able to swell in water, adding this solution or dispersion to the washing powder slurry and drying the slurry. The solution or dispersion can also be subsequently sprayed onto the dried residual washing powder. The appearance can be further enhanced by employing a polyethylene glycol, a surfactant containing ethyleneoxy and/or propyleneoxy groups, and/or a cellulose ether, in addition to the polymer in the solution or dispersion. The solution or dispersion comprising fluorescent whitening agent and polymer can also alternatively be dried, preferably by spray drying, to produce a preparation which, after it has been suspended in water, can also be added to the washing powder slurry. The slurry is then dried, preferably by spray drying.
摘要翻译： 本发明涉及具有稳定或增强外观的洗涤粉的制备，其含有下式的荧光增白剂，其中X 1是氢，氯，溴，烷基或烷氧基，X 2是氢或烷基，M是氢， 碱金属或铵离子。 通过首先将荧光增白剂溶解或分散在水和聚乙烯醇或聚乙烯吡咯烷酮的混合物中，使其溶解或能够在水中溶胀，将该溶液或分散体加入到洗涤粉末中来实现外观的稳定或增强 浆料和干燥浆料。 溶液或分散体也可随后喷洒到干燥的残留洗涤粉末上。 除了溶液或分散体中的聚合物之外，还可以通过使用聚乙二醇，含有乙烯氧基和/或丙烯氧基的表面活性剂和/或纤维素醚来进一步增强外观。 包含荧光增白剂和聚合物的溶液或分散体也可以干燥，优选通过喷雾干燥来制备在悬浮在水中之后也可以加入洗涤粉末浆料中的制剂。 然后将浆料干燥，优选通过喷雾干燥。
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9.发明授权Bis-triazinylaminostilbene compounds and their use as fluorescent brightening agents 失效双三嗪基氨基芪化合物及其作为荧光增白剂的用途
公开(公告)号：US4212763A
公开(公告)日：1980-07-15
申请号：US919115
申请日：1978-06-26
申请人： Werner Fringeli
发明人： Werner Fringeli
IPC分类号： C07D251/38 , C07D251/52 , C08K5/00 , C08K5/34 , C08K5/3477 , C08L33/00 , C08L33/02 , C08L77/00 , C09B57/00 , D06L3/12 , D21H19/10 , D21H21/28 , C07D403/06 , C07D401/14
CPC分类号： C07D251/52 , C07D251/38
摘要： Bis-triazinylaminostilbene compounds of the formula ##STR1## in which R.sub.1 is alkyl, alkenyl, cyclohexyl or phenylalkyl, R.sub.2 is hydrogen, alkyl, cyclohexyl, benzyl, alkyl which is substituted by hydroxyl, cyano, sulpho or carbamoyl, alkoxyalkyl or hydroxyalkoxyalkyl or alkoxyalkoxyalkyl or mono- or di-alkylaminoalkyl, and R.sub.3 is hydrogen, alkyl, alkyl which is substituted by hydroxyl, cyano or sulpho, or alkoxyalkyl or hydroxyalkoxyalkyl or R.sub.2 and R.sub.3 together with the nitrogen atom to which they are bonded are a morpholine ring or a pyrrolidine, piperidine, hexamethyleneimine or piperazine ring which is unsubstituted or substituted by 1 or 2 alkyl groups, and M is hydrogen or an alkali metal, ammonium or amine ion, and, if R.sub.2 or R.sub.3 is hydroxyalkyl, R.sub.1 is methyl, cyclohexyl or alkenyl only, and their use as fluorescent brightening agents for organic material of high molecular weight are disclosed.
摘要翻译： 其中R 1为烷基，链烯基，环己基或苯基烷基，R 2为氢，烷基，环己基，苄基，被羟基，氰基，磺基或氨基甲酰基取代的烷基， 烷氧基烷基或羟基烷氧基烷基或烷氧基烷氧基烷基或单 - 或二 - 烷基氨基烷基，R3为氢，烷基，被羟基，氰基或磺基取代的烷基，或烷氧基烷基或羟基烷氧基烷基或R2和R3与它们所键合的氮原子一起取代 吗啉环或吡咯烷，哌啶，六亚甲基亚胺或哌嗪环，其未被取代或被1或2个烷基取代，M为氢或碱金属，铵或胺离子，如果R2或R3为羟烷基，R1为 甲基，环己基或烯基，并且它们用作高分子量有机材料的荧光增白剂。
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10.发明授权
公开(公告)号：US4364845A
公开(公告)日：1982-12-21
申请号：US55417
申请日：1979-07-06
申请人： Werner Fringeli
发明人： Werner Fringeli
CPC分类号： D06L3/1264 , D21H21/30
摘要： Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners, which are stable on storage, containing a stilbene fluorescent brightener substituted by sulfo groups and a lactam of the formula ##STR1## in which m is 0 or an integer between 1 and 9, and their use for the fluorescent brightening of high molecular weight organic material.
摘要翻译： 含有磺基的荧光增白剂的浓缩水溶液在储存时稳定，含有被磺基取代的芪荧光增白剂和式为“IMAGE”的内酰胺，其中m为0或1至9之间的整数，并且它们 用于高分子量有机材料的荧光增白。
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