Thermal transfer printing with z-alkyl-phenoxy anthraquinone dye mixture
    1.
    发明授权
    Thermal transfer printing with z-alkyl-phenoxy anthraquinone dye mixture 失效
    用Z-烷基 - 苯氧基蒽醌染料混合物进行热转印

    公开(公告)号:US4725284A

    公开(公告)日:1988-02-16

    申请号:US886644

    申请日:1986-07-18

    摘要: The invention relates to:(A) A thermal transfer printing sheet comprising a substrate having a coating comprising either,(i) a dye of the formula: ##STR1## wherein R.sup.1 is C.sub.5-12 -alkyl;R.sup.2 is H or C.sub.1-12 -alkyl; and Rings A & B are optionally substituted in the free positions by non-ionic groups; or(ii) a mixture of at least two dyes of the formula: ##STR2## wherein R.sup.3 is H or C.sub.1-12 -alkyl;R.sup.4 is H or C.sub.1-4 -alkyl; and Rings A & B are optionally substituted in the free positions by non-ionic groups; provided that in at least one component R.sup.3 is C.sub.5-12 -alkyl and in at least one other component R.sup.3 is H or C.sub.1-4 -alkyl;(B) A thermal transfer printing process using the transfer sheets; and(C) The mixture of dyes defined in (A)(ii).

    摘要翻译: 本发明涉及:(A)一种热转印片,其包含具有涂层的基底,该涂层包含:(i)下式的染料:其中R1为C5-12-烷基; R2是H或C1-12 - 烷基; 环A和B任选在非离子基团的任意位置被取代; 或(ii)至少两种下式的染料的混合物:其中R 3是H或C 1-12 - 烷基; R4是H或C1-4烷基; 环A和B任选在非离子基团的任意位置被取代; 条件是在至少一个组分R 3为C 5- 12 - 烷基且至少一个其它组分R 3为H或C 1-4 - 烷基; (B)使用转印纸的热转印印刷工艺; 和(C)(A)(ii)中定义的染料混合物。

    Compositions and inks containing disazo dyes
    2.
    发明授权
    Compositions and inks containing disazo dyes 失效
    含有双偶氮染料的组合物和油墨

    公开(公告)号:US07481522B2

    公开(公告)日:2009-01-27

    申请号:US10516496

    申请日:2003-06-05

    IPC分类号: G01D11/00

    CPC分类号: C09D11/30

    摘要: A process for printing an image on a substrate including applying thereto a composition including a liquid medium and a compound of Formula (1) A-N═N-L-N═N-A wherein: each A independently is optionally substituted aryl or heteroaryl; and L is an optionally substituted, optionally metallised 1,8-dihydroxynaphthylene group; provided that: (i) at most one of the groups represented by A has a hydroxy substituent ortho to the —N═N— groups shown in Formula (1); and (ii) Formula (1) is not: Also claimed are compositions for printing, compounds and processes for making the compounds.

    摘要翻译: 一种在基材上印刷图像的方法,包括向其施涂包含液体介质和式(1)A-N-N-L-N-N-A的化合物的组合物,其中:每个A独立地为任选取代的芳基或杂芳基; 并且L是任选取代的任选金属化的1,8-二羟基萘基; 条件是:(i)由A表示的至多一个基团具有与式(1)所示的-N-N-基邻位的羟基取代基; 和(ii)式(1)不是:还要求的是用于印刷的组合物,化合物和制备该化合物的方法。

    Thermal transfer printing
    3.
    发明授权
    Thermal transfer printing 失效
    热转印

    公开(公告)号:US4859651A

    公开(公告)日:1989-08-22

    申请号:US227990

    申请日:1988-08-03

    摘要: A thermal transfer printing sheet, suitable for use in a thermal transfer printing process, comprising a substrate having a coating comprising a water-insoluble dye of the formula: ##STR1## wherein R represents the residue of an active methylene compound;X represents hydrogen, halogen or an optionally substituted alkyl, aryl or heteroaryl radical;Y represents cyano, nitro, alkanoyl, aroyl, alkylsulphonyl, arylsulphonyl or a group of the formula --COOR.sup.1 or --CONR.sup.2 R.sup.3 wherein R.sup.1 represents a hydrocarbyl radical and each of R.sup.2 and R.sup.3, independently, represents hydrogen or a hydrocarbyl radical; andE represents the residue of a coupling component.

    AZO dyes and compositions comprising such dyes
    5.
    发明授权
    AZO dyes and compositions comprising such dyes 失效
    AZO染料和包含这种染料的组合物

    公开(公告)号:US06290763B1

    公开(公告)日:2001-09-18

    申请号:US09269061

    申请日:1999-03-18

    IPC分类号: C09D1102

    CPC分类号: C09D11/328 C09B43/16

    摘要: Azo dyes of Formula (1) have utility as dyes for ink-jet printing, where Formula (1) represents: which comprises any suitable form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: n represents from 1 to 5 inclusive; R1, R1B, R4 and R4B each independently comprises at least one of the following substituents, optionally substituted: H, C1-8alkyl; C1-8,alkoxy; —NHCOH, C1-8alkylcarbonylamino; and —NHCONR5R6 where R5 and R6 each independently comprises at least one of the following substituents: H, C1-8alkyl and aryl; and R2 and R3 each independently comprises at least one of the following substituents, optionally substituted: H; C1-8alkoxy; -NHC1-8alkyleneOH, —SC1-8-alkyleneSO3H; -NHC1-8alkyleneN(C1-8alkyl)2; where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link, where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link; a moiety of Formula (2) where m and p is each independently from 0 to 5 inclusive, provided that (m+p) is from 1 to 5 inclusive; and R1A, R2A, R4A and R4C each independently comprises at least one of those optionally substituted substituents as defined herein for R1, R2, R4 and R4B respectively; and any other suitable labile or non-labile substituent not mentioned above; where the optional substituents herein comprise: C1-4alkyl (optionally substituted with at least one halo)., C1-4alkoxy (optionally substituted with at least one halo), carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.

    摘要翻译: 式(1)的偶氮染料可用作喷墨印刷用染料,其中式(1)表示:其包含任何合适形式的化合物:例如盐; 立体异构体,两性离子,多晶型物,复合物,同位素形式,它们在同一物种及其混合物中的组合; 其中:n表示1〜5; R1,R1B,R4和R4B各自独立地包含至少一个以下取代基,任选被取代:H,C 1-8烷基; C 1-8,烷氧基; -NHCOH,C 1-8烷基羰基氨基; 和-NHCONR 5 R 6,其中R 5和R 6各自独立地包含以下取代基中的至少一个:H,C 1-8烷基和芳基; 且R 2和R 3各自独立地包含至少一个以下取代基,任选地被取代:H; C 1-8烷氧基 -NHC1-8亚烷基OH,-SC1-8-亚烷基SO3H; -NHC1-8亚烷基N(C1-8烷基)2;其中X包括以下之一:-NHC1-8亚烷基; -NH 2 SO 2 NHC 1-8亚烷基; 和直链,其中X包含以下之一:-NHC1-8亚烷基; -NH 2 SO 2 NHC 1-8亚烷基; 和直链;式(2)的部分,其中m和p各自独立地为0至5,其中(m + p)为1至5(包括端值); R1A,R2A,R4A和R4C各自独立地包含至少一种如本文定义的对于R 1,R 2,R 4和R 4B定义的那些取代的取代基; 以及上文未提及的其他合适的不稳定或非不稳定取代基; 其中本文的任选取代基包括:C 1-4烷基(任选被至少一个卤素取代),C 1-4烷氧基(任选被至少一个卤素取代),羧基,磺基,羟基,氨基,巯基,氰基,硝基和卤素。

    Bisazo inkjet dyes
    6.
    发明授权
    Bisazo inkjet dyes 失效
    双偶氮喷墨染料

    公开(公告)号:US5882391A

    公开(公告)日:1999-03-16

    申请号:US948037

    申请日:1997-10-09

    摘要: A bisazo dye of Formula (1) and salts thereof: ##STR1## in which R is H or ##STR2## R.sub.1 and R.sub.2 each independently is H, optionally substituted C.sub.1-4 -alkyl or optionally substituted aryl;R.sub.3 and R.sub.5 together with the carbon atoms to which they are attached form a 5- or 6-membered carbocyclic ring which is optionally substituted by SO.sub.3 H;R.sub.4 is H;R.sub.6 is COOH;n is 1, 2 or 3; andp is 1, 2, 3 or 4.The dyes are useful for ink jet printing.

    摘要翻译: 式(1)的双偶氮染料及其盐:其中R为H或R 1和R 2各自独立地为H,任选取代的C 1-4 - 烷基或任选取代的芳基的式(1) R3和R5与它们所连接的碳原子一起形成任选被SO 3 H取代的5-或6-元碳环; R4是H; R6是COOH; n为1,2或3; 并且p是1,2,3或4.这些染料可用于喷墨印刷。

    Thermal transfer printing
    8.
    发明授权

    公开(公告)号:US4892859A

    公开(公告)日:1990-01-09

    申请号:US225213

    申请日:1988-07-28

    摘要: A thermal transfer printing sheet suitable for use in a thermal transfer printing process, comprising a substrate having a coating comprising a dye of the formula: ##STR1## wherein: R represents an optionally substituted alkyl, aryl or aralkyl radical;n is one or 2;X represents hydrogen, halogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C.sub.1-4 -alkoxy, C.sub.1-4 -alkylthio, beta-cyanoethyl, C.sub.1-4 -alklcarbonylamino or C.sub.1-4 -alkylsulphonylamino;Y represents hydrogen or methoxy, andeach of R.sup.1 and R.sup.2 independently, represents allyl, C.sub.1-2 -alkyl or C.sub.1-4 -alkyl substituted by a group selected from cyano, C.sub.1-4 -alkoxycarbonyl, C.sub.1-4 -alkylcarbonyloxy, R.sup.3 CONH--, R.sup.3 NHCO-- and R.sup.3 NHCOO-- which R.sup.3 represents C.sub.1-4 -alkyl or optionally substituted aryl.

    Thermal transfer printing
    9.
    发明授权
    Thermal transfer printing 失效
    热转印

    公开(公告)号:US4808568A

    公开(公告)日:1989-02-28

    申请号:US46187

    申请日:1987-05-05

    摘要: A thermal transfer printing sheet, suitable for use in a thermal transfer printing process, especially for the conversion of a digital image into a visible print, comprising a substrate having a coating comprising a dye of the formula: ##STR1## whereinRing A is unsubstituted or carries, in the 2- or 4-position with respect to the azo link, at least one group selected from --CX.sub.3, X.sup.1, CN, NO.sub.2, --OCO.Y, --CO.Y, --CO.H, --OSO.sub.2.Y and --SO.sub.2.Y, provided that A is substituted when Z is CH.sub.3 and R is C.sub.2-4 -alkyl;X & X.sup.1 are each independently halogen;Y is selected from R.sup.1, --OR.sup.1, SR.sup.1 and --NR.sup.1 R.sup.2 ;R.sup.1 is selected from C.sub.1-12 -alkyl, C.sub.1-12 -alkyl interrupted by one or two groups selected from --O--, --CO--, O.CO-- and --CO.O--, C.sub.3-7 -cycloalkyl, mono- or bi-cyclic aryl and C.sub.1-3 -alkylene attached to an adjacent carbon atom on Ring A;R.sup.2 is selected from H, C.sub.1-12 -alkyl, C.sub.3-7 -cycloalkyl and mono- or bi-cyclic aryl;Z is C.sub.1-12 -alkyl or phenyl; andR is selected from C.sub.2-12 -alkyl unbranched in the alpha-position, C.sub.2-12 -alkyl unbranched in alpha-position and interrupted by one or two groups selected from --O--, --CO--, O.CO-- and --CO.O--, phenyl, C.sub.1-4 -alkylphenyl, biphenyl and biphenyl interrupted by a group selected from --O--, --CO--, O.CO-- and --CO.O--, each of which is free from hydrogen atoms capable of intermolecular hydrogen bonding.

    摘要翻译: 一种适用于热转印印刷工艺的热转印片材,特别是用于将数字图像转化成可见印刷物的热转印片材,其包含具有包含下式染料的涂层的基材:其中环A为未取代的 或在相对于偶氮键的2-或4-位上携带至少一个选自-CX 3,X 1,CN,NO 2,-OCO.Y,-CO.Y,-CO.H,-OSO 2的基团 Y和-SO 2 Y,条件是当Z为CH 3且A为C 2-4烷基时,A为取代基; X&X1各自独立地为卤素; Y选自R1,-OR1,SR1和-NR1R2; R 1选自C 1-12 - 烷基,被一个或两个选自-O - , - CO-,OCO-和-COO基团间隔的C 1-12 - 烷基,C 3-7 - 环烷基, 或环环A上的相邻碳原子上的双环芳基和C1-3亚烷基; R 2选自H,C 1-12 - 烷基,C 3-7 - 环烷基和单环或双环芳基; Z是C 1-12 - 烷基或苯基; 并且R选自在α-位上未分支的C 2-12 - 烷基,在α-位上未分支并被一个或两个选自-O - , - CO-,O.CO-和 - CO,O-,苯基,C 1-4 - 烷基苯基,联苯基和联苯被选自-O - , - CO-,OCO-和-CO.O-的基团中断,各自不含氢原子 的分子间氢键。