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公开(公告)号：US5237105A
公开(公告)日：1993-08-17
申请号：US891341
申请日：1992-05-29
申请人： William H. Summerlin
发明人： William H. Summerlin
CPC分类号： C07C45/50
摘要： A method for removing cobalt values from the crude product of a cobalt-catalyzed hydroformylation reaction which utilizes the same equipment in two different operating sequences to accommodate olefinic feedstocks having a wide range of carbon numbers. Olefinic feedstocks having a carbon number in the range C.sub.4 -C.sub.14, more preferably C.sub.5 -C.sub.7, can be decobalted by the application of an acid-air cobalt demetalling step upstream of the stripping step of a Cobalt Flash hydroformylation catalyst recovery process; whereas C.sub.7 to C.sub.20 olefinic feedstocks, more preferably C.sub.8 -C.sub.14, can be decobalted by application of the acid-air cobalt demetalling step downstream of the stripping step.
摘要翻译： 从钴催化加氢甲酰化反应的粗产物中除去钴值的方法，该方法利用两种不同操作顺序的相同设备来适应具有宽范围碳数的烯烃原料。 通过在钴闪加氢甲酰化催化剂回收方法的汽提步骤的上游施加酸 - 空气钴脱金属步骤，可以使碳数在C4-C14范围内，更优选C5-C7的烯烃原料脱羰; 而C7至C20烯烃原料，更优选为C8-C14，可以通过在汽提步骤下游施加酸 - 空气钴脱金属步骤来脱钯。
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2.发明授权
公开(公告)号：US5410090A
公开(公告)日：1995-04-25
申请号：US224911
申请日：1994-04-08
摘要： A method for removing cobalt values from the crude product of a cobalt-catalyzed hydroformylation reaction by the application of an airless cobalt demetalling step upstream of the stripping step of a Cobalt Flash hydroformylation catalyst recovery process for C.sub.4 to C.sub.14 olefins, whereby no oxygen is required to oxidize cobalt carbonyls to their cobaltous form. This airless demetalling step may also be used downstream of the stripping step in the case of C.sub.7 to C.sub.20 olefins to remove carbonyls from a water soluble cobaltous salt and carbon carbonyl stream which is taken as bottoms from the stripper reactor.
摘要翻译： 通过在C4至C14烯烃的钴闪加氢甲酰化催化剂回收方法的汽提步骤的上游施加无气体脱钴步骤来从钴催化的加氢甲酰化反应的粗产物中除去钴值的方法，由此不需要氧气 以将羰基钴氧化成它们的钴耳托形式。 在C7至C20烯烃的情况下，该无气体脱金属步骤也可用于汽提步骤的下游，以从水溶性钴铵盐中除去羰基，并将碳羰基物流从汽提塔反应器中作为塔底产物。
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公开(公告)号：US5237104A
公开(公告)日：1993-08-17
申请号：US891317
申请日：1992-05-29
申请人： William H. Summerlin
发明人： William H. Summerlin
IPC分类号： C07C45/50
CPC分类号： C07C45/50
摘要： An olefin of a heavier molecular weight than the feed olefin in a hydroformylation reaction process is used as an absorbent for recovering hydro cobalt carbonyl stripped from an oxonation reactor product. The cobalt in the stripping gas is completely absorbed but light hydrocarbons, e.g., hydrocarbons having a carbon number of C.sub.7 or less, are only partially absorbed, thus permitting hydro cobalt carbonyl to be recycled to the oxonation reactor without a continuing concentration build up of light hydrocarbons, e.g., paraffins.
摘要翻译： 使用在加氢甲酰化反应过程中比进料烯烃更重的分子量的烯烃作为用于回收从催化反应器产物中汽提的羰基钴的吸收剂。 汽提气体中的钴被完全吸收，但碳氢化合物（例如碳数为C7以下的碳氢化合物）仅被部分吸收，因此允许氢化钴羰基再循环到氧化反应器中，而不会持续浓缩聚集光 烃类，如石蜡。
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公开(公告)号：US5321168A
公开(公告)日：1994-06-14
申请号：US122859
申请日：1993-09-16
IPC分类号： B01J31/20 , C07C29/16 , C07C45/50 , C07C27/22 , C07C29/141 , C07C31/125
CPC分类号： B01J31/08 , B01J23/44 , B01J31/20 , B01J31/403 , B01J31/4038 , B01J31/4092 , C07C29/16 , C07C45/50 , B01J2231/321 , B01J2531/845 , Y02P20/584
摘要： Noble metal or other preformer catalysts used to convert cobalt salts to hydrido cobalt carbonyl for use in the oxonation of olefins are activated or regenerated by treatment with H.sub.2 O at 120.degree. to 170.degree. C., 13.78 MPa (2,000 psig) to 31.00 MPa (4,500 psig) for 2-50 hours.
摘要翻译： 用于将钴盐转化为氢化羰基钴的贵金属或其他预成型催化剂用于烯烃的羰化用于通过在120-170℃，13.78MPa（2000psig）至31.00MPa（4,500）下用H 2 O处理来活化或再生 psig）2-50小时。
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