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公开(公告)号：US5962386A
公开(公告)日：1999-10-05
申请号：US964654
申请日：1997-11-05
CPC分类号： C11D3/3932
摘要： Automatic dishwashing detergent compositions comprising certain cobalt catalysts are provided. More specifically, the invention relates to automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits (especially tea stain removal) through the selection of cobalt bleach catalyst having the formula:�Co(NH.sub.3).sub.n (M).sub.m (B).sub.b !T.sub.ywherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; m is 0, 1 or 2 (preferably 1); B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0), and when b=0, then m+n=6, and when b=1, then m=0 and n=4; and T is one or more appropriately selected counteranions present in a number y, where y is an integer to obtain a charge-balanced salt (preferably y is 1 to 3; most preferably 2 when T is a -1 charged anion); and wherein further said catalyst has a base hydrolysis rate constant of less than 0.23M.sup.-1 s.sup.-1 (25.degree. C.).Preferred automatic dishwashing compositions comprise amylase and/or protease enzymes. Included are methods for washing tableware in domestic automatic dishwashing appliances using the cobalt catalysts.
摘要翻译： 提供了包含某些钴催化剂的自动餐具洗涤剂组合物。 更具体地，本发明涉及通过选择具有下式的钴漂白催化剂提供增强的清洁/漂白益处（特别是茶脱色）的自动餐具洗涤剂：[Co（NH 3）n（M）m（B）b] 钴处于+3氧化态; n为4或5（优选5）; M是通过一个位点与钴配位的一种或多种配体; m为0,1或2（优选1）; B是通过两个位点与钴配位的配体; b为0或1（优选为0），当b = 0时，m + n = 6，当b = 1时，m = 0，n = 4; 并且T是以y为单位存在的一个或多个适当选择的余离子，其中y是获得电荷平衡盐的整数（优选y为1至3;当T为带负电荷的阴离子时最优选为2）; 并且其中所述催化剂的另一个基础水解速率常数小于0.23M-1s -1（25℃）。 优选的自动餐具洗涤组合物包含淀粉酶和/或蛋白酶。 包括在使用钴催化剂的国内自动洗碗设备中洗餐具的方法。
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公开(公告)号：US5705464A
公开(公告)日：1998-01-06
申请号：US795898
申请日：1997-02-06
CPC分类号： C11D3/3932
摘要： Automatic dishwashing detergent compositions comprising certain cobalt catalysts are provided. More specifically, the invention relates to automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits (especially tea stain removal) through the selection of cobalt bleach catalyst having the formula: �Co(NH.sub.3).sub.n (M).sub.m (B).sub.b !T.sub.y wherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; m is 0, 1 or 2 (preferably 1); B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0), and when b=0, then m+n=6, and when b=l, then m=0 and n=4; and T is one or more appropriately selected counteranions present in a number y, where y is an integer to obtain a charge-balanced salt (preferably y is 1 to 3; most preferably 2 when T is a -1 charged anion); and wherein further said catalyst has a base hydrolysis rate constant of less than 0.23 M.sup.-1 s.sup.-1 (25.degree. C.). Preferred automatic dishwashing compositions comprise amylase and/or protease enzymes. Included are methods for washing tableware in domestic automatic dishwashing appliances using the cobalt catalysts.
摘要翻译： 提供了包含某些钴催化剂的自动餐具洗涤剂组合物。 更具体地，本发明涉及通过选择具有下式的钴漂白催化剂提供增强的清洁/漂白益处（特别是茶脱色）的自动餐具洗涤剂：[Co（NH 3）n（M）m（B）b] 钴处于+3氧化态; n为4或5（优选5）; M是通过一个位点与钴配位的一种或多种配体; m为0,1或2（优选1）; B是通过两个位点与钴配位的配体; b为0或1（优选为0），当b = 0时，m + n = 6，当b = 1时，m = 0，n = 4; 并且T是以y为单位存在的一个或多个适当选择的余离子，其中y是获得电荷平衡盐的整数（优选y为1至3;最优选2当T为-1荷电阴离子时）; 并且其中所述催化剂的另一个基础水解速率常数小于0.23M-1s-1（25℃）。 优选的自动餐具洗涤组合物包含淀粉酶和/或蛋白酶。 包括在使用钴催化剂的国内自动洗碗设备中洗餐具的方法。
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公开(公告)号：US5703030A
公开(公告)日：1997-12-30
申请号：US736647
申请日：1996-10-25
CPC分类号： C11D3/3932
摘要： Bleach compositions comprising certain carboxylate-containing cobalt catalysts are provided. More specifically, the invention relates to automatic dishwashing detergents and laundry compositions which provide enhanced cleaning/bleaching benefits (especially tea stain removal) through the selection of cobalt catalysts having the formula: �Co(NH.sub.3).sub.5 M!T.sub.y wherein cobalt is in the +3 oxidation state; and M is a substituted and unsubstituted C.sub.1 -C.sub.30 carboxylate-containing ligand having the formula RC(O)O--.
摘要翻译： 提供了包含某些含羧酸盐的钴催化剂的漂白组合物。 更具体地，本发明涉及通过选择具有下式的钴催化剂提供增强的清洁/漂白益处（特别是茶脱色）的自动餐具洗涤剂和洗衣组合物：钴[Co（NH 3）5 M] 氧化态; 并且M是具有式RC（O）O-的取代和未取代的含C1-C30羧酸盐的配体。
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公开(公告)号：US20100190678A1
公开(公告)日：2010-07-29
申请号：US12752240
申请日：2010-04-01
申请人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent
发明人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent
IPC分类号： C11D3/395
CPC分类号： C11D3/3932
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
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公开(公告)号：US20080167212A1
公开(公告)日：2008-07-10
申请号：US12070850
申请日：2008-02-21
申请人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent
发明人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent
CPC分类号： C11D3/3932
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
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公开(公告)号：US06566318B2
公开(公告)日：2003-05-20
申请号：US10093115
申请日：2002-03-07
申请人： Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent , Michael Eugene Burns
发明人： Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent , Michael Eugene Burns
IPC分类号： C11D732
CPC分类号： C11D3/3907 , C11D3/168 , C11D3/3932 , C11D3/3945
摘要： Laundry or cleaning composition comprising: (a) an effective amount, preferably from about 0.0001% to about 99.9%, more typically from about 0.1% to about 25%, of a bleach activator and/or organic percarboxylic acid; (b) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (c) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts in combination with bleach activators and/or organic percarboxylic acids.
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公开(公告)号：US06444808B1
公开(公告)日：2002-09-03
申请号：US09832579
申请日：2001-04-11
IPC分类号： C07D22500
摘要： Improved synthesis of a macropolycycle, more particularly, of a cross-bridged tetraazamacrocycle.
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公开(公告)号：US20110190188A1
公开(公告)日：2011-08-04
申请号：US13082685
申请日：2011-04-08
申请人： Daryle Hadley BUSCH , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Key Wiliams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent
发明人： Daryle Hadley BUSCH , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Key Wiliams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St. Laurent
IPC分类号： C11D3/60
CPC分类号： C11D3/3932
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
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公开(公告)号：US20080125344A1
公开(公告)日：2008-05-29
申请号：US11605627
申请日：2006-11-28
申请人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St.Laurent
发明人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Johnathan Kitko , James Charles Theophile Roger Burckett-St.Laurent
IPC分类号： C11D3/395
CPC分类号： C11D3/3932
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
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公开(公告)号：US06608015B2
公开(公告)日：2003-08-19
申请号：US10228853
申请日：2002-08-27
申请人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Jonathan Kitko , James Charles Theophile Roger Burckett-St. Laurent , Michael Eugene Burns
发明人： Daryle Hadley Busch , Simon Robert Collinson , Timothy Jay Hubin , Christopher Mark Perkins , Regine Labeque , Barbara Kay Williams , James Pyott Johnston , David Jonathan Kitko , James Charles Theophile Roger Burckett-St. Laurent , Michael Eugene Burns
IPC分类号： C11D300
CPC分类号： C11D3/3935 , C11D3/168 , C11D3/3932 , C11D3/3942 , C11D3/3945
摘要： Laundry or cleaning composition comprising: (a) a catalytically effective amount, preferably from about 1 ppb to about 99.9%, of a transition-metal bleach catalyst which is a complex of a transition-metal and a cross-bridged macropolycyclic ligand; and (b) at least about 0.1% of one or more laundry or cleaning adjunct materials, preferably comprising an oxygen bleaching agent. Preferred compositions are laundry compositions and automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits through the use of such catalysts.
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