Method for making amine-terminated polyarylene polyethers
    1.
    发明授权
    Method for making amine-terminated polyarylene polyethers 失效
    制备胺封端聚亚芳基聚醚的方法

    公开(公告)号:US06992165B2

    公开(公告)日:2006-01-31

    申请号:US10740095

    申请日:2003-12-17

    IPC分类号: C08G75/00

    CPC分类号: C08G65/4093

    摘要: A method for making an amine-terminated polyarylene polyether thermoplastic in which a liquid/solid slurry reaction mixture is formed in an oxygen-free atmosphere. The reaction mixture is composed of a dihydroxyaromatic compound, a dihaloaromatic compound, an amino-hydroxyaromatic compound, a weak base, an aprotic polar solvent and a non-aromatic azeotrope former which is substantially imiscible with the aprotic polar solvent, said azeotrope former consisting of a molecule which has from 6 to 10 carbon atoms. The reaction mixture is refluxed at an elevated temperature to eventually produce a solution of the amine-terminated polyarylene polyether in the polar solvent. The method is designed for use in producing large amounts of thermoplastic in a simple, efficient and reliable manner.

    摘要翻译: 一种制备其中在无氧气氛中形成液体/固体淤浆反应混合物的胺封端聚亚芳基聚醚热塑性塑料的方法。 该反应混合物由二卤代芳族化合物,氨基羟基芳族化合物,弱碱,非质子极性溶剂和与非质子极性溶剂基本上可混溶的非芳族共沸物组成,所述共沸物由 具有6至10个碳原子的分子。 将反应混合物在升高的温度下回流以最终产生胺封端的聚亚芳基聚醚在极性溶剂中的溶液。 该方法设计用于以简单,有效和可靠的方式生产大量的热塑性塑料。