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公开(公告)号：US08382945B2
公开(公告)日：2013-02-26
申请号：US12549960
申请日：2009-08-28
申请人： Yaoliang Hong , Kosaraju Krishna Mohan , Peter M. Froass , Mark Fagan , Christopher D. Anderson , Brian Boyars , Eric Scott Daniels , Victoria Laurentia Dimonie , Edward David Sudol , Andrew Klein
发明人： Yaoliang Hong , Kosaraju Krishna Mohan , Peter M. Froass , Mark Fagan , Christopher D. Anderson , Brian Boyars , Eric Scott Daniels , Victoria Laurentia Dimonie , Edward David Sudol , Andrew Klein
IPC分类号： D21H23/00
摘要： Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk.
摘要翻译： 提供了通过使用喷射生长法的悬浮聚合形成的可发泡微球。 微球由围绕发泡剂的连续不透气壳形成。 壳包括由初级单体形成的第一聚合物层和包含化学反应性单体或高Tg单体的第二层。 为了形成微球，将初级单体在反应容器中聚合至约90％的聚合，此时加入作为Tg至少为85℃的单体的二级单体或化学反应性单体 到反应容器中以驱动聚合反应完成。 因此，外层含有较大量的高Tg单体或具有共价键合阳离子物质的能力的化学反应性单体。 微球可用于造纸过程中以增加纸张体积。
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公开(公告)号：US20100051220A1
公开(公告)日：2010-03-04
申请号：US12549960
申请日：2009-08-28
申请人： Yaoliang Hong , Kosaraju Krishna Mohan , Peter M. Froass , Mark Fagan , Christopher D. Anderson , Brian Boyars , Eric Scott Daniels , Victoria Laurentia Dimonie , Edward David Sudol , Andrew Klein
发明人： Yaoliang Hong , Kosaraju Krishna Mohan , Peter M. Froass , Mark Fagan , Christopher D. Anderson , Brian Boyars , Eric Scott Daniels , Victoria Laurentia Dimonie , Edward David Sudol , Andrew Klein
摘要： Expandable microspheres formed by suspension polymerization using a shot growth method are provided. The microspheres are formed of a continuous, gas impermeable shell surrounding a blowing agent. The shell includes a first polymer layer formed from primary monomers and a second layer that includes a chemically reactive monomer or a high Tg monomer. To form the microspheres, the primary monomers are polymerized in a reaction vessel to an approximate 90% polymerization, at which time a secondary monomer that is either a monomer having a Tg of at least 85° C. or a chemically reactive monomer, is added to the reaction vessel to drive the polymerization reaction to completion. The outer layer thus contains either a larger amount of the high Tg monomer or a chemically reactive monomer that possesses the ability to covalently bond a cationic species. The microspheres may be used in papermaking processes to increase the paper bulk.
摘要翻译： 提供了通过使用喷射生长法的悬浮聚合形成的可发泡微球。 微球由围绕发泡剂的连续不透气壳形成。 壳包括由初级单体形成的第一聚合物层和包含化学反应性单体或高Tg单体的第二层。 为了形成微球，将初级单体在反应容器中聚合至约90％的聚合，此时加入作为Tg至少为85℃的单体的二级单体或化学反应性单体 到反应容器中以驱动聚合反应完成。 因此，外层含有较大量的高Tg单体或具有共价键合阳离子物质的能力的化学反应性单体。 微球可用于造纸过程中以增加纸张体积。
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公开(公告)号：US20080272331A1
公开(公告)日：2008-11-06
申请号：US11894883
申请日：2007-08-21
申请人： Satish C. Mohapatra , Edward David Sudol , Kejian Bian , Li Zhang , Eric Scott Daniels , Victoria Laurentia Dimonie , Andrew Klein
发明人： Satish C. Mohapatra , Edward David Sudol , Kejian Bian , Li Zhang , Eric Scott Daniels , Victoria Laurentia Dimonie , Andrew Klein
CPC分类号： C09K5/10 , B01J13/04 , Y10T428/2989 , Y10T428/2991 , Y10T428/2998 , Y10T428/31678 , Y10T428/31692 , Y10T428/31801 , Y10T428/31909
摘要： A method and composition for making hybrid nanoparticles and use of such nanoparticles are disclosed herein. In one embodiment of the invention, the hybrid nanoparticles comprise a phase change material (PCM) and a metal layer encapsulating the phase change material. In another embodiment of the invention, the hybrid nanoparticles comprise a phase change material, a polymer layer encapsulating the phase change material, and an outer metal layer encapsulating the polymer layer. In another embodiment of the invention, the hybrid nanoparticles comprise an inner core of a PCM encapsulated by a polymer shell containing embedded nanoparticles that have a high thermal conductivity.
摘要翻译： 本文公开了用于制备杂合纳米颗粒的方法和组合物以及这种纳米颗粒的使用。 在本发明的一个实施方案中，杂化纳米颗粒包含相变材料（PCM）和封装相变材料的金属层。 在本发明的另一个实施方案中，杂化纳米颗粒包含相变材料，封装相变材料的聚合物层和封装聚合物层的外部金属层。 在本发明的另一个实施方案中，杂化纳米颗粒包含由包含具有高热导率的嵌入纳米颗粒的聚合物壳包封的PCM的内芯。
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公开(公告)号：US07919184B2
公开(公告)日：2011-04-05
申请号：US11894883
申请日：2007-08-21
申请人： Satish C. Mohapatra , Edward David Sudol , Kejian Bian , Li Zhang , Eric Scott Daniels , Victoria Laurentia Dimonie , Andrew Klein
发明人： Satish C. Mohapatra , Edward David Sudol , Kejian Bian , Li Zhang , Eric Scott Daniels , Victoria Laurentia Dimonie , Andrew Klein
CPC分类号： C09K5/10 , B01J13/04 , Y10T428/2989 , Y10T428/2991 , Y10T428/2998 , Y10T428/31678 , Y10T428/31692 , Y10T428/31801 , Y10T428/31909
摘要： A method and composition for making hybrid nanoparticles and use of such nanoparticles are disclosed herein. In one embodiment of the invention, the hybrid nanoparticles comprise a phase change material (PCM) and a metal layer encapsulating the phase change material. In another embodiment of the invention, the hybrid nanoparticles comprise a phase change material, a polymer layer encapsulating the phase change material, and an outer metal layer encapsulating the polymer layer. In another embodiment of the invention, the hybrid nanoparticles comprise an inner core of a PCM encapsulated by a polymer shell containing embedded nanoparticles that have a high thermal conductivity.
摘要翻译： 本文公开了用于制备杂合纳米颗粒的方法和组合物以及这种纳米颗粒的使用。 在本发明的一个实施方案中，杂化纳米颗粒包含相变材料（PCM）和封装相变材料的金属层。 在本发明的另一个实施方案中，杂化纳米颗粒包含相变材料，封装相变材料的聚合物层和封装聚合物层的外部金属层。 在本发明的另一个实施方案中，杂化纳米颗粒包含由包含具有高热导率的嵌入纳米颗粒的聚合物壳包封的PCM的内芯。
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